DOI QR코드

DOI QR Code

박테리아 제거를 위한 완속 모래여과에서 탄소나노튜브의 적용성 검토

Applicability Assessment of Carbon Nanotube to Slow Sand Filtration for Bacteria Removal

  • 안희경 (한경대학교 지역자원시스템공학과) ;
  • 박성직 (한경대학교 지역자원시스템공학과)
  • An, Hee-Kyung (Department of Bioresources & Rural systems Engineering, Hankyong National University) ;
  • Park, Seong-Jik (Department of Bioresources & Rural systems Engineering, Hankyong National University)
  • 투고 : 2014.09.02
  • 심사 : 2014.12.31
  • 발행 : 2014.12.31

초록

본 연구에서는 박테리아 제거를 위한 완속모래여과에서 탄소나노튜브(Carbon Nanotube, CNT)의 적용성을 검토하기 위해서 전자현미경 분석 및 칼럼 실험을 수행하였다. CNT의 형태적 특성을 분석하기 위하여, 주사전자현미경으로 분석한 결과 CNT는 박테리아 부착이 용이한 섬유형태로 응집되어 있었다. CNT의 충진 두께, pH, 이온강도를 달리하며 칼럼 실험을 수행하였다. CNT의 충진 두께가 1 cm, 3 cm, 5 cm로 증가할수록 박테리아 제거율이 44.15%에서 99.95%로 증가하는 것으로 나타났다. 반면, pH가 5.5에서 8.5로 증가할 경우 정전기적 반발력에 의해 박테리아 제거율이 감소하는 경향을 보였다. 이온강도를 0 mM에서 50 mM로 증가하여 칼럼 실험을 수행한 경우 박테리아 제거율이 97.25%에서 70.90%로 감소하였다. 본 연구를 통해 CNT가 오염된 물에 함유되어 있는 박테리아를 처리하는 완속모래여과에 적용 가능한 것으로 나타났다.

The applicability of carbon nanotube (CNT) to slow sand filtration for the removal of bacteria was studied using scanning electron microscope and column experiments. The morphology of CNT were investigated using scanning electron microscope and the CNT looked like a skein serving bacteria favorable site for adhesion. Column experiments were performed over a range of CNT filter depth, pH, and ionic strength. Bacteria removal efficiency was found to increase from 44.15% to 99.95% as the CNT filter depth increased from 1 cm to 5 cm, and 3 cm of CNT filter depth was required for significant removal of bacteria. pH increase from 5.5 to 8.5 decreased the bacteria removal efficiency, due to the electrostatic repulsion between bacteria and CNT at higher pH. Bacteria removal efficiency decreased from 97.25% to 70.90% as the ionic strength increased from 0 mM to 50 mM. This study demonstrated that the CNT can be applied to slow sand filtration for treating microbially contaminated water.

키워드

참고문헌

  1. Woo, D. S., Kwon, M. S., Yoo, B. R., Park, G. H., Lee, Y. S., Jo, G. H. and Jo, Y. T., "Status of Water Resources in Korea" New introduction to water pollution, DongHwa Technology, p. 17(2006).
  2. Foppen, J. W., Transport of Escherichia coli in saturated porous media. Taylor & Francis Group plc, London(2007).
  3. World Health Organization, Combating waterborne disease at the household level / International Network to Promote Household Water Treatment and Safe Storage, WHO Press, Geneva, Switzerland, pp. 10-31(2007).
  4. Upadhyayula, V. K. K., Deng, S., Mitchell, M. C. and Smith, G. B., "Application of carbon nanotube technology for removal of contaminants in drinking water: A review," Sci. Total Environ., 408(1), 1-13(2009). https://doi.org/10.1016/j.scitotenv.2009.09.027
  5. Kosek, M., Bern, C. and Guerrant, R. L., "The global burden of diarrhoeal disease, as estimated from studies published between 1992 and 2000," Bullet. World Health Organ., 81 (3), 197-204(2003).
  6. Brady-Estevezal, A. S., Nguyenb, T. H., Gutierrezb, L. and Elimelecha, M., "Impact of solution chemistry on viral removal by a single-walled carbon nanotube filter," Water Res., 44(13), 3773-3780(2010). https://doi.org/10.1016/j.watres.2010.04.023
  7. Montgomery, M. A. and Elimelech, M., "Water and sanitation in developing countries: including health in the equation," Environ. Sci. Technol., 41(1), 17-24(2007). https://doi.org/10.1021/es072435t
  8. Assavasilavasukul, P., Lau, B. L. T., Harrington, G. W., Hoffman, R. M. and Borchardt, M, A., "Effect of pathogen concentrations on removal of Cryptosporidium and Giardia by conventional drinking water treatment," Water Res., 42 (10-11), 2678-2690(2008). https://doi.org/10.1016/j.watres.2008.01.021
  9. Lechevallier, M. W. and Au, K. K., Water treatment and pathogen control, Impact of treatment on microbial quality: a review document on treatment efficiency to remove pathogens, IWA Publishing(2004).
  10. Ijima, S., "Helical microtube of graphitic carbon," Nature, 354, 56-58(1991). https://doi.org/10.1038/354056a0
  11. Lee, S. H., "Preparation of Metallic Nanoparticle/Carbon Nanotube,"Ph. D. Degree thesis, Graduate School of Kyung Hee University(2009).
  12. Diallo, M. S. and Savage, N., "Nanoparticles and water quality," J. Nanopart. Res., 7(4-5), 325-330(2005). https://doi.org/10.1007/s11051-005-8543-x
  13. Li, Q. L., Mahendra, S., Lyon, D. Y., Brunet, L., Liga, M. V., Li, D. and Alvarez, P. J. J., "Antimicrobial nanomaterials for water disinfection and microbial control: potential applications and implications," Water Res., 42(18), 4591-4602 (2008). https://doi.org/10.1016/j.watres.2008.08.015
  14. Mauter, M. S. and Elimelech, M., "Environmental applications of carbon-based nanomaterials," Environ Sci. Technol., 42(16), 5843-5859(2008). https://doi.org/10.1021/es8006904
  15. Kim, H. C., "Mechanical and Physical Properties Changes of Nanocomposites due to Addition of Carbon Nanotubes," Ph. D. Degree thesis, Graduate School of KAIST(2003).
  16. Kang, S., Herzberg, M., Rodrigues, D. F. and Elimelech, M., "Antibacterial effect of carbon nanotubes: Size dose matter!," Langmuir, 24, 6409-6413(2008). https://doi.org/10.1021/la800951v
  17. Brady-Estevez, A. S., Kang, S. and Elimelech, M., "A singlewalled- carbon-nanotube filter for removal of viral and bacterial pathogens," Small, 4(4), 481-484(2008). https://doi.org/10.1002/smll.200700863
  18. Upadhyayula, V. K. K., Deng, S., Smith, G. B. and Mitchell, M. C., "Adsorption of Bacillus subtilis on single-walled carbon nanotube aggregates, activated carbon and NanoCeram," Water Res., 43(1), 148-156(2009). https://doi.org/10.1016/j.watres.2008.09.023
  19. Jo, G. H., Kwon, J. H., Kim, T. G., Park, G. Y., Son, I. S., Woo, D. S., Lee, S. H. and Lee, W. H., Water and wastewater engineering, DongHwa Technology, (2008).
  20. Taylor, D. H., Moore, R. S. and Sturman, L. S., "Influence of pH and electrolyte composition on adsorption of poliovirus by soils and minerals," Appl. Environ. Microbiol., 42 (6), 976-984(1981).
  21. Elimelech, M., Gregory, J., Jia, X. and Williams, R. A., Particle Deposition and Aggregation: Measurement, Modeling and Simulation, Butterworth-Heinemann Ltd.(1995).