Applied Science and Convergence Technology

한국진공학회 (The Korean Vacuum Society)
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Reaction Route to the Crystallization of Copper Oxides

  • Chen, Kunfeng (State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences) ;
  • Xue, Dongfeng (State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences)
  • 투고 : 2014.01.22
  • 심사 : 2014.01.28
  • 발행 : 2014.01.30
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초록

Copper is an important component from coin metal to electronic wire, integrated circuit, and to lithium battery. Copper oxides, mainly including $Cu_2O$ and CuO, are important semiconductors for the wide applications in solar cell, catalysis, lithium-ion battery, and sensor. Due to their low cost, low toxicity, and easy synthesis, copper oxides have received much research interest in recent year. Herein, we review the crystallization of copper oxides by designing various chemical reaction routes, for example, the synthesis of $Cu_2O$ by reduction route, the oxidation of copper to $Cu_2O$ or CuO, the chemical transformation of $Cu_2O$ to CuO, the chemical precipitation of CuO. In the designed reaction system, ligands, pH, inorganic ions, temperature were used to control both chemical reactions and the crystallization processes, which finally determined the phases, morphologies and sizes of copper oxides. Furthermore, copper oxides with different structures as electrode materials for lithium-ion batteries were also reviewed. This review presents a simple route to study the reaction-crystallization-performance relationship of Cu-based materials, which can be extended to other inorganic oxides.

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피인용 문헌

  1. Room temperature light-induced recrystallization of Cu2O cubes to CuO nanostructures in water vol.16, pp.36, 2014, https://doi.org/10.1039/C4CE01174K
  2. Polymorphic crystallization of Cu2O compound vol.16, pp.24, 2014, https://doi.org/10.1039/C4CE00339J
  3. An investigation on the tuning effect of glucose-capping on the size and bandgap of CuO nanoparticles vol.27, pp.2, 2016, https://doi.org/10.1016/j.apt.2016.01.006