Journal of the Korean Ceramic Society (한국세라믹학회지)

The Korean Ceramic Society (한국세라믹학회)
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Microwave Dielectric Properties of Oriented BN / Polyvinyl Butyral Matrix Composites

  • Ahn, Hong Jun (Department of Materials Engineering, Kyonggi University) ;
  • Kim, Eung Soo (Department of Materials Engineering, Kyonggi University)
  • Received : 2013.10.18
  • Accepted : 2013.12.11
  • Published : 2014.01.31
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Abstract

The effects of an amphiphilic agent and the orientation of BN on the microwave dielectric properties of BN / polyvinyl butyral (PVB) composites were investigated as a function of the BN content in volume fractions from 0.1 to 0.5 ($V_f$). The plate-shaped BN samples were oriented in the PVB matrix by physical processes, in this case tape casting and laminate methods. With an increase in the BN content, the dielectric constant (K) increased because the K of BN was higher than that of the PVB. At the same BN content, composites with an in-plane orientation of the BN showed a higher dielectric constant than that of composites with a transverse orientation of the BN because the ceramics were oriented parallel to the electric field. All of the composites showed nearly constant K values ranging from 1 to 9.4 GHz, indicating good frequency stability over a wide frequency range. At the same frequency, the K values of the composites increased with an increase in the BN content.

Keywords

References

  1. C. Y. Zhi, B. Yoshio, T. Takeshi, C. C. Tang, and D. Goldberg, "Dielectric and Thermal Properties of Epoxy/Boron nitride Nanotube Composites," Pure Appl. Chem., 82 [11] 2175-83 (2010).
  2. D. Mishra and A. Satapathy, "An Investigation on The Dielectric Properties of Epoxy Filled With Glass Micro-Spheres and Boron Nitride," Int. J. Polym. Mater., 10-12 (2012).
  3. C. Zhang and G. C. Stevens, "Dielectric Properties of Boron Nitride Filled Epoxy Composites," IEEE Conf. Electr. Insul. Dielectr. Phenom., 19-22 (2006).
  4. B. H. Xie, X. Huang, and G. J. Zhang, "High Thermal Conductive Polyvinyl Alcohol Composites with Hexagonal Boron Nitride Microplatelets as Fillers," Compos. Sci. Technol., 85 [21] 98-103 (2013). https://doi.org/10.1016/j.compscitech.2013.06.010
  5. D. Tan and P. Irwin, Polymer Based Nanodielectric Composites, in Advances in Ceramics - Electric and Magnetic Ceramics, Bioceramics, Ceramics and Environment; Ed. by Prof. Costas Sikalidis, InTech, Croatia, 2011.
  6. S. K. Mohamed, M. Albayati, W. A. M. Omara, A. A. Abdelhamid, H. Potgeiter, A. S. Hameed, and K. M. Al-Janabi, "Functionalization of Ibuprofen Core Structure Compound: Part 1 Synthesis of Potential Chemotherapeutic Agents Incorporated Ibuprofen Substructure and Their in vitro Antimicrobial Study," J. Chem. Pharm. Res., 4 [7] 3505-17 (2012).
  7. K. Thakur and K. S. Pitre, "Polarographic (DCP & DPP) Determination of Ellagic Acid in Strawberries& Pharmaceutical Formulations," J. Chin. Chem. Soc., 55 [1] 143-46 (2008). https://doi.org/10.1002/jccs.200800022
  8. W. L. Song, P. Wang, L. Cao, A. Anderson, M. J. Meziani, A. J. Farr, and Y. P. Sun, "Polymer/Boron Nitride Nanocomposites Materials for Superior Thermal Transport Performance," Angew. Chem., Int. Ed., 51 [26] 6498-501 (2012). https://doi.org/10.1002/anie.201201689
  9. R. Inoue, Y. Odate, E. Tanab, H. Kitano, and A. Maeda "Data Analysis of the Extraction of Dielectric Properties from Insulating Substrates Utilizing the Evanescent Perturbation Method," IEEE Trans. Microwave Theory Tech., 54 [2] 522-32 (2006). https://doi.org/10.1109/TMTT.2005.862707
  10. E. Tuncer, I. Sauers, D. R. James, and A. R. Ellis, "Dielectric Properties of Polyvinyl Alcohol, Poly(Methyl Methacrylate), Polyvinyl Butyral Resin and Polyimide at Low Temperatures," AIP Conf. Proc., 986 [1] 190 (2008).
  11. T. Zhang, M. Q. Wu, S. R. Zhang, J. Xiong, J. M. Wang, D. H. Zhang, F. M. He, and Z. O. Li, "Permittivity and its Temperature Dependence in Hexagonal Structure BN Dominated by the Local Electric Filed," Chin. Phys. B, 21 [7] 077701 (2012). https://doi.org/10.1088/1674-1056/21/7/077701
  12. R. Kochetov, T. Andritsch, P. H. F. Morshuis, and J. J. Smit, "Anomalous Behavior of the Dielectric Spectroscopy Response of Nanocomposites," IEEE Trans. Dielectr. Electr. Insul., 19 [1] 107-17 (2012). https://doi.org/10.1109/TDEI.2012.6148508
  13. S. George, V. N. Deepu, P. Mohanan, and M. T. Sebastian, "Influence of $Ca[(Li_{1/3}Nb_{2/3})_{0.8}Ti_{0.2}]O_{3-{\delta}}$ Filler on the Micro-Wave Dielectric Properties of Polyethylene and Polystyrene for Microelectronic Applications," Polym. Eng. Sci., 50 [3] 570-76 (2010). https://doi.org/10.1002/pen.21554
  14. M. A. Chaudhry, "High-Temperature Dielectric Behaviour of Hexagonal Boron Nitride Measured Perpendicular to the Cleavage Plane," J. Mater. Sci., 26 [4] 1106-08 (1991). https://doi.org/10.1007/BF00576794

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