Membrane Journal (멤브레인)

The Membrane Society of Korea (한국막학회)
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Utilization of Iodine for the Enhanced Permeance of Facilitated Olefin Transport Nanocomposite Membrane

올레핀 촉진수송 나노복합체 분리막의 투과도 향상을 위한 iodine의 활용

  • Choi, Yeji (Department of Chemistry, Sangmyung University) ;
  • Lee, Eun Yong (Department of Chemistry, Sangmyung University) ;
  • Kang, Sang Wook (Department of Chemistry, Sangmyung University)
  • 최예지 (상명대학교 자연과학대학 화학과) ;
  • 이은용 (상명대학교 자연과학대학 화학과) ;
  • 강상욱 (상명대학교 자연과학대학 화학과)
  • Received : 2014.10.16
  • Accepted : 2014.12.11
  • Published : 2014.12.31
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Abstract

Nanocomposite membrane to show facilitated olefin transport was prepared for enhanced separation performance. Addtion of halogen molecules into PVP/AgNPs/ TCNQ nanocomposite membrane was expected to further polarize the surface of AgNPs for enhancing the separation performance. The formation of AgNPs and presence of iodine was confirmed by TEM and EDS analysis, respectively. The separation performance for propylene/propane mixture was compared with that of PVP/AgNPs/TCNQ nanocomposite membrane. The long-term stability of membrane was investigated with time.

올레핀/파라핀 분리 기술로 silver nanoparticles(AgNPs)를 운반체로 사용하여 보다 효과적으로 올레핀을 분리하는 고성능 올레핀 촉진수송 분리막을 제조하고자 하였다. 기존에 성능이 밝혀진 PVP/AgNPs/TCNQ 나노복합체 막에 추가적으로 할로겐 물질을 첨가하여 AgNPs의 표면을 더 양극화시킴으로써 성능을 향상시키고자 하였다. 제조한 용액을 TEM과 EDS로 분석해서 AgNPs의 형성과 iodine의 존재를 확인하였다. Propylene/propane 혼합기체의 분리 성능 실험을 통해 기존 PVP/AgNPs/TCNQ 나노복합체 분리막과 기체 분리 성능을 비교하였고, long-term stability 실험을 통해 분리막의 안정성을 조사하였다.

Keywords

References

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