Polymer(Korea) (폴리머)

The Polymer Society of Korea (한국고분자학회)
권호 표지
DOI QR코드

DOI QR Code

Preparation of Acrylic Pressure Sensitive Adhesives for Optical Applications and Their Adhesion Performance

광학용 아크릴 점착제 제조 및 점착특성에 관한 연구

  • Baek, Seung-Suk (Department of Polymer Science & Engineering, Center for Photofunctional Energy Materials, Dankook University) ;
  • Jang, Se-Jung (Department of Polymer Science & Engineering, Center for Photofunctional Energy Materials, Dankook University) ;
  • Lee, Jong-Hoon (Advanced Materials Research Center, Toray Advanced Materials Korea Inc.) ;
  • Kho, Dong-Han (Advanced Materials Research Center, Toray Advanced Materials Korea Inc.) ;
  • Lee, Sang-Hoon (Advanced Materials Research Center, Toray Advanced Materials Korea Inc.) ;
  • Hwang, Seok-Ho (Department of Polymer Science & Engineering, Center for Photofunctional Energy Materials, Dankook University)
  • 백승석 (단국대학교 고분자공학과, 광에너지소재연구센터) ;
  • 장세정 (단국대학교 고분자공학과, 광에너지소재연구센터) ;
  • 이종훈 (도레이첨단소재(주) 첨단재료연구센터) ;
  • 고동한 (도레이첨단소재(주) 첨단재료연구센터) ;
  • 이상훈 (도레이첨단소재(주) 첨단재료연구센터) ;
  • 황석호 (단국대학교 고분자공학과, 광에너지소재연구센터)
  • Received : 2013.10.09
  • Accepted : 2013.11.09
  • Published : 2014.03.25
Download PDF
⟨ Previous Next ⟩

Abstract

To prepare acrylic pressure sensitive adhesives (PSAs), quaternary copolymer syrups were photopolymerized from 2-ethylhexyl acrylate and 2-hydroxyethyl acrylate as default constituents and isobornyl acrylate and tetrahydrofurfuryl acrylate (THFA) as variable constituents. After polymerization, 1,6-hexanediol diacrylate and photoinitiator were added and then crosslinked by UV-irradiation to prepare the PSAs. The characteristics of the syrup such as viscosity, molecular weight, and solid content were investigated. As increasing THFA contents, the relationship between molecular weight and solid content of the syrup was reciprocal. Also, the relationship between peel strength and surface energy of the PSAs showed the same tendency. All the PSA samples showed high transmittance (more than 92%), low haze (less than 1.0%) and low color-difference (less than 1.0).

본 연구는 2-ethylhexyl acrylate와 2-hydroxyethyl acrylate 기본구조에 isobornyl acrylate와 tetrahydrofurfuryl acrylate(THFA)의 조성비를 변화시키면서 광중합된 4원 공중합체를 합성한 후 가교제로 1,6-hexanediol diacrylate가 혼합된 시럽을 제조하였다. 합성한 시럽에 UV-광원을 조사시켜 점착제를 제조한 후 점착특성과 광학특성을 고찰하였으며 시럽의 기본물성인 고형분, 점도, 및 분자량 분석도 수행하였다. THFA의 함량이 증가할수록 시럽의 분자량은 감소하였으나 고형분은 반대로 증가하였다. 점착제의 박리강도는 THFA의 함량에 따른 반비례관계를 나타내고 점착제의 표면에너지는 비례관계를 나타내었다. 또한 모든 점착제에서 92% 이상의 광투과도와 1.0%이하의 haze값, 그리고 1.0 이하의 색차계값을 보여주었다.

Keywords

References

  1. I. Benedek, Pressure-Sensitive Adhesives and Application, 2nd Edition, Marcel Dekker, Inc., New York, 2004.
  2. C. Creton, Materials Science and Technology: A Comprehensive Treatment, VCH, Weinheim, 1997.
  3. W. H. Shecut and H. H. Day, U.S. Patent 3,965 (1845).
  4. I. W. Levine, U.S. Patent 1,537 (1926).
  5. H. S. Park, Polymer(Korea), 16, 693 (1992).
  6. J. S. Bae, E. K. Park, H. S. Park, and M. S. Pyun, Polymer(Korea), 17, 203 (1993).
  7. R. Mehnert, A. Pincus, I. Janorsky, R. Stowe, and A. Berejka, UV & EB Curing Technology & Equipment, John Wiley & Sons, New York, 1998.
  8. T. Kauffman, Adhesives Age, Sep., s8 (1999).
  9. M. Okido, Adhesion, 43, 23 (1999).
  10. T. Doba, J. Adh. Soc. Jap., 35, 521 (1999).
  11. K. Kimura, J. Adh. Soc. Jap., 35, 323 (1999).
  12. M. Nakazawa, J. Adh. Soc. Jap., 36, 28 (2000).
  13. S.-S. Baek, S. W. Lee, and S.-H. Hwang, Polymer(Korea), 37, 121 (2013).
  14. I. B. Kim and M. C. Lee, Korean Chem. Eng. Res., 46, 76 (2008).
  15. T. Fukuda, Y.-D. Ma, and H. Inagaki, Macromolecules, 18, 17 (1985). https://doi.org/10.1021/ma00143a003
  16. Q. You, J. Wang, Y. Eng, X. Shu, Q. Ou, X. Xu, and K. Shen, Plasma Sci. Technol., 8, 433 (2006). https://doi.org/10.1088/1009-0630/8/4/14
  17. Y. Liu, J. C. Haley, K. Deng, W. Lau, and M. A. Winnik, Macromolecules, 40, 6422 (2007). https://doi.org/10.1021/ma070853c
  18. C. Plessis, G. Arzamendi, J. R. Leiza, J. M. Alberdi, H. A. S. Schoonbrood, D. Charmot, and J. M. Asua, J. Polym. Sci., Part A: Polym. Chem., 39, 1106 (2001). https://doi.org/10.1002/1099-0518(20010401)39:7<1106::AID-POLA1088>3.0.CO;2-M
  19. L. Li, M. Tirrell, G. R. Korba, and A. Poclus, J. Adhes., 76, 307 (2001). https://doi.org/10.1080/00218460108030724
  20. S. M. Taghizadeh and D. Ghasemi, J. Appl. Polym. Sci., 120, 411 (2011). https://doi.org/10.1002/app.33153
  21. K. Yatho and K. Dodou, Int. J. Pharm., 24, 333 (2007).
  22. J. Lim, UV/EB Curable Polymeric Materials, Korean Studies Information, Paju, 2009.
  23. R. Seighi, E. Hewlett, and J. Kim, J. Dent. Res., 68, 1760 (1989). https://doi.org/10.1177/00220345890680120801
  24. M. Gross and J. Moser, J. Oral Rehab., 4, 311 (1977). https://doi.org/10.1111/j.1365-2842.1977.tb00997.x

Cited by

  1. Improvement in mechanical properties and thermal stability of solvent-based pressure-sensitive adhesives based on triazine heterocyclic monomer vol.133, pp.15, 2015, https://doi.org/10.1002/app.43281
  2. Adhesion Properties on the Molecular Weight and Various Substrates of Multi-layered Structural Acrylic Adhesive vol.39, pp.3, 2015, https://doi.org/10.7317/pk.2015.39.3.514
  3. The Preparation and Adhesion Performances of Transparent Acrylic Pressure Sensitive Adhesives Containing Acrylamide Monomer for Optical Applications vol.51, pp.3, 2016, https://doi.org/10.7473/ec.2016.51.3.181
  4. Preparation of Solventless UV Curable Thermally Conductive Pressure Sensitive Adhesives and Their Adhesion Performance vol.52, pp.2, 2017, https://doi.org/10.7473/ec.2017.52.2.136
  5. FTIR을 이용한 아크릴레이트 단량체의 광-열 복합경화 거동 연구 vol.42, pp.4, 2018, https://doi.org/10.7317/pk.2018.42.4.714
  6. 색차계를 이용한 방사무늬김(Pyropia yezoensis Ueda)의 황백화 평가 vol.36, pp.4, 2014, https://doi.org/10.11626/kjeb.2018.36.4.620