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Structural and Magnetic Properties of Epitaxial FexCo100-x Alloys Grown on Cr Substrate

  • Hossain, M.B. (Department of Materials Science and Engineering, Chungnam National University) ;
  • Kim, C.G. (Department of Materials Science and Engineering, Chungnam National University) ;
  • Chun, B.S. (Division of Industrial Metrology, Korea Research Institute of Standards and Science) ;
  • Kim, W.D. (Division of Industrial Metrology, Korea Research Institute of Standards and Science) ;
  • Hwang, C. (Division of Industrial Metrology, Korea Research Institute of Standards and Science)
  • Received : 2013.10.14
  • Accepted : 2013.11.07
  • Published : 2014.03.31

Abstract

We report the correlation between the magnetic properties and lattice parameter of $Fe_xCo_{100-x}$ alloys as a function of constituent concentration. The saturation magnetization increases with Fe content and has a maximum value at approximately x=70 at.%. However, collapse in relative saturation magnetization is observed at approximately 30 at.% to 70 at.% of Fe in $Fe_xCo_{100-x}$ alloys. The collapse is due to the formation of Co-Co and Fe-Fe antibonding states instead of Fe-Co bonds. The lattice parameter also shrinks at approximately 30 at.% to 70 at.% of Fe. This shrinkage is due to an increase in the number of nearest neighbor antisite atoms, which then leads to a decrease in the long range order parameter.

Keywords

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