Journal of the Korean Ceramic Society (한국세라믹학회지)

The Korean Ceramic Society (한국세라믹학회)
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Joining Behavior of Ceramics to Metal by Using Lead-bismate Heavy Metal Glass Frit

중금속 창연산화납계 저온유리 분말을 이용한 세라믹스/금속의 접합거동

  • Choi, Jin Sam (School of Advanced Materials Engineering, University of Ulsan)
  • 최진삼 (울산대학교 첨단소재공학부)
  • Received : 2014.03.14
  • Accepted : 2014.06.16
  • Published : 2014.07.31
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Abstract

The joining behavior of forsterite ceramics to SUS304 alloy using $8PbO-78Bi_2O_3-8B_2O_3-4ZnO-2SiO_2$ (wt%) system glass frit was investigated. The contact angle was smaller than $90^{\circ}$ at a temperature of $460^{\circ}C$. Redox reaction at the interface between forsterite and SUS304 was found to appear when the electrons in the metal part moved toward the glass part and the oxygen ions in glass moved to the metal side. The decrease of the surface tension due to the PbO solubility on the forsterite side contributed to the better wetting behavior at low temperature.

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References

  1. A. G. M. Othman and N. M. Khalil, "Sintering of Magnesia Refractories though the Formation of Periclase-Forsterite-Spinel Phase," Ceram. Inter., 31 [8] 1117-21 (2005). https://doi.org/10.1016/j.ceramint.2004.11.011
  2. W. D. Kingery, H. K. Bowen, and D. R. Uhlmann, "Introduction to Ceramics," 2nd Ed. pp. 207-10 and pp. 304-11, John Wiley & Sons, New Jersey, 1976.
  3. C. Chanmung, M. Naksata, T. C. Chairuangsri, H. Jain, and C. E. Lyman, "Microscopy and Strength of Borosilicate Glass-to-Kovar Alloy Joints," Mater. Sci. Eng., A, 474 [1-2] 218-24 (2008). https://doi.org/10.1016/j.msea.2007.04.016
  4. T. S. Chern and H. L. Tsai, "Wetting and Sealing of Interface between 7056 Glass and Kovar Alloy," Mat. Chem. Phy., 104 [2-3] 472-78 (2007). https://doi.org/10.1016/j.matchemphys.2007.04.012
  5. J. S. Choi, D. Y. Jeong, D. W. Shin, and W. T. Bae, "Characteristics of the PbO-$Bi_2O_3$-$B_2O_3$-ZnO-$SiO_2$ Glass System Doped with Pb Metal Filler(in Korean)," J. Kor. Ceram. Soc., 50 [3] 238-43 (2013). https://doi.org/10.4191/kcers.2013.50.3.238
  6. J. S. Choi, D. W. Shin, and W. T. Bae, "Effect of an Additive on the Physical and Electrical Properties of the $B_2O_3$-$Bi_2O_3$-ZnO Glass System for a Sheath Heater Module(in Korean)," J. Kor. Ceram. Soc., 50 [1] 57-62 (2013). https://doi.org/10.4191/kcers.2013.50.1.57
  7. E. M. Levin, C. R. Robbins, and H. F. McMurdie, "Phase Diagrams for Ceramists," Am. Ceram. Soc., 1 712 (1979).
  8. W. D. Kingery, "Role of Surface Energies and Wetting in Metal-ceramics Sealing," Bull. Am. Ceram. Soc., 35 108-12 (1956).
  9. A. Zanchetta, P. Lortholary, and P. Lefort, "Ceramic to Metal Sealing: Interfacial Reactions Mechanism in a Porcelain-Kovar Junction," J. All. Comp., 228 86-95(1995). https://doi.org/10.1016/0925-8388(95)01656-2
  10. W. C. Wagner, K. Asgar, W. C. Bigelow, and R. A. Flinn, "Effect of Interfacial Variables on Metal-porcelain Bonding," J. Biomed. Mat. Res., 27 [4] 531-37 (1993). https://doi.org/10.1002/jbm.820270414
  11. C. E. Hoge, J. J. Brennan, and J. A. Pask, "Inerfacial Reaction and Wetting Behavior of Glass Iron System," J. Am. Ceram. Soc., 56 [2] 51-54 (1973). https://doi.org/10.1111/j.1151-2916.1973.tb12355.x
  12. J. A. Pask, "New Techniques in Glass-to-Metal Sealing," Proc. IRC, 36 [2] 286-89 (1948). https://doi.org/10.1109/JRPROC.1948.233914
  13. W. D. Kingery, "Role of Surface Energies and Wetting in Metal-ceramics Sealing," Bull. Am. Ceram. Soc., 35 108-112 (1956).
  14. W. Gąsior, Z. Moser, and J. Pstrus, "Density and Surface Tension of the Pb-Sn Liquid Alloys," J. Phas. Equ., 22 [1] 20-25 (2001). https://doi.org/10.1007/s11669-001-0051-9

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