DOI QR코드

DOI QR Code

Assessment of TOC Analysis Method for Livestock Manure including High Strength Solid Organics

고농도 고형 유기물질을 포함하는 가축 분뇨의 TOC 분석방법 평가

  • Lee, Yunhee (Department of Railroad, Civil & Environmental Engineering, Woosong University) ;
  • Oa, Seong-Wook (Department of Railroad, Civil & Environmental Engineering, Woosong University) ;
  • Kim, Yongseok (National Institute of Environmental Research) ;
  • Park, Jihyung (National Institute of Environmental Research)
  • Received : 2014.07.03
  • Accepted : 2014.08.22
  • Published : 2014.09.30

Abstract

Two different methods for TOC (Total Organic Carbon) analysis of livestock manure including high strength solid organics were evaluated. Firstly, an analyzing method by dilution after pre-treated by Ultrasonicator and 100 mesh sieve for homogenization was defined as TOC 1; and secondly method divided by particulate organic carbon (POC) and dissolved organic carbon (DOC) was defined as TOC 2. 116 samples collected from 56 farms were analyzed in TOC1, TOC2, BOD and VSS. TOC1 method showed higher accuracy at less than 30,000 mg/L of TOC while TOC2 method presented significant reliability at over that concentration. Regarding to the sample with the same VSS concentration, the correlation between TOC 2 and VSS (${\rho}$: 0.806) was slightly higher than that between TOC 1 and VSS (${\rho}$: 0.784), resulted from a relatively low loss of solids and a low error probability (dilution and homogenization effects) in the analyzing procedures. In addition, the reliability between POC and VSS in TOC2 was high and the POC was about 4.4 fold that of the VSS. Consequently, TOC 2 without dilution effect was assessed as a proper method to increase the analyzing accuracy of swine manure including high solid organics.

Keywords

References

  1. American Public Health Association, American Water Works Association, and Water Environment Federation (APHA, AWWA, WEF). (2005). Standard Methods for the Examination of Water and Wastewater, 21st ed., American Public Health Association, American Water Works Association, and Water Environment Federation, Washington D.C, USA, pp. 5-18-5-24.
  2. Choi, E., Kim, D., Eum, Y., Yun, Z., and Min, K. S. (2005). Full-scale Experience for Nitrogen Removal from Piggery Waste, Water Environmental Research, 77(4), pp. 381-389. https://doi.org/10.2175/106143005X51969
  3. El-rehaili, A. M. (1995). Response of BOD, COD and TOC of Secondary Effluents to Chlorination, Water Research, 29(6), pp. 1571-1577. https://doi.org/10.1016/0043-1354(94)00234-X
  4. Lasagni, M., Collina, E., Ferri, M., Tettamanti, M., and Pitea, D. (1997). Total Organic Carbon in Fly Ash from MSW Incinerators as a Potential Combustion Indicator: Setting Up of the Measurement Methodology and Preliminary Evaluation, Waste Management & Research, 15(5), 507-521. https://doi.org/10.1177/0734242X9701500506
  5. Leenheer, J. A. and Croue, J. P. (2003). Characterizing Aquatic Dissolved Organic Matter, Environmental Science & Technology, 37(1), 18A-26A. https://doi.org/10.1021/es032333c
  6. Ministry of Environment (MOE). (2006). General Plan for Water Environmental Management: General Plan for Water Quality Control of 4 Major River Basins, Ministry of Environment, pp. 12-24. [Korean Literature]
  7. Ministry of Environment (MOE). (2008). A Study of Direction of Policy to Evaluate and Control of Organic Compounds in Public Water, Ministry of Environment, pp. 7. [Korean Literature]
  8. Ministry of Environment (MOE). (2011). Standard Methods for the Measurement of Water and Wastewater, No. 2011-103, pp. 87 & 137. [Korean Literature]
  9. National Institute of Environmental Research (NIER). (2009). A study of Proper Control Direction of Organic Matters for Watershed Management and Discharge Sources, National Institute of Environmental Research, pp. 11-16. [Korean Literature]
  10. National Institute of Environmental Research (NIER). (2012a). The National Water Quality Assessment 2011, National Institute of Environmental Research, No. 2012-160, pp. 2-7. [Korean Literature]
  11. National Institute of Environmental Research (NIER). (2012b). The Study on the Background TOC Levels and Accomplishment Rate of Target Water Quality in 4 Major River Basins, National Institute of Environmental Research, NIER-RP2012-185, pp. 1-2. [Korean Literature]
  12. National Institute of Environmental Research (NIER). (2013). The study on the background TOC levels and accomplishment rate of target water quality in 4 major river basins (II), National Institute of Environmental Research, NIER-RP2013-291, pp. 1-2. [Korean Literature]
  13. Rural Development Administration (RDA). (2009). Study to Re-establish the Amount and Major Compositions of Manure from Livestock, Rural Development Administration, 11-1390000-002309-01, pp. 102-105. [Korean Literature]
  14. Visco, G., Campanella, L., and Nobili, V. (2005). Organic Carbons and TOC in Waters: An Overview of the International Norm for Its Measurement, Micro-chemical Journal, 79, pp. 185-191. https://doi.org/10.1016/j.microc.2004.10.018