Journal of the Korean Crystal Growth and Crystal Technology (한국결정성장학회지)

The Korea Association of Crystal Growth (한국결정성장학회)
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Separation of Nickel and Tin from copper alloy dross

구리 합금 부산물에서의 주석과 니켈의 분리

  • Lee, Jung-Il (Department of Materials Science and Engineering, Korea National University of Transportation) ;
  • Hong, Chang Woo (Department of Civil Engineering, Korea National University of Transportation) ;
  • Ryu, Jeong Ho (Department of Materials Science and Engineering, Korea National University of Transportation)
  • 이정일 (한국교통대학교 신소재공학과) ;
  • 홍창우 (한국교통대학교 토목공학과) ;
  • 류정호 (한국교통대학교 신소재공학과)
  • Received : 2014.08.25
  • Accepted : 2014.09.12
  • Published : 2014.10.31
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Abstract

Recently, the demands for separation/recovery of valuable metals such as nickel or tin from copper based alloys has been attracting much attention from the viewpoints of environmental protection and resource utilization. In this report, experimental results on concentration increasement of nickel and tin compared to the previous report are investigated. Ni is successfully separated by a organic solvent and reduced to the metal powder whose concentration is over 98 %. Sn is separated by a selective solution method and its concentration is increased to 97.5 % by three consecutive solution and reduction process. Crystal structure, surface morphology and microstructure of the separated samples are studied.

최근 금속자원 재활용과 환경보호에 대한 기술적 필요성에 의해 구리(Cu)를 주성분으로 하는 동합금으로부터 니켈, 주석 등의 유가금속의 분리/회수에 대한 관심이 높아지고 있다. 본 연구에서는 기존에 발표한 니켈과 주석의 분리연구 결과를 토대로 보다 높은 농도로 분리할 수 있는 공정을 검토하였다. 니켈의 경우 유기용매를 이용하여 동합금에서 니켈을 선택적으로 분리한 후 환원열처리를 통하여 순도 98.0 % 이상의 니켈 금속분말을 성공적으로 제조하였다. 주석의 경우에는 3회의 연속적인 선택적 용해법과 환원열처리를 통하여 주석 분말의 농도를 97.5 % 이상으로 향상시켰다. 제조된 분말의 FE-SEM 및 TEM 분석을 통하여 미세구조 변화여부를 분석하였다.

Keywords

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