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Formation of Magnetic Graphene Nanosheets for Rapid Enrichment and Separation of Methyl Orange from Water

  • Zhang, Feng-Jun (Anhui Key Laboratory of Advanced Building Materials, Anhui Jianzhu University) ;
  • Zhang, Zhuo (Anhui Key Laboratory of Advanced Building Materials, Anhui Jianzhu University) ;
  • Xie, Fa-Zhi (School of Materials and Chemical Engineering, Anhui Jianzhu University) ;
  • Xuan, Han (School of Materials and Chemical Engineering, Anhui Jianzhu University) ;
  • Xia, Hong-Chen (School of Materials and Chemical Engineering, Anhui Jianzhu University) ;
  • Zhu, Lei (Department of Advanced Materials Science & Engineering, Hanseo University) ;
  • Oh, Won-Chun (Department of Advanced Materials Science & Engineering, Hanseo University)
  • Received : 2013.11.09
  • Accepted : 2014.09.09
  • Published : 2014.11.30

Abstract

Magnetic-graphene nanosheets have been synthesized via a simple effective chemical precipitation method followed by heat treatment. The composite nanosheets are super paramagnetic at room temperature and can be separated by an external magnetic field. The prepared magnetic-graphene nanosheets were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), Raman spectroscopy, and BET surface area analysis. The results demonstrated the successful attachment of iron oxide nanoparticles to graphene nanosheets. It was found that the attached nanoparticles were mainly $Fe_3O_4$. The magnetic-graphene nanosheets showed near complete methyl orange removal within 10 mintues and would be practically usable for methyl orange separation from water.

Keywords

References

  1. C. G. Navarro, M. Burghard, and K. Kern, "Elastic Properties of Chemically Derived Single Graphene Sheets," Nano Lett., 8 [7] 2045-49 (2008). https://doi.org/10.1021/nl801384y
  2. S. J. Park , K. S. Lee, G. Bozoklu , W. W. Cai , S. T. Nguyen, and R. S. Ruoff, "Graphene Oxide Papers Modified by Divalent Ions-Enhancing Mechanical Properties via Chemical Cross-Linking," ACS Nano, 2 [3] 572-78 (2008). https://doi.org/10.1021/nn700349a
  3. J. Wu, W. Pisula, and K. Mullen, "Graphene Molecules as Potential Material for Electronics," Chem. Rev., 107 718-47 (2007). https://doi.org/10.1021/cr068010r
  4. C. G. Navarro, R. T. Weitz, A. M. Bittner, M. Scolari, A. Mews, M. Burghard, and K. Kern, "Electronic Transport Properties of Individual Chemically Reduced Graphene Oxide Sheets," Nano Lett., 7 [11] 3499-503 (2007). https://doi.org/10.1021/nl072090c
  5. A. Balandin, S. Ghosh, W. Z. Bao, I. Calizo, D. Teweldebrhan, F. Miao, and C. N. Lau, "Superior Thermal Conductivity of Single-Layer Graphene," Nano. Lett., 8 [3] 902-07 (2008). https://doi.org/10.1021/nl0731872
  6. J. M. Pereira, P. Vasilopoulos, and F. M. Peeters, "Tunable Quantum Dots in Bilayer Graphene," Nano. Lett., 7 [4] 946-49 (2007). https://doi.org/10.1021/nl062967s
  7. R. Kou, Y. Y. Shao, D. H. Wang, M. H. Engelhard, J. H. Kwak, J. Wang ,V. V. Viswanathan, C. M. Wang, Y. H. Lin, Y. Wang, I. A. Aksay, and J. Liu, "Enhanced Activity and Stability of Pt Catalysts on Functionalized Graphene Sheets for Electrocatalytic Oxygen Reduction," Electrochem. Commun., 11 [5] 954-57 (2009). https://doi.org/10.1016/j.elecom.2009.02.033
  8. H. Zhang, X. J. Lv, Y. M. Li, Y. Wang, and J. H. Li, "P25-Graphene Composite As a High Performance Photocatalyst," ACS Nano., 4 [1] 380-86 (2010). https://doi.org/10.1021/nn901221k
  9. X. H. Kang, J. Wang, H. Wu, I. A. Aksay, J. Liu, and Y. H. Lin, "Glucose Oxidase-Graphene-Chitosan Modified Electrode for Direct Electrochemistry and Glucose Sensing," Biosens. Bioelectron., 25 [4] 901-05 (2009). https://doi.org/10.1016/j.bios.2009.09.004
  10. N. Mohanty and V. Berry, "Graphene-Based Single-Bacterium Resolution Biodevice and DNA Transistor: Interfacing Graphene Derivatives with Nanoscale and Microscale Biocomponents," Nano Lett., 8 [12] 4469-76 (2008). https://doi.org/10.1021/nl802412n
  11. Y. Si and T. S. Edward, "Exfoliated Graphene Separated by Platinum Nanoparticles," Chem. Mater., 20 [21] 6792-97 (2008). https://doi.org/10.1021/cm801356a
  12. R. Muszynski, B. Seger, and P. V. Kamat, "Decorating Graphene Sheets with Gold Nanoparticles," J. Phys. Chem. C, 112 [14] 5263-66 (2008). https://doi.org/10.1021/jp800977b
  13. H. P. Cong, J. J. He, Y. Lu, and S. H. Yu, "Water-Soluble Magnetic-Functionalized Reduced Graphene Oxide Sheets: In situ Synthesis and Magnetic Resonance Imaging Applications," Small, 6 [2] 169-73 (2010). https://doi.org/10.1002/smll.200901360
  14. T. A. Pham, N. A. Kumar, and Y. T. Jeong, "Covalent Functionalization of Graphene Oxide with Polyglycerol and Their Use as Templates for Anchoring Magnetic Nanoparticles," Synth. Met., 160 [17-18] 2028-36 (2010). https://doi.org/10.1016/j.synthmet.2010.07.034
  15. F. He, J. T. Fan, D. Ma, L. M. Zhang, C. Leung, and H. L. Chan, "The Attachment of $Fe_3O_4$ Nanoparticles to Graphene Oxide by Covalent Bonding," Carbon, 48 [11] 3139-44 (2010). https://doi.org/10.1016/j.carbon.2010.04.052
  16. W. S. Hummers and R. E. Offeman, "Preparation of Graphitic Oxide," J. Am. Chem. Soc., 80 [6] 1339-39 (1958). https://doi.org/10.1021/ja01539a017
  17. W. C. Oh, M. L. Chen, K. Zhang, and F. J. Zhang, "The Effect of Thermal and Ultrasonic Treatment on the Formation of Graphene-Oxide Nanosheets," J. Kor. Phys. Soc., 56 [4] 1097-102 (2010). https://doi.org/10.3938/jkps.56.1097
  18. W. C. Oh and F. J. Zhang, "Preparation and Characterization of Graphene Oxide Reduced From a Mild Chemical Method," Asian J. Chem., 23 875-79 (2011).
  19. S. H. Lee, H. W. Kim, J. O. Hwang, W. J. Lee, J. Kwon, C. W. Bielawski, R. S. Ruoff, and S. O. Kim, "Three-Dimensional Self-Assembly of Graphene Oxide Platelets into Mechanically Flexible Macroporous Carbon Films," Angew. Chem. Int. Ed., 49 [52] 10084-88 (2010). https://doi.org/10.1002/anie.201006240
  20. D. De Faria, S. V. Silva, and M. T. de Oliveira, "Raman Microspectroscopy of Some Iron Oxides and Oxyhydroxides," J. Raman Spectrosc., 28 873-78 (1997). https://doi.org/10.1002/(SICI)1097-4555(199711)28:11<873::AID-JRS177>3.0.CO;2-B
  21. P. P. Lottici, D. Bersani, and A. Montenero, "Micro-Raman Investigation of Iron Oxide Films and Powder Produced by Sol-Gel Syntheses," J. Raman Spectrosc., 30 355-60 (1999). https://doi.org/10.1002/(SICI)1097-4555(199905)30:5<355::AID-JRS398>3.0.CO;2-C
  22. C. X. Cong, T. Yu, Z. H. Ni, L. Liu, Z. X. Shen, and W. Huang, "Fabrication of Graphene Nanodisk Arrays Using Nanosphere Lithography," J. Phys. Chem. C, 113 [16] 652-53 (2009).
  23. J. F. Shen, Y. Z. Hu, M. Shi, N. Li, H. W. Ma, and M. X. Ye, "One Step Synthesis of Graphene Oxide-Magnetic Nanoparticle Composite," J. Phys. Chem. C, 114 [3] 1498-503 (2010).

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