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Synthesis and Characterization of CdSe/graphene Nanocomposites and their Catalytic Reusability Studies under Visible Light Radiation

  • Ali, Asghar (Department of Advanced Materials Science & Engineering, Hanseo University) ;
  • Oh, Won-Chun (Department of Advanced Materials Science & Engineering, Hanseo University)
  • Received : 2015.09.05
  • Accepted : 2015.10.27
  • Published : 2015.11.30

Abstract

We examined the photo catalytic activity and catalytic recyclability of CdSe/graphene nanocomposites fabricated via modified hydrothermal technique. The prepared composites were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) with energy dispersive X-ray (EDX), transmission electron microscopy (TEM), Raman spectroscopic analysis, and X-ray photoelectron spectroscopy (XPS). The photocatalytic behavior was investigated through decomposition of RBB as a standard dye under visible light radiation. Our results indicate that there is significant potential for graphene based semiconductor hybrids materials to be used as photocatalysts under visible light irradiation for the degradation of organic dyes from industry effluents.

Keywords

References

  1. K. Selvam, K. Swaminathan, and K. S. Chae, "Microbial Decolorization of Azo Dyes and Dye Industry Effluent by Fomes lividus," World J. Microbiol. Biotechnol., 19 591-93 (2003). https://doi.org/10.1023/A:1025128327853
  2. R. Vinu. and M. Madras "Photocatalytic Activity of Ag-substituted and Impregnated Nano-$TiO_2$," G. Environ. Sci. Technol., 336 130-40 (2009).
  3. L. B. Reutergardh and M. Iangphasuk, "Photocatalytic Decolorization of Reactive Azo Dye: a Comparison between $TiO_2$ and CdS Photocatalysis," Chemosphere., 35 585-96 (1997). https://doi.org/10.1016/S0045-6535(97)00122-7
  4. K. Ullah, L. Zhu, Z. D. Shu, Y. Q. Sun, and W.-C. Oh, "A Facile and Fast Synthesis of Novel Composite Pt-Graphene/$TiO_2$ with Enhanced Photocatalytic Activity under UV/Visible Light," Chem. Eng. J., 231 76-83 (2013). https://doi.org/10.1016/j.cej.2013.07.014
  5. L. Zhu and W. C. Oh, "Review of Semiconductor/Reduced Graphene Oxide Nanocomposites; Fabrication, Characterization and application of Decontamination of Organic Dyes," J. Multifunct. Mater. Photosci., 5 [2] 153-70 (2014).
  6. L. X. Yang, S. L. Luo, and Q. Y. Cai, Y. Xiao, and S. H. Liu, "Fabrication of CdSe Nanoparticles Sensitized Long $TiO_2$ Nanotube Arrays for Photocatalytic Degradation of Anthracene-9-Carbonxylic Acid under Green Monochromatic Light," J. Phys. Chem. C, 114 4783-89(2010).
  7. T. Kai-An and Y.-J. Hsu "Graphene Quantum Dots Mediated Charge Transfer of CdSe Nanocrystals for Enhancing Photo Electrochemical Hydrogen Production," Applied Catalysis B: Environmental., 164 271-78 (2015). https://doi.org/10.1016/j.apcatb.2014.09.034
  8. K. Ullah, S. Ye, S.-B. Jo, L. Zhu, K.-Y. Cho, and W.-C. Oh, "Optical and Photocatalytic Properties of Novel Heterogeneous $PtSe_2$-Graphene/$TiO_2$ Nanocomposites Synthesized via Ultrasonic Assisted Techniques," Ultrasonics Sonochemistry, 21 1849-57 (2014). https://doi.org/10.1016/j.ultsonch.2014.04.016
  9. C. S. Lim, M. L. Chen, and W. C. Oh, "Synthesis of CdSe-$TiO_2$ Photocatalyst and their Enhanced Photocatalytic Activities under UV and Visible Light," Korean Chem. Soc., 32 1657-61 (2011). https://doi.org/10.5012/bkcs.2011.32.5.1657
  10. K. S. Novoselov, A. K. Geim, S. V. Morozov, D. Jiang, Y. Zhang, S. V. Dubonos, I. V. Grigorieva, and A. A. Firsov, "Electric Field Effect in Atomically Thin Carbon Films," Science, 306 666-69 (2004). https://doi.org/10.1126/science.1102896
  11. L. Zhu, S.-B. Jo, S. Ye, K. Ullah, Z.-D Meng, and W.-C. Oh, "A Green and Direct Synthesis of Photosensitized $CoS_2$-Graphene/$TiO_2$ Hybrid with High Photocatalytic Performance," J. Ind. Eng. Chem., 22 264-71 (2015). https://doi.org/10.1016/j.jiec.2014.07.019
  12. W. W. Cai, R. D. Piner, F. J. Stadermann, S. Park, M. A. Shaibat, Y. Ishii, D. X. Yang, A. Velamakanni, S. J. An, M. Stoller, J. An, D. Chen, and R. S. Ruoff, "Synthesis and Solid-State NMR Structural Characterization of 13CLabeled Graphite Oxide," Science, 321 1815-17 (2008). https://doi.org/10.1126/science.1162369
  13. T. Wang, S. Y. Zhang, C. J. Mao, J. M. Song, H. L. Niu, B. K. Jin, and Y. P. Tian, "Enhanced Electrochemi Luminescence of CdSe Quantum Dots Composited with Graphene Oxide and Chitosan for Sensitive Sensor," Tian, Biosens. Bioelectron., 31 369-75 (2012). https://doi.org/10.1016/j.bios.2011.10.048
  14. C. Berger, Z. M. Song, T. B. Li, X. B. Li, A. Y. Ogbazghi, R. Feng, Z. T. Dai, A. N. Marchenkov, E. H. Conrad, P. N. Frist, and W. A. Heer, "Graphene Multilayers are Grown Epitaxially on Single Crystal Silicon," J. Phys. Chem. B, 108 19912-16 (2004). https://doi.org/10.1021/jp040650f
  15. Q. Guo and X. Qin, "Flower-like $SnO_2$ Nanoparticles Grown on Graphene as Anode Materials for Lithium-Ion Batteries," J. Solid State Electrochem., 18 1031-39 (2014). https://doi.org/10.1007/s10008-013-2352-4
  16. A. M. Wang, H. L. Wang, S. Y. Zhang, C. J. Mao, J. M. Song, H. L. Niu, B. K. Jin, and Y. P. Tian, "Controlled Synthesis of Nickel Sulfide/Graphene Oxide Nanocomposite for High-Performance Supercapacitor," Appl. Surf. Sci., 282 704-8 (2013). https://doi.org/10.1016/j.apsusc.2013.06.038
  17. Y. T. Yan, Q. Liu, K. Wang, L. Jiang, X. W. Yang, J. Qian, X. Y. Dong, and B. J. Qiu, "Enhanced Peroxydisulfate Electrochemiluminescence for Dopamine Biosensing Based on Au Nanoparticle Decorated Reduced Graphene Oxide," Analyst, 138 7101-6 (2013). https://doi.org/10.1039/c3an01533e
  18. Q. J. Xiang, J. G. Yu, and M. Jaronie, "Graphene-based Semiconductor Photocatalysts," Chem. Soc. Rev., 41 782-96 (2012). https://doi.org/10.1039/C1CS15172J
  19. Q. Li, B. D. Guo, J. G. Yu, J. R. Ran, B. H. Zhang, H. J. Yan, and J. R. Gong, "Highly Efficient Visible-Light-Driven Photocatalytic Hydrogen Production of CdS-Cluster-Decorated Graphene Nanosheets," J. Am. Chem. Soc., 133 [28] 10878-84 (2011). https://doi.org/10.1021/ja2025454
  20. Q. J. Xiang, J. G. Yu, and M. Jaroniec, "Synergetic Effect of $MoS_2$ and Graphene as Cocatalysts for Enhanced Photocatalytic $H_2$ Production Activity of $TiO_2$ Nanoparticles," J. Am. Chem. Soc., 134 [15] 6575-78(2012). https://doi.org/10.1021/ja302846n
  21. K. Ullah, S. Ye, S.-B. Jo, L. Zhu, K.-Y. Cho, and W.-C. Oh, "Synergistic Effect of $PtSe_2$ and Graphene Sheets Supported by $TiO_2$ as Co-catalysts Synthesized via Microwave Techniques for Improved Photocatalytic Activity," Catal. Sci. Technol., 5 184-98 (2015).. https://doi.org/10.1039/C4CY00886C
  22. K. Ullah, S. Ye, S.-B. Jo, L. Zhu, K.-Y. Cho, and W.-C. Oh, "Optical and Photocatalytic Properties of Novel Heterogeneous $PtSe_2$-Graphene/$TiO_2$ Nanocomposites Synthesized via Ultrasonic Assisted Techniques," Ultrason. Sonochem., 21 1849-57 (2014). https://doi.org/10.1016/j.ultsonch.2014.04.016
  23. K. Ullah, A. Ali, S. Ye, L. Zhu, and W. C. Oh, "Microwave-Assisted Synthesis of Pt-Graphene/$TiO_2$ Nanocomposites and their Efficiency in Assisting Hydrogen Evolution from Water in the Presence of Sacrificial Agents," Sci. Adv. Mater., 7 [4] 606-14 (2015). https://doi.org/10.1166/sam.2015.2135
  24. W.-C. Oh and F. J. Zhang, "Preparation and Characterization of Graphene Oxide Reduced from a Mild Chemical Method," Asian J. Chem., 23 875 (2011).
  25. M. L. Chen, C. Y. Park, J. G. Choi, and W. C. Oh, "Synthesis and Characterization of Metal (Pt, Pd and Fe)-graphene Composites," J. Korean Ceram. Soc., 48 [2] 147-51 (2011). https://doi.org/10.4191/KCERS.2011.48.2.147
  26. T. Ghosh, K. Ullah, V. Nikam, C. Y. Park, Z. D. Meng, and W.-C. Oh, "The Characteristic Study and Sonocatalytic Performance of CdSe-Graphene as Catalyst in the Degradation of Azo Dyes in Aqueous Solution under Dark Conditions," Ultrason. Sonochem., 20 [2] 768-76 (2013). https://doi.org/10.1016/j.ultsonch.2012.09.005
  27. Q. Li, B. D. Guo, J. G. Yu, J. R. Ran, B. H. Zhang, H. J. Yan, J. R. Gong, "Highly Efficient Visible-Light-Driven Photocatalytic Hydrogen Production of CdS-Cluster-Decorated Graphene Nanosheets" J. Am. Chem. Soc., 133 [28] 10878-84 (2011). https://doi.org/10.1021/ja2025454
  28. Q. J. Xiang, J. G. Yu, and M. Jaroniec, "Preparation and Enhanced Visible-Light Photocatalytic $H_2$-Production Activity of Graphene/$C_3N_4$ Composites," J. Phys. Chem. C, 115 [5] 7355-63 (2011). https://doi.org/10.1021/jp200953k
  29. S. A. Vanalakar, S. S. Mali, R. C. Pawar, N. L. Tarwal, A. V. Moholkar, J. A. Kim, Y.-B. Kwon, J. H. Kim, and P. S. Patil, "Synthesis of Cadmium Sulfide Spongy Balls with Nanoconduits for Effective Light Harvesting," Electrochem. Acta, 56 [6] 2762-68 (2011). https://doi.org/10.1016/j.electacta.2010.12.080
  30. A. Benayad, H. J. Shin, H. K. Park, S. M. Yoon, K. K. Kim, M. H. Jin, H. K. Jeong, J. C. Lee, J. Y. Choi, and Y. H. Lee, "Controlling Work Function of Reduced Graphite Oxide with Au-ion Concentration," Chem. Phys. Lett., 475 91-5 (2009). https://doi.org/10.1016/j.cplett.2009.05.023
  31. K. Ullah, L. Zhu, Y. Shu, A. Ali, and W.-C. Oh, "Microwave Synthesis of $CoSe_2$/Graphene-$TiO_2$ Heterostructure for Improved Hydrogen Evolution from Aqueous Solution in the Presence of Sacrificial Agents," RSC Adv., 18841-49 (2015).
  32. T. Ghosh, K. Ullah, V. Nikam, C.-Y. Park, Z.-D. Meng, and W.-C. Oh, "The Characteristic Study and Son Catalytic Performance of CdSe-Graphene as Catalyst in the Degradation of Azo Dyes in Aqueous Solution under Dark Conditions," Ultrason. Sonochem., 768-76 (2013).
  33. L .Z. Du and Y. Lei, "Synthesis and Photovoltaic Characteristic of n-type CdSe Nanobelts," Mater. Lett., 106 100-3 (2013). https://doi.org/10.1016/j.matlet.2013.04.107
  34. N. Zhang and Y. J. Xu, "Synthesis of Graphene-ZnO Nanorod Nanocomposites with Improved Photoactivity and Antiphotocorrosion," Cryst. Eng. Comm., 15 [8] 3022-30 (2013). https://doi.org/10.1039/c3ce27021a