한국수소및신에너지학회논문집 (Transactions of the Korean hydrogen and new energy society)

  • 제26권6호
  • /
  • Pages.507-515
  • /
  • 2015
  • /
  • 1738-7264(pISSN)
  • /
  • 2288-7407(eISSN)
한국수소및신에너지학회 (The Korean Hydrogen and New Energy Society)
권호 표지
DOI QR코드

DOI QR Code

Ni 기반 촉매를 이용한 HI 분해 반응 특성

Characteristics of Hydrogen Iodide Decomposition using Alumina-Supported Ni Based Catalyst

  • KIM, JI HYE (Hydrogen Laboratory, Korea Institute of Energy Research) ;
  • PARK, CHU SIK (Hydrogen Laboratory, Korea Institute of Energy Research) ;
  • KIM, CHANG HEE (Hydrogen Laboratory, Korea Institute of Energy Research) ;
  • KANG, KYOUNG SOO (Hydrogen Laboratory, Korea Institute of Energy Research) ;
  • JEONG, SEONG UK (Hydrogen Laboratory, Korea Institute of Energy Research) ;
  • CHO, WON CHUL (Hydrogen Laboratory, Korea Institute of Energy Research) ;
  • KIM, YOUNG HO (Department of Applied Chemical and Biological Engineering, Chung-nam university) ;
  • BAE, KI KWANG (Hydrogen Laboratory, Korea Institute of Energy Research)
  • 투고 : 2015.11.30
  • 심사 : 2015.12.30
  • 발행 : 2015.12.30
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

HI decomposition reaction requires a catalyst for the efficient production of hydrogen as a key reaction for hydrogen production in sulfur-iodine thermochemical water-splitting (SI) cycle. As a catalyst used in the reaction, the performance of platinum catalyst is excellent. While, the platinum catalyst is not economical. Therefore, studies of a nickel catalyst that could replace platinum have been carried out. In this study, the characteristics of the catalytic HI decomposition on the amount of loaded nickel (Ni = 0.1, 0.5, 1, 3, 5, 10 wt%) were investigated. As the supported Ni amount increased up to 3 wt%, HI decomposition was found to increase in linear proportion. However, the conversion of $Ni/Al_2O_3$ catalyst loaded above 3 wt% was not linear. It was thought that the different HI decomposition characteristics was caused in the size and metal dispersion of Ni particles of catalyst. The physical property of catalyst before and after HI decomposition reaction was characterized by BET, chemisorption, XRD and SEM analysis.

키워드

참고문헌

  1. X Lin, Y Zhang "Hydrogen production by HI decomposition over nickel-ceria-zirconia catalysts via the sulfur-iodine thermochemical water-splitting cycle". Energy Conversion and Management. vol. 84, 2014. pp.664-670. https://doi.org/10.1016/j.enconman.2014.04.074
  2. J. E. Funk, "Thermochemical production of hydrogem via multistage water splitting process", International Journal of Hydrogen Energy, Vol. 1, 1976. pp. 33-43.
  3. K. Onuki, Y. Inagaki, R. Hido, and Y. Tachibana, "Research and development on nuclear hydrogen production using HTGR at JAERI", Progress in Nuclear Energy, 47, 2005, p. 496. https://doi.org/10.1016/j.pnucene.2005.05.050
  4. D. O'keefe, C. Allen, G, Besenbruch, L. Browon, J. Norman, and R. Sharp, "Preliminary results from bench-scale testing of a sulfur-iodine thermochemical water-splitting cycle", Int hydrogen Energy, 7, 1982, p. 381. https://doi.org/10.1016/0360-3199(82)90048-9
  5. K. D. Jung "Thermochemical Cycle for Hydrogen Production", Prospectives of Industrial Chemistry, Vol. 9, No. 4, 2006, pp. 15-22.
  6. I. Iida, Z. phys. Chem. N. F., 1978, 109, 221.
  7. Y. shindo. "Kinetics of the catalytic decomposition of hydrogen iodide in the thermochemical hydrogen production", Hydrogen energy, Vol 9, No 8, 1984, pp. 695-700. https://doi.org/10.1016/0360-3199(84)90267-2
  8. Z. C. Wang, L. J. Wang, P. Zhang, S. Z. Chen, J. M. Xu, J. Chen, "Effect of preparation methods on Pt/alumina catalysts for the hydrogen iodide catalytic decomposition", Chinese Chmical Letters, Vol 20, 2009 pp. 102-105. https://doi.org/10.1016/j.cclet.2008.09.059
  9. L Wang, Q Han, D Li, Z Wang, J Chen. Comparisons of Pt catalysts supported on active carbon, carbon molecular sieve, carbon nanotubes and graphite for HI decomposition at different temperature. Vol 38, 2013 p. 109. https://doi.org/10.1016/j.ijhydene.2012.10.052
  10. Y. K. Ko, C. S. Park, K.S. Kang, K. K. Bea, and Y. h. Kim, "Effect of Support in HI Decomposition Reaction using Pt Catalyst", Trans. of the Korea Hydrogen and New Energy Society, Vol 22, No. 4, 2011, pp. 415-423.
  11. P. Favuzza, C. Felici, M. Lanchi, R. Liberatore, C.V. Mazzocchia, A. Spadoni, P. Tarquini, A.C. Tito, Int. J. Hydrogen Energy, 34, 4049, 2009. https://doi.org/10.1016/j.ijhydene.2008.07.076
  12. Y Zhang, J Zhou, Y Chen, Z Wang. hydrogen iodide decomposition over nickel-ceria catalysts for hydrogen production in the sulfur-iodine cycle. Vol 33, 2008. pp. 5477-5483. https://doi.org/10.1016/j.ijhydene.2008.07.007
  13. S. Y. Kim, Y. K. Ko, C. S. Park, K.S. Kang, K. K. Bea, and Y. h. Kim, "Characteristics of Hydrogen Iodide Decomposition using Ni-Pt Bimetallic Catalyst in Sulfur-Iodine Process", Trans. of the Korea Hydrogen and New Energy Society, Vol 23, No. 1, 2012, pp. 1-7. https://doi.org/10.7316/khnes.2012.23.1.001
  14. D Li, L Wang, P Zhang, S Chen, J Xu. HI decomposition over active carbon supported binary Ni-Pd catalysts prepared by electroless plating. Vol 38, 2013 pp. 32-35.
  15. D Li, L Wang, P Zhang, S Chen, J Xu. HI decomposition over PtNi/C bimetallic catalysts prepared by electroless plating. Vol 38, 2013, pp. 10839-10844. https://doi.org/10.1016/j.ijhydene.2013.01.014
  16. P. Betancourt. Rivesb, R. Hubautb, C.E. Scotta, J. Goldwasser "A study of the ruthenium${\pm}$alumina system". Applied Catalysis A: General 170, 1998, pp. 307-314. https://doi.org/10.1016/S0926-860X(98)00061-1
  17. E. J. Park, Y. K. Ko, C. S. Park, K.S. Kang, K. K. Bea, and Y. h. Kim, "The Characteristics of HI Decomposition using Pt/Al2O3 Catalyst Heat Treated in Air and Hydrogen Atmosphere". Trans. of the Korea Hydrogen and New Energy Society. vol.25, 2014. pp. 219-226. https://doi.org/10.7316/KHNES.2014.25.3.219
  18. C. H. bartholomew, R. B. pannell. The stoichiometry of hydrogen and carbon monoxide chemisorption on alumina- and silica-supported nickel. 65, 390-401, 1980. https://doi.org/10.1016/0021-9517(80)90316-4

피인용 문헌

  1. supported Ni in the HI Decomposition of Sulfur-Iodine Process vol.67, pp.2261-236X, 2016, https://doi.org/10.1051/matecconf/20166706063