DOI QR코드

DOI QR Code

Effect of Graphite Intercalation Compound on the Sound Absorption Coefficient and Sound Transmission Loss of Epoxy Composites

그라파이트 인터칼레이션 컴파운드가 에폭시 복합재료의 흡·차음성에 미치는 영향

  • Lee, Byung-Chan (Department of Environmental Engineering, Korea National University of Transportation) ;
  • Park, Gyu-Dae (Department of Polymer Science and Engineering, Korea National University of Transportation) ;
  • Choi, Sung-Kyu (Department of Green Bio Engineering, Graduate School, Korea National University of Transportation) ;
  • Kim, Sung-Ryong (Department of Polymer Science and Engineering, Korea National University of Transportation)
  • Received : 2015.11.23
  • Accepted : 2015.12.22
  • Published : 2015.12.31

Abstract

The sound absorption coefficient and sound transmission loss of graphite intercalation compound (GIC) included epoxy composites were investigated. Epoxy resin was infused into the expanded GIC and the impedance tube method was employed to measure the sound absorption coefficient and sound transmission loss. Scanning electron microscopy photographs showed uniform distribution of the GIC in the epoxy matrix. The surface density of epoxy/GIC (20 wt%) composites decreased about 56% compared to that of pure epoxy. The sound absorption coefficient of composites increased about 3 times at the frequency range of 500~1000 Hz compared to the pure epoxy. The sound transmission loss of composites decreased with increasing the GIC content and it is attributed to the increase of pores in the composites.

팽창된 그라파이트 인터칼레이션 컴파운드에 에폭시 수지를 주입하여 제조한 복합재료의 흡 차음성을 연구하였다. 관내법을 이용하여 복합재료의 흡음률과 음향투과손실을 측정하였다. 주사전자현미경을 이용하여 에폭시 매트릭스 내부에 그라파이트 인터칼레이션 컴파운드가 무질서한 방향으로 균일하게 분산된 것을 확인하였다. 그라파이트 인터칼레이션 컴파운드 함량이 증가함에 따라 복합재료의 면밀도가 감소하였으며, epoxy/(GIC 20 wt%) 복합재료의 면밀도는 순수 에폭시에 비하여 56% 감소하였다. 500~1000 Hz 주파수 영역에서 복합재료의 흡음률은 순수 에폭시에 비해 3배 정도 증가하였다. 그라파이트 인터칼레이션 컴파운드의 함량이 증가함에 따라 복합재료에 포함된 기공의 비율이 증가하여 순수 에폭시에 비하여 복합재료의 음향투과손실이 감소하는 것으로 판단된다.

Keywords

References

  1. Choi, J.W. and Hwang, Y., "Preparation and Sound Insulation Properties of Thermoplastic Elastomer Composites with $CaCO_3$ Filler", Korean Journal of Materials Research, Vol. 20, Issue. 9, 2010, pp. 467-471. https://doi.org/10.3740/MRSK.2010.20.9.467
  2. ASTM C384-04, "Standard Test Method for Impedance and Absorption of Acoustical Materials by Impedance Tube Method", 2011.
  3. Seybert, A.F. and Ross, D.F., "Experimental Determination of Acoustic Properties Using a Two-microphone Random-Excitation Technique", Journal of the Acoustical Society of America, Vol. 61, No. 5, 1977, pp. 1362-1370. https://doi.org/10.1121/1.381403
  4. Jung, S.S. and Hwang, C.H., "A Study on the Acoustical Characteristics of the Absorbent Materials Using Two Microphones", Transactions of the Korean Society for Noise and Vibration Eng., Vol. 6, No. 2, 1996, pp. 225-231.
  5. KS F 2814-1, Determination of Sound Absorption Coefficient and Impedance in Impedance Tubes Part 1: Method Using Standing Wave Ratio, 2001.
  6. Wang, X., You, F., Zhang, F.S., Li, J., and Guo, S.Y., "Experimental and Theoretic Studies on Sound Transmission Loss of Laminated Mica-Filled Poly(vinyl chloride) Composites", Journal of Applied Polymer Science, Vol. 122, No. 2, 2011, pp. 1427-1433. https://doi.org/10.1002/app.34047
  7. Lee, C.M. and Kim, D.R., "A Measuring Technology of the Absorption Ratio and the Transmission Loss Using the Tube Method," Transactions of the Korean Society for Noise and Vibration Engineering, 1998, pp. 659-663.
  8. Jung, S.S., Kim, Y.T., Lee, Y.B., Cho, S.I. and Lee, J.K., "Measurement of Sound Transmission Loss by Using Impedance Tubes," Journal of the Korean Physical Society, Vol. 53, No. 2, 2008, pp. 596-600. https://doi.org/10.3938/jkps.53.596
  9. Scott, R.A., The Absorption of Sound in a Homogeneous Porous Medium, Proceedings of the Physical Society, UK, Vol. 58, 1946.
  10. Lee, B.C. and Kim, S.R., "Effect of Structure on the Sound Absorption and Sound Transmission Loss of Composite Sheet", Journal of the Korean Society for Composite Materials, Vol. 25, No. 5, 2012, pp. 154-158. https://doi.org/10.7234/kscm.2012.25.5.154
  11. Kim, S.R., Poostforush, M., Kim, J.H. and Lee, S.G., "Thermal Diffusivity of in-situ Exfoliated Graphite Intercalated Compound/Polyamide and Graphite/Polyamide Composites", eXPRESS Polymer Letters Vol. 6, No. 6, 2012, pp. 476-484. https://doi.org/10.3144/expresspolymlett.2012.50
  12. Kim, J.S., Noise and Vibration, Sejin Publishing, Korea, 2007.
  13. Norton, M.P., Fundamentals of Noise and Vibration Analysis for Engineers, Cambridge University Press, USA, 1989.
  14. Corsaro, R.D. and Sperling, L.H. ed., Sound and Vibration Damping with Polymers, American Chemical Society, USA, 1990.