Textile Coloration and Finishing (한국염색가공학회지)

The Korean Society of Dyers and Finishers (한국염색가공학회)
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Study on the Interaction between Curcumin and Ethylamines by Absorption and Fluorescence Spectroscopic Techniques

  • Kim, Sung Hoon (Department of Textile System Engineering, Kyungpook National University) ;
  • Gwon, Seon Yeong (Department of Textile System Engineering, Kyungpook National University) ;
  • Lee, Eun-Mi (FITI Testing and Research Institute) ;
  • Bae, Jin-Seok (Department of Textile System Engineering, Kyungpook National University)
  • Received : 2015.09.23
  • Accepted : 2015.12.09
  • Published : 2015.12.27
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Abstract

The interaction between curcumin(1,7-bis[4-hydroxy-3-methoxyphenyl]-1,6-heptadiene-3,5-dione) and ethylamines was studied in DMSO:$H_2O$(5:1, v/v) using absorption and fluorescence measurements. The association constant, $K_{ass}$, and the Stern-Volmer constants were calculated by the Benesi-Hildebrand and Stern-Volmer equation, respectively. Curcumin displayed marked UV-Vis absorption changes and highly responsive fluorescence quenching in the presence of ethylamine and the quenching ability was enhanced almost linearly with the concentration of ethylamines. The apparent Stern-Volmer constant measured for the ethylamine-curcumin system was about 1000-fold greater than that of the triethylamine-curcumin system, indicating considerably greater quenching efficiency of ethylamines.

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References

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