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The relationship between minority carrier life time and structural defects in silicon ingot grown with single seed

  • Lee, A-Young (Department of Advanced Materials Science and Engineering, Incheon National University) ;
  • Kim, Young-Kwan (Department of Advanced Materials Science and Engineering, Incheon National University)
  • Received : 2015.01.21
  • Accepted : 2015.02.06
  • Published : 2015.02.28

Abstract

Among the various possible factors affecting the Minority Carrier Life Time (MCLT) of the mc-Si crystal, dislocations formed during the cooling period after solidification were found to be a major element. It was confirmed that other defects such as grain boundary or twin boundary were not determinative defects affecting the MCLT because most of these defects seemed to be formed during the solidification period. With a measurement of total thickness variation (TTV) and bow of the silicon wafers, it was found that residual stress remaining in the mc-Si crystal might be another major factor affecting the MCLT. Thus, it is expected that better quality of mc-Si can be grown when the cooling process right after solidification is carried out as slow as possible.

Keywords

References

  1. B. Gao, X.J. Chen, S. Nakano and K. Kakimoto, "Crystal growth of high-purity multicrystalline silicon using a unidirectional solidification furnace for solar cells", J.Crystal Growth 312 (2010) 1572. https://doi.org/10.1016/j.jcrysgro.2010.01.034
  2. X. Gu, X. Yu, K. Guo, L. Chen, D. Wang and D. Yang, "Seed-assisted cast quasi-single crystalline silicon for photovoltaic application: Towards high efficiency and low cost silicon solar cells", Solar Energy Materials & Solar Cells 101 (2012) 95. https://doi.org/10.1016/j.solmat.2012.02.024
  3. A.Y. Lee, D.G. Lee and Y.K. Kim, "The current status in the silicon crystal growth technology for solar cells", J. Korean Cryst. Growth Cryst. Technol. 24 (2014) 47. https://doi.org/10.6111/JKCGCT.2014.24.2.047
  4. J.D. Zook, "Effects of grain boundaries in polycrystalline solar cells", Applied Physics Letters 37 (1980) 223. https://doi.org/10.1063/1.91832
  5. H.J. Moller, C. Funke, M. Rinio and S. Scholz, "Multicrystalline silicon for solar cells", Thin Solid Films 487 (2005) 179. https://doi.org/10.1016/j.tsf.2005.01.061
  6. J.W. Shur, J.H. Hwang, Y.J. Kim, S.J. Moon, W.W. So and D.H. Yoon, "Simulation by heat transfer of ADS process for large sized polycrystalline silicon ingot growth", J. Korean Cryst. Growth Cryst. Technol. 18 (2008) 45.
  7. N. Chen, S. Qiu, B. Liu, G. Du, G. Liu and W. Sun, "An optical microscopy study of dislocations in multicrystalline silicon grown by directional solidification method", Materials Science in Semiconductor Processing 13 (2010) 276. https://doi.org/10.1016/j.mssp.2010.12.006
  8. A.Y. Lee and Y.K. Kim, "Structural defects in the multicrystalline silicon ingot grown with the seed at the bottom of crucible", J. Korean Cryst. Growth Cryst. Technol. 24 (2014) 190. https://doi.org/10.6111/JKCGCT.2014.24.5.190
  9. K. Fujiwara, W. Pan, N. Usami, K. Sawada, M. Tokairin, Y. Nose, A. Nomura, T. Shishido and K. Nakajima, "Growth of structure-controlled polycrystalline silicon ingots for solar cells by casting", Acta Materialia 54 (2006) 3191. https://doi.org/10.1016/j.actamat.2006.03.014
  10. H.J. Su, J. Zhang, L. Liu and H.Z. Fu, "Preparation, microstructure and dislocation of solar-grade multicrystalline silicon by directional solidification from metallurgical- grade silicon", Trans. Nonferrous Met. Soc. China 22 (2012) 2548. https://doi.org/10.1016/S1003-6326(11)61499-4
  11. K. Jiptner, M. Fukuzawa, Y. Miyamura, H. Harada, K. Kakimoto and T. Sekiguchi, "Evaluation of residual strain in directional solidified mono-Si ingots", Phys. Status Solidi C No. 1 10 (2013) 141. https://doi.org/10.1002/pssc.201200884
  12. G. Stokkan, "Relationship between dislocation density and nucleation of multicrystalline silicon", Acta Materialia 58 (2010) 3223. https://doi.org/10.1016/j.actamat.2010.01.042
  13. M.G. Tsoutsouva, V.A. Oliveira, D. Camel, T.N. Tran Thi, J. Baruchel, B. Marie and T.A. Lafford, "Segregation, precipitation and dislocation generation between seeds in directionally solidified mono-like silicon for photovoltaic applications", J. Crystal Growth 401 (2014) 397. https://doi.org/10.1016/j.jcrysgro.2013.12.022

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