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Structural characteristics of [N(CH3)4]2CdCl4 determined by 1H MAS NMR, 13C CP/ MAS NMR, and 14N NMR

  • Lee, Seung Jin (Department of Carbon Fusion Engineering, Jeonju University) ;
  • Lim, Ae Ran (Department of Science Education, Jeonju University)
  • Received : 2015.03.27
  • Accepted : 2015.05.14
  • Published : 2015.06.30

Abstract

The structural geometry of $[N(CH_3)_4]_2CdCl_4$ in a hexagonal phase is studied by $^1H$ MAS NMR, $^{13}C$ CP/MAS NMR, and $^{14}N$ NMR. The changes in the chemical shifts for $^{13}C$ and $^{14}N$ in the hexagonal phase are explained by the structural geometry. In addition, the temperature dependencies of the spin-lattice relaxation time in the rotating frame $T_{1{\rho}}$ for $^1H$ MAS NMR and $^{13}C$ CP/MAS NMR are measured.

Keywords

Acknowledgement

Supported by : National Research Foundation of Korea (NRF)

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