DOI QR코드

DOI QR Code

Effect of Ca Addtion on Microstructure and Mechanical Properties of Mg-11Li-3Zn-1Sn-0.4Mn Based Alloys

Mg-11Li-3Zn-1Sn-0.4Mn 마그네슘 합금의 Ca 첨가에 따른 미세조직 및 기계적 특성평가

  • Received : 2015.04.07
  • Accepted : 2015.05.21
  • Published : 2015.06.27

Abstract

The effect of adding Ca on the microstructural and mechanical properties of as-cast Mg-11Li-3Zn-1Sn(wt%) alloys were investigated. Mg-11Li-3Zn-1Sn-0.4Mn with different Ca additions (0.4, 0.8, 1.2 wt%) were cast under an $SF_6$ and $Co_2$ atmosphere at $720^{\circ}C$. The cast billets were homogenized at $400^{\circ}C$ for 12h and extruded at $200^{\circ}C$. The microstructural and mechanical properties were analyzed by OM, XRD, SEM, and tensile tests. The addition of Ca to the Mg-11Li-3Zn-1Sn-0.4Mn alloy resulted in the formation of $Ca_2Mg_6Zn_3$, MgSnCa intermetallic compound. By increasing Ca addition, the volume fraction and size of $Ca_2Mg_6Zn_3$ with needle shape were increased. This $Ca_2Mg_6Zn_3$ intermetallic compound was elongated to the extrusion direction and refined to fine particles due to severe deformation during hot extrusion. The elongation of the 0.8 wt% Ca containing alloy improved remarkably without reduction strength due to the formation of fine grain and $Ca_2Mg_6Zn_3$ intermetallic compounds by Ca addition. It is probable that fine and homogeneous $Ca_2Mg_6Zn_3$ intermetallic compounds played a significant role in the increase of mechanical properties.

Keywords

References

  1. A. Kozlov, M. Ohno, T. Abu Leil, N. Hort, K. U. Kainer and R. Schmid-Fetzer, Intermetallics, 16(2), 316 (2008). https://doi.org/10.1016/j.intermet.2007.10.011
  2. M. Gheisari, M. Mozaffari, M. Acet and J. Amighian, J. Magn. Magn. Mater., 320(21), 2618 (2008). https://doi.org/10.1016/j.jmmm.2008.05.028
  3. A. Kozlov, M. Ohno, R. Arroyave, Z. K. Liu and R. Schmid-Fetzer, Intermetallics, 16(2), 299 (2008). https://doi.org/10.1016/j.intermet.2007.10.010
  4. T. Abu Leil, N. Hort, W. Dietzel, C. Blawert, Y. Huang, K. U. kainer and K. P. Rao, Trans. Nonferrous Met. Soc. China, 19(1), 40 (2009). https://doi.org/10.1016/S1003-6326(08)60225-3
  5. Y. H. Kim, J. H. Kim, H. S. Yoo, J. W. Choi and H. T. Son, J. Alloys Compd., 583, 15 (2014). https://doi.org/10.1016/j.jallcom.2013.08.154
  6. H. T. Son, Y. H. Kim, D. W. Kim, J. H. Kim and H. S. Yoo, J. Alloys Compd., 564, 130 (2014).
  7. L. B. Tong, M. Y. Zheng, S. W. Xu, S. Kamado, Y. Z. Du, X. S. Hu, W. M. Gan, H. G. Brokmeier, G. J. Wamg and X. Y. Lv, Mater. Sci. Eng. A, 528(10), 3741 (2011). https://doi.org/10.1016/j.msea.2011.01.037
  8. S. S. Park and B. S. You, Scripta Mater., 65(3), 202 (2011). https://doi.org/10.1016/j.scriptamat.2011.04.005
  9. J. P. Eom, S. G. Lim and B. Y. Hur, J. Korean Foundrumen's Soc., 20(6), 395 (2000).
  10. J. P. Eom, S. G. Lim and B. Y. Hur, J. Korean Foundrumen's Soc., 19(1), 7 (1999).
  11. H. T. Son, T. J. Konno, H. G. Jung and J. B. Lee, Mater. Lett., 65(12), 1966 (2011). https://doi.org/10.1016/j.matlet.2011.03.083
  12. W. W. Park and B. S. You, J. Korean Foundrumen's Soc., 19(15), 377 (1999).
  13. W. C. Kim, J. H. Park, W. W. Park and B. S. You, J. Korean Foundrumen's Soc., 19(5), 433 (1999).