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님 또는 고삼추출물을 주원료로 하는 작물병해충 관리용 유기농업자재의 유효성분 열 안정성

Stability of Representative Active Compounds on Commercial Biopesticides Based on Neem or Sophora flavescens Extract Under Controlled Temperature

  • 김진효 (농촌진흥청 국립농업과학원 화학물질안전과) ;
  • 최근형 (농촌진흥청 국립농업과학원 화학물질안전과) ;
  • 강재은 (화학물질안전원 사고예방심사과) ;
  • 박병준 (농촌진흥청 국립농업과학원 화학물질안전과)
  • Kim, Jin Hyo (Chemical Safety Division, National Academy of Agricultural Science, RDA) ;
  • Choi, Geun-Hyoung (Chemical Safety Division, National Academy of Agricultural Science, RDA) ;
  • Kang, Jae-Eun (Accident Prevention and Assessment Division, National Institute of Chemical Safety) ;
  • Park, Byung-Jun (Chemical Safety Division, National Academy of Agricultural Science, RDA)
  • 투고 : 2015.03.19
  • 심사 : 2015.06.01
  • 발행 : 2015.06.30

초록

님 추출물 또는 고삼 추출물을 주원료로 하는 유기농업자재의 유효성분인 limonoid계 4성분 (azadirachtin A, azadirachtin B, deacetylsalannin, salannin)과 alkaloid계 2성분 (matrine, oxymatrine)을 중심으로 열 안정성을 평가하였다. 시험은 $30^{\circ}C$, $35^{\circ}C$, $40^{\circ}C$, $45^{\circ}C$, $54^{\circ}C$에서 각각 진행하였으며, 님 추출물을 주성분으로 하는 유기농업자재 3종에서 유효성분 반감기는 25.6-220일로 제품에 따라 열 안정성의 차이가 큰 것을 확인하였다. 반면, 고삼 추출물을 주성분으로 하는 유기농업자재의 유효성분 반감기는 231-346일로 님 추출물에 비해 상대적으로 열 안정성이 높은 것으로 나타났다.

This study investigated the thermal stabilities of the four limonoidal active compounds like azadirachtin A, azadirachtin B, deacetylsalannin and salannin and of the two alkaloidal active compounds like matrine and oxymatrine in commercial biopesticides at incubated conditions ($30^{\circ}C$, $35^{\circ}C$, $40^{\circ}C$, $45^{\circ}C$, and $54^{\circ}C$). Half-lives of the limonoidal compounds in biopesticide ranged from 25.6 to 220 days. And the total limonoid contents changed over 15% after 14 days at all the conditions in the tested biopesticide containing neem extract. On the contrary, half-lives of the alkaloidal compounds in biopesticide showed the ranges from 231 to 346 days. And total alkaloidal compounds in all the tested biopesticides containing Sophora flavescens extracts decomposed below 15% after 14 days incubation at $54^{\circ}C$.

키워드

참고문헌

  1. Lee, J. W., C. L. Jin, K. C. Jang, G. H. Choi, H. D. Lee and J. H. Kim (2013a) Investigation on the insecticidal limonoid content of commercial biopesticides and neem extract using solid phase extraction. J. Agric. Chem. Environ. 2:81-85.
  2. Lee, W. M., S. J. Yoon and Y. J. An (2013b) Assessing adjuvants and extractants applicable to environmentfriendly organic agro-materials. J. Appl. Biol. Chem. 56:69-78 (Korean). https://doi.org/10.3839/jabc.2013.012
  3. Lim, S. J., D. Y. Jeong, G. H. Choi, B. J. Park and J. H. Kim (2014) Quantitative analysis of matrine and oxymatrine in Sophora flavescens extract and its biopesticides by UPLC. J. Agric. Chem. Environ. 3:64-73.
  4. Kim, J. H., D. Y. Jeong, C. L.Jin, W. I. Kim, S. J. Lim, G. H. Choi and B. J. Park (2014) Stability of four limonoidal substances of neem extract under controlled aquatic and soil conditions. Kor. Soc. Pestic. Sci. 18:156-160 (Korean).
  5. Kim, J. H., G. H. Choi, S. J. Lim and B. J. Park (2015) Stability of matrine and oxymatrine from the biopesticide from Sophora flavescens under aquatic and soil environment. Kor. J. Environ. Agric. 34:1-5 (Korean). https://doi.org/10.5338/KJEA.2015.34.1.01
  6. Paik, M. K., S. E. Park, B. H. Kim, Y. K. Kim, J. A. Oh, D. H. Kim and J. B. Lee (2013) A survey on the use and perception of environmentally-friendly organic materials among Korean farmers. Kor. Soc. Pestic. Sci. 17:41-49 (Korean).

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  1. The Shelf-life of Agricultural Organic Materials Containing Cinnamon or Derris Extract: Thermal Stability of Cinnamyl Derivatives and Rotenoids vol.20, pp.3, 2016, https://doi.org/10.7585/kjps.2016.20.3.197
  2. 피마자유와 양명아주 추출물을 원료로 하는 유기농업자재 유효성분의 열 안정성 평가 vol.36, pp.1, 2015, https://doi.org/10.5338/kjea.2017.36.1.06
  3. Quantitative Analysis of Active Ingredients in Organic Inputs Derived from Tea Extract vol.24, pp.4, 2020, https://doi.org/10.7585/kjps.2020.24.4.352