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The Membrane Society of Korea (한국막학회)
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Preparation of TiCoxFe1-x(x=0.50~1.00) System Metal Membrane for Hydrogen Separation

수소분리용 TiCoxFe1-x(x=0.50~1.00)계 금속막 제조

  • Received : 2015.04.10
  • Accepted : 2015.04.28
  • Published : 2015.04.30
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Abstract

We have studied on the preparation of $TiCo_xFe_{1-x}$(x=0.50~1.00) system alloy, the characteristics of $TiCo_xFe_{1-x}$(x=0.50~1.00) system alloy by X-ray diffractometer (XRD), pressure composition temperature (PCT) curve, scanning electron microscopy (SEM) and the $H_2-N_2$ gas mixture separation of $TiCo_xFe_{1-x}$(x=0.50~1.00)- stainless steel (SS) composite membranes. The formation of $TiCo_xFe_{1-x}$(x=0.50~1.00) system alloys with cubic crystal same as TiCo was confirmed by X-ray diffractometer. $TiCo_xFe_{1-x}$(x=0.50~1.00) system alloys showed the hysteresis at $120^{\circ}C$. As the Fe content of $TiCo_xFe_{1-x}$(x=0.50~1.00) system alloys increased, the hysteresis was increased both range x=0.90~1.00 and x=0.55~0.60, and the range x=0.55~0.90 gave decreased hysteresis. $TiCo_{0.55}Fe_{0.45}$ alloy was the one showed the lowest hysteresis among them. The lowest value of hydrogen permeation pressure of $TiCo_xFe_{1-x}$(x=0.50~1.00)-SS composite membrane was $TiCo_{0.55}Fe_{0.45}$-SS composite membrane with the value of 2.5 atm at $120^{\circ}C$; otherwise, $TiCo_{0.90}Fe_{0.10}$-SS composite had the highest pressure value among the membranes with the value of 10 atm. $TiCo_{0.55}Fe_{0.45}$-SS composite membrane was the best to separate the $H_2-N_2$ gas mixture excellently among the $TiCo_xFe_{1-x}$(x=0.50~1.00)-SS composite membranes since $TiCo_{0.55}Fe_{0.45}$ had the least hysteresis, and hydrogen permeation pressure was the lowest with value of 2.5 atm.

$TiCo_xFe_{1-x}$(x=0.50~1.00)계 합금을 제조하고, 합금의 특성을 X-ray diffractometer (XRD), pressure composition temperature (PCT)곡선, scanning electron microscopy (SEM)에 의해 조사하였고, $TiCo_xFe_{1-x}$(x=0.50~1.00)-stainless steel (SS) 복합막에 대해 $H_2-N_2$ 혼합기체분리실험을 하였다. X-선 회절분석에 의하면 $TiCo_xFe_{1-x}$(x=0.50~1.00)계 합금의 결정구조는 TiCo와 같은 입방정구조이었다. $TiCo_xFe_{1-x}$(x=0.50~1.00)계 합금은 $120^{\circ}C$에서 hysteresis현상을 나타내었고, 합금 중 Fe의 양이 증가함에 따라 x=0.90~1.00과 0.50~0.55 범위에서는 hysteresis가 증가하였고, x=0.55~0.90 범위에서는 감소하였다. 가장 작은 hysteresis를 나타낸 합금은 $TiCo_{0.55}Fe_{0.45}$이었다. $120^{\circ}C$에서 $TiCo_xFe_{1-x}$(x=0.50~1.00)-SS 복합막의 수소투과압력의 최저값은 $TiCo_{0.55}Fe_{0.45}$에서 2.5 atm을 나타내었고, 최대값은 $TiCo_{0.90}Fe_{0.10}$에서 10 atm을 나타내었다. $TiCo_xFe_{1-x}$(x=0.50~.00)-SS 복합막에 의하여 $120^{\circ}C$에서 $H_2-N_2$ 혼합기체를 분리하는 경우, 가장 우수한 복합막은 고압부의 수소투과압력이 2.5 atm으로 가장 낮고, hysteresis가 가장 작은 $TiCo_{0.55}Fe_{0.45}$-SS 복합막이었다.

Keywords

References

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