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Effect of Zn Addition on Corrosion Behavior of Mg-8%Al Casting Alloy

Mg-8%Al 주조 합금의 부식 거동에 미치는 Zn 첨가의 영향

  • Hwang, In-Je (Advanced Process and Materials R&D Group, Korea Institute of Industrial Technology) ;
  • Moon, Jung-Hyun (Advanced Process and Materials R&D Group, Korea Institute of Industrial Technology) ;
  • Jun, Joong-Hwan (Advanced Process and Materials R&D Group, Korea Institute of Industrial Technology) ;
  • Kim, Young-Jig (School of Advanced Materials Science & Engineering, Sungkyunkwan University)
  • 황인제 (한국생산기술연구원 융합공정신소재그룹) ;
  • 문정현 (한국생산기술연구원 융합공정신소재그룹) ;
  • 전중환 (한국생산기술연구원 융합공정신소재그룹) ;
  • 김영직 (성균관대학교 공과대학 신소재공학부)
  • Received : 2015.04.07
  • Accepted : 2015.05.27
  • Published : 2015.06.30

Abstract

Effects of Zn addition on the microstructure and corrosion behavior of Mg-8%Al-(0-1)%Zn casting alloys were investigated. With increasing Zn content, the amount of ${\beta}(Mg_{17}Al_{12})$ phase increased, while ${\alpha}$-(Mg) dendritic cell size became reduced. The corrosion rate decreased continuously with the increase in the Zn content. The evaluation of the microstructural evolution indicates that the improved barrier effect of ${\beta}$ particles formed more continuously along the dendritic cell boundaries and the incorporation of more ZnO into the surface corrosion product, by which the absorption of $Cl^-$ ions is impeded, are responsible for the better corrosion resistance in relation to the Zn addition.

Keywords

References

  1. Song GL and Atrens A, Adv. Eng. Mater., "Understanding Magnesium Corrosion-A Framework for Improved Alloy Performance", 5 (2003) 837-858. https://doi.org/10.1002/adem.200310405
  2. Jones DA, Principles and prevention of Corrosion (2nd Edition), Prentice Hall (2011).
  3. Dahle AK, Lee YC, Nave MD, Schaffer PL and StJohn DH, J. Light Met., "Development of the as-cast microstructure in magnesium-aluminium alloys", 1 (2001) 61-72. https://doi.org/10.1016/S1471-5317(00)00007-9
  4. Caceres CH, Davidson CJ, Griffiths JR and Newton CL, Mater. Sci. Eng., "Effects of solidification rate and ageing on the microstructure and mechanical properties of AZ91 alloy", A325 (2002) 344-355.
  5. Ballerini G, Bardi U, Bignucolo R and Ceraolo G, Corr. Sci., "About some corrosion mechanisms of AZ91D magnesium alloy", 47 (2005) 2173-2184. https://doi.org/10.1016/j.corsci.2004.09.018
  6. Song GL, Atrens A and Dargush M, Corr. Sci., "Influence of microstructure on the corrosion of die-cast AZ91D", 41 (1999) 249-273.
  7. Avedesian MM, Magnesium and Magnesium Alloys, ASM international, Materials Park, OH, (1999).
  8. Wang YS, Wang QD, Wu GH, Zhu YP and Ding WJ, Mater. Lett., "Hot-tearing susceptibility of Mg-9Al-xZn alloy", 57 (2002) 929-934. https://doi.org/10.1016/S0167-577X(02)00898-4
  9. Gao DM, Zhang YH, Hua Q and Zhai QQ, Mater Sci. Eng., "Study on mechanical properties of Mg-Al-Zn-Mn alloys cast by two different methods", A507 (2009) 1-5.
  10. Wang YS, Wang QD, Ma CJ, Ding WJ and Zhu YP, Mater. Sci. Eng., "Effects of Zn and RE additions on the solidification behavior of Mg-9Al magnesium alloy", A342 (2003) 178-182.
  11. Polmear IJ, Mater. Trans. JIM., "Recent Developments in Light Alloys", 37 (1996) 12-31. https://doi.org/10.2320/matertrans1989.37.12
  12. Zhang L, Cao JY, Liu YB, Su GH and Cheng LR, Mater. Sci. Eng., "Effect of Al content on the microstructures and mechanical properties of Mg-Al alloys", A508 (2009) 129-133.
  13. Nave MD, Dahle AK and StJohn DH, Magnesium Technology by TMS, "The Role of Zinc in the Eutectic Solidification of Magnesium-Aluminium-Zinc alloys" (2000) 243-250.
  14. Nave MD, Dahle AK and StJohn DH, Magnesium Technology by TMS, "Eutectic Growth Morphologies in Magnesium-Aluminium Alloys" (2000) 233-242.
  15. Duly D, Brechet Y and Chenal B, Acta Metall., "Macroscopic kinetics of discontinuous precipitation in a Mg-8.5 wt% Al alloy", 40 (1992) 2289-2300. https://doi.org/10.1016/0956-7151(92)90147-7
  16. Song YW, Han EH, Shan D, Yim CH and You BS, Corros. Sci., "The effect of Zn concentration on the corrosion behavior of Mg-xZn alloys", 65 (2012) 322-330. https://doi.org/10.1016/j.corsci.2012.08.037
  17. Izumi S, Yamasaki M and Kawamura Y, Corros. Sci., "Relation between corrosion behavior and microstructure of Mg-Zn-Y alloys prepared by rapid solidification at various cooling rates", 51 (2009) 395-402. https://doi.org/10.1016/j.corsci.2008.11.003
  18. Zhang JH, Niu XD, Qiu X, Liu K, Nan CM, Tang DX and Meng JA, J. Alloys Compd., "Effect of yttrium-rich misch metal on the microstructures, mechanical properties and corrosion behavior of die cast AZ91 alloy", 471 (2009) 322-330. https://doi.org/10.1016/j.jallcom.2008.03.089
  19. Song YW, Han EH, Dong KH, Shan DY, Yim CH and You BS, Corr. Sci., "Study of the corrosion product films formed on the surface of Mg-xZn alloys in NaCl solution", 88 (2014) 215-225. https://doi.org/10.1016/j.corsci.2014.07.034
  20. Kim MS, J. Corr. Sci. Soc. Kor., "Surface And Complex in Corrosion Aspect", 1 (1980) 24-28.
  21. Kim JT, Jeong HS, Ryu SS, Lee GD and Park JM, Korea Chem. Eng. Res., "Anti-Corrosion Performance of the Novel Pigment, Ion-Exchanged Zeolite for the Protection of Galvanized Steel", 49 (2011) 745-751. https://doi.org/10.9713/kcer.2011.49.6.745

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