DOI QR코드

DOI QR Code

Study of Dye Encapsulated Microcapsule Polymerization Using Polyurethane Prepolymer Synthesis and Textile Finishing

폴리우레탄 프리폴리머 합성을 통한 색소 담지 마이크로캡슐 제조 및 섬유가공

  • Kim, Ji Yeon (Department of Advanced Organic Materials Science and Engineering, Kyungpook National University) ;
  • Woo, Ji Yun (Korea Dyeing and Finishing Technology Institute) ;
  • Min, Mun Hong (Korea Dyeing and Finishing Technology Institute) ;
  • Yoon, Seok Han (Korea Dyeing and Finishing Technology Institute) ;
  • Yeum, Jeong Hyun (Department of Advanced Organic Materials Science and Engineering, Kyungpook National University)
  • Received : 2015.08.14
  • Accepted : 2015.09.02
  • Published : 2015.09.27

Abstract

In this study, dye encapsulated microcapsules were produced by polyurethane prepolymer synthesis method using hexamethylene diisocyanate, ethylene glycol and methyl ethyl ketone. The study showed that the average size of microcapsules were $4.697{\mu}m$ in normal distribution. These microcapsules were induced red color by thermochromic fluoran red dye with showing color change as temperature. After the textile finishing of microcapsules, durability of microcapsules were checked as crocking times and lightfastness. The microcapsules were pressed at protrusion of textile weave in 10 crocking times which meant that the microcapsules not fallen off. Lightfastness was acceptable giving rating 4. It means that the polyurethane microcapsules not affect to light durability.

Keywords

References

  1. E. J. Kim, "Development of Hydrophilic Non-porous Type Breathable Resin and Finishing Technology", Ministry of Trade, Industry and Energy, Korea, pp.30-37, 2001.
  2. C. N. Choi, J. B. Kim, T. Y. Hwang, M. S. Lee, R. Kim, and I. B. Jung, Preparation of Polyurethane Derivative Microcapsule and Its Application to Textile Finishing, J. of the Korean Fiber Society, 38(4), 174(2001).
  3. J. H. Shim, Study on Characterization of Film Manufactured by Hydrophilic Thermoplastic Polyurethane, M.S. Thesis, Yeungnam University, 2006.
  4. S. Yun, S. Meiqin, and T. Qiyu, Synthesis of Fluoran Dyes with Improved Properties, Dyes and Pigments, 29(1), 49(1995).
  5. H. I. Park, A. K. Kim, W. E. Lee, and C. N. Choi, The Preparation of Polyurethane Microcapsule and Its Breaking BehavioJ. of the Korean Society of Dyers and Finishers, 10(2), 37(1998).
  6. C. F. Zhu and A. B. Wu, Studies on the Synthesis and Thermochromic Properties of Crystal Violet Lactone and Its Reversible Thermochromic Complexes, Thermochimica Acta, 425(1-2), 7(2005). https://doi.org/10.1016/j.tca.2003.08.001
  7. I. H. Kim, J. B. Seo, and Y. J. Kim, Preparation and Characterization of Polyurethane Microcapsules Containing Functional Oil, Polymer(Korea), 26(3), 400(2002).
  8. Y. Frere, L. Danicher, and P. Gramain, Preparation of Polyurethane Microcapsules by Interfacial Polycondensation, Eur. Polym. J., 34(2), 193(1998). https://doi.org/10.1016/S0014-3057(97)00084-0
  9. H. I. Kim and S. M. Park, Functional Finishing of Microcapsule Application, Fiber Technology and Industry, 7(3), 322(2003).
  10. C. Y. Park, Effect of PPG, MDI, 2-HEMA and Butyl Acrylate Content on the Properties of Polyurethane Adhesive, Elastomer and Composites, 49(3), 245(2014). https://doi.org/10.7473/EC.2014.49.3.245
  11. H. G. Im, H. S. Lee, and J. H. Kim, Dispersity of Silver Particles in Polyurethane Matrix, Effect of Polyurethane Chemical Structure, Polymer(Korea), 31(6), 543(2007).
  12. J. H. Hwang, K. S. Oh, and N. S. Yoon, Fluoroalkylation of the Surface of Hydrophilic Polyurethane Breathable Membrane, Textile Coloration and Finishing, 25(1), 30(2013). https://doi.org/10.5764/TCF.2013.25.1.30
  13. J. S. Bae, S. Y. Gwon, and S. H. Kim, Anthraquinone- carbamodithiolate Assembly as Selective Chromogenic Chemosensor for $Fe^{3+}$, Textile Coloration and Finishing, 25(1), 13(2013). https://doi.org/10.5764/TCF.2013.25.1.13

Cited by

  1. Study of Dye Encapsulated Microcapsule Polymerization Using Styrene Monomer vol.28, pp.3, 2016, https://doi.org/10.5764/TCF.2016.28.3.164
  2. Crystallization of Poly(1,4-diaminobutane-co-adipic acid-co-ε-caprolactam-co-diethylenetriamine) Copolymer Fiber vol.28, pp.4, 2016, https://doi.org/10.5764/TCF.2016.28.4.231