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Preparation of conductive EPDM rubber sheets by electroless Ni-plating for electromagnetic interference shielding applications

무전해 Ni 도금법을 이용한 전자파 차폐용 도전성 EPDM 고무의 제조

  • Lee, Byeong Woo (Department of Marine Equipments Engineering, Korea Maritime University) ;
  • Cho, Soo Jin (Department of Marine Equipments Engineering, Korea Maritime University) ;
  • Yang, Jun Seok (Department of Marine Equipments Engineering, Korea Maritime University)
  • 이병우 (한국해양대학교 조선기자재공학과) ;
  • 조수진 (한국해양대학교 조선기자재공학과) ;
  • 양준석 (한국해양대학교 조선기자재공학과)
  • Received : 2015.09.04
  • Accepted : 2015.09.25
  • Published : 2015.10.31

Abstract

In the study, electroless Ni-plating on flexible ethylene-propylene-diene-monomer (EPDM) rubber sheets for the application of an insert block for shielding electromagnetic interference of multi cable transit (MCT) systems was investigated. Ni crystallinity and adhesion have been found to vary with processing parameters such as pH and temperature of the plating bath. It was shown that Ni-films having the high crystallinity and optimum electric conductivity were obtained on EPDM rubber sheets under pH 7 and 8 at $60{\sim}70^{\circ}C$. The conductive Ni-plated EPDM rubber prepared at pH 7 at $70^{\circ}C$ showed the enhanced adhesion and electric conductivity, and the high electromagnetic interference shielding effect in the 400 MHz~1 GHz range.

본 연구에서는 전자파 차폐형 MCT(multi cable transit)의 인서트블록에 사용되는 유연성 EPDM(ethylene propylene diene monomer)고무 상에 무전해 도금을 이용하여 니켈도금을 실시하였다. 도금욕의 공정변수 조절 즉 pH 및 온도에 따라 Ni 도금층의 결정성 및 부착력이 결정되었다. pH와 온도를 달리하여 합성 한 결과 pH 7 및 8, $60{\sim}70^{\circ}C$에서 얻은 도금막들에서 잘 발달된 결정상과 높은 전기 전도도를 가짐을 알 수 있었다. pH 7, $70^{\circ}C$에서 도금 시 가장 높은 부착력 및 전기전도도를 얻을 수 있었으며, 또한 400 MHz~1 GHz 범위에서 우수한 전자파 차단능을 얻을 수 있었다.

Keywords

References

  1. M. Stoppa and A. Chiolerio, "Wearable electronics and smart textiles: a critical review", Sensors 14 (2014) 11957. https://doi.org/10.3390/s140711957
  2. N.C. Das, D. Khastgir, T.K. Chaki and A. Chakraborty, "Electromagnetic interference shielding effectiveness of carbon black and carbon fibre filled EVA and NR based composites", Composites 31A (2000) 1069.
  3. K. Sasikumar, G. Suresh, K.A. Thomas, R. John, V. Natarajan, T. Mukundav and R.M.R. Vishnubhatla, "Magnetoactive elastomeric composites: cure, tensile, electrical and magnetic properties", Bull. Mater. Sci. 29 (2006) 637. https://doi.org/10.1007/s12034-006-0016-z
  4. S.J Lee, D.Y. Lee, M.H. Lee and B.Y. Kim, "Tailored biomimetic actuators made with multiwalled carbon nanotube loaded ionomeric nanocomposites", J. Korean Cryst. Growth Cryst. Technol. 15 (2005) 108.
  5. Technical report, Roxtec multi-cable transit devices: applications and design practices, Roxtec, Sweden (2014).
  6. D.Y.W. Yu and F. Spaepen, "The yield strength of thin copper films on Kapton", J. Appl. Phys. 95 (2004) 2991. https://doi.org/10.1063/1.1644634
  7. S. Rosset, M. Niklaus, P. Dubois and H.R. Shea, "Metal ion implantation for the fabrication of stretchable electrodes on elastomers", Adv. Funct. Mater. 19 (2009) 470. https://doi.org/10.1002/adfm.200801218
  8. S. Griehl, T. Muller and R. Winkler, "Thick metallization- layers on polymers through vacuum-technology", J. Surf. Coat. Technol. 169 (2003) 24.
  9. K. De Bruyn, M. van Stappen, H. De Deurwaerder, L. Rouxhet and J.P. Celis, "Study of pretreatment methods for vacuum metallization of plastics", Surf. Coat. Technol. 163 (2003) 710.
  10. S.P. Lacour, J. Jones, S. Wagner T. Li and Z. Suo, "Stretchable interconnects for elastic electronic surfaces", Proc. IEEE 93 (2005) 1459. https://doi.org/10.1109/JPROC.2005.851502
  11. M.C. Zhang, E.T. Kang, K.G. Neoh and K.L. Tan, "Electroless plating of copper and nickel on surface modified poly (tetrafluoroethylene) films", J. Electrochem. Soc. 148 (2001) 71. https://doi.org/10.1149/1.1337609
  12. D. Li, K. Goodwin and C.L. Yang, "Electroless copper deposition on aluminum-seeded ABS plastics", J. Mater. Sci. 43 (2008) 7121. https://doi.org/10.1007/s10853-008-3031-1
  13. P. Dechasit and W. Trakarnpruk, "Ni electroless plating of ABS polymer by palladium and tin-free process", J. Met. Mater. Miner. 21 (2011) 19.
  14. B.W. Lee and J.H. Lee, "Preparation of conductive silicone rubber sheets by electroless nickel plating", J. Kor. Inst. Surf. Eng. 47 (2014) 269. https://doi.org/10.5695/JKISE.2014.47.5.269
  15. IEEE Std. 299, IEEE standard method for measuring the effectiveness of electromagnetic shielding enclosure (1997).