DOI QR코드

DOI QR Code

Dynamic Oxidation Behaviors of Aluminide Coated Titanium Alloys

알루미나이드 코팅된 티타늄 합금의 동적산화거동

  • Son, Youngil (Advanced Propulsion Technology Center, Agency for Defense Development) ;
  • Park, Jinsoo (Department of Materials Science and Engineering, Hanbat National University) ;
  • Park, Joonsik (Department of Materials Science and Engineering, Hanbat National University)
  • Received : 2015.06.01
  • Accepted : 2015.09.01
  • Published : 2015.10.01

Abstract

Titanium alloys has been received an attention due to their excellent specific strength and many other superior properties in the application of components of flying subjects. In this study, Ti-6Al-4V (Ti64 alloy) has been selected in order to evaluate oxidation and degradation behaviors under the exposure of high temperature flame. The alloy has been coated with Al diffusion coating routes. The coated alloys showed an improved oxidation and degradation behaviors. The oxidation and degradation mechanism for the coated and uncoated alloys has been discussed in terms of microstructural observations.

티타늄 합금은 고온 추진체의 부품에 사용될 경우, 고온의 화염에서 순간적으로 노출될 수 있음으로, 고온의 화염하에서의 내산화특성을 평가할 필요가 있다. 본 연구에서는 Ti64 합금 (Ti-6%Al-4%V) 및 코팅된 Ti64 합금을 고온화염하에서 산화손상 및 내산화 특성을 평가하고자 하였다. Ti64 합금의 코팅은 알루미늄 확산코팅법을 사용하여 코팅을 수행하였다. 표면에 알루미나이드층이 코팅되지 않은 Ti64 합금은 고온의 화염 노출시에 표면 박리현상이 발생하였으나, 코팅된 시험편은 표면박리현상이 나타나지 않았고 알루미나이드 층의 산화물 생성으로 인하여 표면이 보호됨을 관찰할 수 있었다. 화염노출시 코팅층의 역할을 고찰하기 위하여 코팅층을 분석하였으며, 조직의 변화를 고찰하고 논의하였다.

Keywords

References

  1. Li, B., Shen, Y., Luo, L., Hu, W. and Zhang, Z., "Surface Aluminizing on Ti- 6Al-4V Alloy via a Novel Multi-pass Friction-stir Lap Welding Method: Preparation Process, Oxidation Behavior and Interlayer Evolution," Materials and Design, Vol. 49, pp. 647-656, 2013. https://doi.org/10.1016/j.matdes.2013.02.013
  2. Gurrappa, I., "An Oxidation Model for Predicting the Life of Titanium Alloy Components in Gas Turbine Engines," Journal of Alloys and Compounds, Vol. 389, Issues 1-2, pp. 190-197, 2005. https://doi.org/10.1016/j.jallcom.2004.05.079
  3. Prasad, K. and Kumar, V. "Isothermal and Thermomechanical Fatigue Behaviour of Ti -6Al-4V Titanium Alloy," Materials Science and Engineering A, Vol. 528, Issues 19-20, pp. 6263-6270, 2011. https://doi.org/10.1016/j.msea.2011.04.085
  4. Zhang, Z.G., Peng, Y.P., Mao, Y.L., Pang, C.J. and Lu, L.Y., "Effect of Hot-dip Aluminizing on the Oxidation Resistance of Ti-6Al-4V Alloy at High Temperatures," Corrosion Science, Vol. 55, pp. 187-193, 2012. https://doi.org/10.1016/j.corsci.2011.10.029
  5. Xiong, Y., Zhu, S. and Wang, F., "The Oxidation Behavior and Mechanical Performance of Ti60 Alloy with Enamel Coating," Surface and coatings Technology, Vol. 190, Issues 2-3, pp. 195-199, 2005. https://doi.org/10.1016/j.surfcoat.2004.09.005
  6. Park, J.S., Kim, J.M., Cho, S.H., Son, Y.I. and Kim, D.S., "Oxidation of MoSi2-Coated and Uncoated TZM (Mo0.5Ti0.1Zr0.02C) Alloys under High Temperature Plasma Flame," Materials Transactions, Vol. 54, No. 8, pp. 1517-1523, 2013. https://doi.org/10.2320/matertrans.M2013065
  7. Xiang, Z.D., Rose, S. and Datta, P.K., "Pack Deposition of Coherent Aluminide Coatings on γ-TiAl for Enhancing its High Temperature Oxidation Resistance," Surface and coatings Technology, Vol. 161, Issues 2-3, pp. 286-292, 2002. https://doi.org/10.1016/S0257-8972(02)00469-3
  8. Yoon, J.K., Lee, K.H., Kim, G.H., Lee, J.K., Doh, J.M. and Hong, K.T., "Growth Kinetics of MoSi2 Coating Formed by a Pack Siliconizing Process," Journal Electrochemical Society, Vol. 151, Issue 6, pp. B309-B318, 2004. https://doi.org/10.1149/1.1710896
  9. Levine, S.R. and Caves, R.M., "Thermodynamics and Kinetics of Pack Aluminide Coating Formation on IN-100," Journal Electrochemical Society, Vol. 121, Issue 8, pp. 1051-1064, 1974. https://doi.org/10.1149/1.2401976
  10. Majumdar, S., Sharma, I., Samajdar, I. and Bhargava, P., "Relationship between Pack Chemistry and Growth of Silicide Coatings on Mo-TZM Alloy," Journal Electrochemical Society, Vol. 155, Issue 12, pp. D734-D741, 2008. https://doi.org/10.1149/1.2987954
  11. Costa, W.D, Gleeson, B. and Young, D.J., "Codeposited Chromium-Aluminide Coatings," Journal Electrochemical Society, Vol. 141, Issue 6, pp. 2690-2698, 1994. https://doi.org/10.1149/1.2059176
  12. Xiang, Z.D. and Datta, P.K., "Effects of Pack Composition on the Formation of Aluminide Coatings on Alloy Steels at $650^{\circ}C$," Journal of Materials Science, Vol. 40, Issue 8, pp. 1959-1966, 2005. https://doi.org/10.1007/s10853-005-1217-3
  13. Xiang, Z.D. and Datta, P.K. "Relationship between Pack Chemistry and Aluminide Coating Formation for Low-temperature Aluminisation of Alloy Steels," Acta Materialia, Vol 54, Issue 17, pp. 4453-4463, 2006. https://doi.org/10.1016/j.actamat.2006.05.032
  14. Zhou, C., Xu, H., Gong, S. and Kim, K.Y., "A Study of Aluminide Coatings on TiAl Alloys by the Pack Cementation Method," Materials Science and Engineering A, Vol. 341, Issues 1-2, pp. 169-173, 2003. https://doi.org/10.1016/S0921-5093(02)00197-1