DOI QR코드

DOI QR Code

Strength Development of Alkali-Activated Fly Ash Exposed to a Carbon Dioxide-Rich Environment at an Early Age

  • Park, Sol-Moi (Department of Civil and Environmental Engineering, Korea Advanced Institute of Science and Technology) ;
  • Jang, Jeong-Gook (Department of Civil and Environmental Engineering, Korea Advanced Institute of Science and Technology) ;
  • Kim, Gwang-Mok (Department of Civil and Environmental Engineering, Korea Advanced Institute of Science and Technology) ;
  • Lee, Haeng-Ki (Department of Civil and Environmental Engineering, Korea Advanced Institute of Science and Technology)
  • Received : 2015.12.11
  • Accepted : 2016.01.13
  • Published : 2016.01.31

Abstract

The development of a binder system with a lower carbon footprint as an alternative to Portland cement has been intensely researched. In the present study, alkali-activated fly ash exposed to carbon dioxide at an early age was characterized in compressive strength tests and by MIP, XRD and FT-IR analyses. The compressive strength of carbonated specimens experienced a dramatic increase in comparison to uncarbonated specimens. The microstructural densification of the carbonated specimens was evidenced by MIP. The XRD pattern showed peaks assigned to nahcolite, indicating that the pH was lower in the carbonated specimens. Under the carbon dioxide-rich environment, the aluminosilicate gel reached a more Si-rich state, which improved the mechanical properties of the alkali-activated fly ash.

Keywords

References

  1. B. Lothenbach, K. Scrivener, and R. D. Hooton, "Supplementary Cementitious Materials," Cem. Concr. Res., 41 [12] 1244-56 (2011). https://doi.org/10.1016/j.cemconres.2010.12.001
  2. M. C. G. Juenger, F. Winnefeld, J. L. Provis, and J. H. Ideker, "Advances in Alternative Cementitious Binders," Cem. Concr. Res., 41 [12] 1232-43 (2011). https://doi.org/10.1016/j.cemconres.2010.11.012
  3. J. S. J. Deventer, J. L. Provis, and P. Duxon, "Technical and Commercial Progress in the Adoption of Geopolymer Cement," Miner. Eng., 29 89-104 (2012). https://doi.org/10.1016/j.mineng.2011.09.009
  4. S. A. Bernal and J. L. Provis, "Durability of Alkali-Activated Materials: Progress and Perspectives," J. Am. Ceram. Soc., 97 [4] 997-1008 (2014). https://doi.org/10.1111/jace.12831
  5. A. Fernandez-Jimenez, A. G. De La Torre, A. Palomo, G. Lopez-Olmo, M. M. Alonso, and M. A. G. Aranda, "Quantitative Determination of Phases in the Alkaline Activation of Fly Ash. Part II: Degree of Reaction," Fuel, 85 [14] 1960-69 (2006). https://doi.org/10.1016/j.fuel.2006.04.006
  6. M. Criado, A. Palomo, and A. Fernandez-Jimenez, "Alkali Activation of Fly Ashes. Part 1: Effect of Curing Conditions on the Carbonation of the Reaction Products," Fuel, 84 [16] 2048-54 (2005). https://doi.org/10.1016/j.fuel.2005.03.030
  7. S. A. Bernal, J. L. Provis, B. Walkley, R. S. Nicolas, J. D. Gehman, D. G. Brice, A. R. Kilcullen, P. Duxson, and J. S. J. Deventer, "Gel Nanostructure in Alkali-Activated Binders Based on Slag and Fly Ash, and Effects of Accelerated Carbonation," Cem. Concr. Res., 53 127-44 (2013). https://doi.org/10.1016/j.cemconres.2013.06.007
  8. S. Diamond, "Mercury Porosimetry: An Inappropriate Method for the Measurement of Pore Size Distributions in Cement-Based Materials," Cem. Concr. Res., 30 [10] 1517-25 (2000). https://doi.org/10.1016/S0008-8846(00)00370-7
  9. J. G. Jang and H. K. Lee, "Effect of Fly Ash Characteristics on Delayed High-Strength Development of Geopolymers," Constr. Build. Mater., 102 260-69 (2016). https://doi.org/10.1016/j.conbuildmat.2015.10.172
  10. J. G. Jang, H. J. Kim, S. M. Park, and H. K. Lee, "The Influence of Sodium Hydrogen Carbonate on the Hydration of Cement," Constr. Build. Mater., 94 746-9 (2015). https://doi.org/10.1016/j.conbuildmat.2015.07.121
  11. Z. Zhang, H. Wang, J. L. Provis, and A. Reid, "Efflorescence: A Critical Challenge for Geopolymer Applications?," Concrete Institute of Australia's Biennial National Conference 2013, Gold Coast, Australia, 16-18 Oct, 2013.
  12. M. Sitarz, W. Mozgawa, and M. Handke, "Rings in the Structure of Silicate Glasses," J. Mol. Struct., 511 281-85 (1999).
  13. C. A. Rees, J. L. Provis, G. C. Lukey, and J. S. J. Deventer, "Attenuated Total Reflectance Fourier Transform Infrared Analysis of Fly Ash Geopolymer Gel Aging," Langmuir, 23 [15] 8170-79 (2007). https://doi.org/10.1021/la700713g
  14. A. Fernandez-Jimenez, A. Palomo, I. Sobrados, and J. Sanz, "The Role Played by the Reactive Alumina Content in the Alkaline Activation of Fly Ashes," Microporus Mesoporous Mater., 91 [1] 111-19 (2006). https://doi.org/10.1016/j.micromeso.2005.11.015
  15. P. Innocenzi, "Infrared Spectroscopy of Sol-Gel Derived Silica-Based Films: A Spectra-Microstructure Overview," J. Non-Cryst. Solids, 316 [2] 309-19 (2003). https://doi.org/10.1016/S0022-3093(02)01637-X
  16. T. Bakharev, "Geopolymeric Materials Prepared using Class F Fly Ash and Elevated Temperature Curing," Cem. Concr. Res., 35 [6] 1224-32 (2005). https://doi.org/10.1016/j.cemconres.2004.06.031

Cited by

  1. An NMR Spectroscopic Investigation of Aluminosilicate Gel in Alkali-Activated Fly Ash in a CO2-Rich Environment vol.9, pp.5, 2016, https://doi.org/10.3390/ma9050308
  2. A synopsis of carbonation of alkali-activated materials vol.7, pp.3, 2016, https://doi.org/10.1680/jgrma.18.00052