수소연료전지 스택용 가스켓 고무소재 개발동향

  • 박상우 (전북대학교 고분자나노공학과) ;
  • 왕원석 (전북대학교 고분자나노공학과) ;
  • 전진석 (전북대학교 고분자나노공학과) ;
  • 원주혜 (전북대학교 고분자나노공학과) ;
  • 윤창현 (전북대학교 고분자나노공학과) ;
  • 나창운 (전북대학교 고분자나노공학과)
  • Published : 2016.12.31

Abstract

Keywords

References

  1. K. A. Mauritz and R. B. Moore, "State of Understanding of Nafion", Chem. Rev., 104, 4535 (2004). https://doi.org/10.1021/cr0207123
  2. S. Gottesfeld and T. Zawodzinki, "Polymer Electrolyte Fuel Cells", Adv. Electrochem. Sci. Eng., 5, 195 (1997).
  3. J. Tan, Y. J. Chao, J. W. van Zee and W. K. Lee, "Degradation of elastomeric gasket materials in PEM fuel cells", Mater. Sci. Eng. A, 445, 669 (2007).
  4. C. W. Lin, C. H. Chien, J. Tan, Y. J. Chao and J. W. van Zee, "Chemical degradation of five elastomeric seal materials in a simulated and an accelerated PEM fuel cell environment", J. Power Sourc., 196, 1955 (2011). https://doi.org/10.1016/j.jpowsour.2010.10.012
  5. R. Blunk, F. Zhong and J. Owens, "Automotive composite fuel cell bipolar plates: Hydrogen permeation concerns", J. Power Sourc., 159, 533 (2006). https://doi.org/10.1016/j.jpowsour.2005.09.068
  6. G. Bandlamudi, C. Siegel, S. Multhaupt, T. Derith, I. Buder, J. burfeind, P. Beckhaus and A. Heinzel, Duisburg, Chemical and mechanical stability of HTPEM fuel cell components report, Germany.
  7. T. Cui, C. W. Lin, C. H. Chien, Y. J. Chao and J. W. van Zee, "Service life estimation of liquid silicone rubber seals in polymer electrolyte membrane fuel cell environment", J. Power Sourc., 196, 1216 (2011). https://doi.org/10.1016/j.jpowsour.2010.08.075
  8. J. Tan, Y. J. Chao, J. W. van Zee, X. Li, X. Wang and M. Yang, "Assessment of mechanical properties of fluoroelastomer and EPDM in a simulated PEM fuel cell environment by microindentation test", Mater. Sci. Eng. A, 496, 464 (2008). https://doi.org/10.1016/j.msea.2008.05.052
  9. J. Tan, Y. J. Chao, H. Wang, J. Gong and J. W. van Zee, "Chemical and mechanical stability of EPDM in a PEM fuel cell environment", Polym. Degrad. Stab., 94, 2072 (2009). https://doi.org/10.1016/j.polymdegradstab.2009.07.009
  10. V. Parry, G. Berthome, J. C. Joud, O. Lemaire and A. A. Franco, "XPS investigations of the proton exchange membrane fuel cell active layers aging:Characterization of the mitigating role of an anodic CO contamination on cathode degradation", J. Power Sourc., 196, 2530 (2011). https://doi.org/10.1016/j.jpowsour.2010.11.027
  11. M. Schulze, T. Knori, A. Schneider and E. Gulzow, "Degradation of sealings for PEFC test cells during fuel cell operation", J. Power Sourc., 127, 222 (2004). https://doi.org/10.1016/j.jpowsour.2003.09.017
  12. S. J. C. Cleghorn, D. K. Mayfield, D. A. Moore, J. C. Moore, G. Rusch, T. W. Sherman, N. T. Sisofo and U. Beuscher, "A polymer electrolyte fuel cell life test: 3 years of continuous operation", J. Power Sourc., 158, 446 (2006). https://doi.org/10.1016/j.jpowsour.2005.09.062
  13. J. St-Pierre and N. Jia, "Successful demonstration of ballard PEMFCS for space shuttle applications", J. New Mater. Electrochem. Syst., 5, 263 (2002).
  14. S. Mitra, A. Ghanbari-Siahkali, P. Kingshott, K. Almdal, H. K. Rehmeier and A. G. Christensen, "Chemical degradation of fluoroelastomer in an alkaline environment", Polym. Degrad. Stab., 83, 195 (2004) https://doi.org/10.1016/S0141-3910(03)00235-0
  15. M. A. Kader, M. Y. Lyu and C. Nah, "A study on melt processing and thermal properties of fluoroelastomer nanocomposites", Compos. Sci. Technol., 66, 1431 (2006). https://doi.org/10.1016/j.compscitech.2005.09.001
  16. M. Maiti, S. Mitra and A. K. Bhowmick, "Effect of nanoclays on high and low temperature degradation of fluoroelastomers", Polym. Degrad. Stab., 93, 188 (2008). https://doi.org/10.1016/j.polymdegradstab.2007.10.007
  17. Y. Wang, L. Liu, Y. Luo and D. Jia, "Aging behavior and thermal degradation of fluoroelastomer reactive blends with poly-phenol hydroxy EPDM", Polym. Degrad. Stab., 94, 443 (2009). https://doi.org/10.1016/j.polymdegradstab.2008.11.007
  18. T. Sugama, "Surface analyses of fluoroelastomer bearings exposed to geothermal environments", Mater. Lett., 50, 66 (2001). https://doi.org/10.1016/S0167-577X(00)00415-8
  19. S. Maria-Daniela, "Physico-Mechanical Characteristics of Some EPDM/Plasticized PVC Blends", Macromol. Symp., 263, 70 (2008). https://doi.org/10.1002/masy.200850309
  20. S. Mitra, A. Ghanbari-Siahkali, P. Kingshott, H. K. Rehmeier, H. Abildgaard and K. Almdal, "Chemical degradation of crosslinked ethylenepropylene-diene rubber in an acidic environment. Part I. Effect on accelerated sulphur crosslinks", Polym. Degrad. Stab., 91, 69 (2006). https://doi.org/10.1016/j.polymdegradstab.2005.04.032
  21. S. Mitra, A. Ghanbari-Siahkali, P. Kingshott, H. K. Rehmeier, H. Abildgaard and K. Almdal, "Chemical degradation of crosslinked ethylenepropylene-diene rubber in an acidic environment. Part II. Effect of peroxide crosslinking in the presence of a coagent", Polym. Degrad. Stab., 91, 81 (2006). https://doi.org/10.1016/j.polymdegradstab.2005.04.031
  22. R. Nevshupa, L. Martinez, L. Alvarez, M. F. Lopez, Y. Huttel, J. Mendez and E. Roman, "Influence of thermal ageing on surface degradation of ethylene-propylene-diene elastomer" J. Appl. Polym. Sci., 119, 242 (2011). https://doi.org/10.1002/app.32519
  23. J. Tan, Y. J. Chao, X. Li and J. W. van Zee, "Degradation of silicone rubber under compression in a simulated PEM fuel cell environment", J. Power Sourc., 172, 782 (2007). https://doi.org/10.1016/j.jpowsour.2007.05.026
  24. J. Tan, Y. J. Chao, M. Yang, W. K. Lee and J. W. van Zee, "Chemical and mechanical stability of a Silicone gasket material exposed to PEM fuel cell environment", Int. J. Hydrogen Energ., 36, 1846 (2011). https://doi.org/10.1016/j.ijhydene.2009.12.048
  25. J. Tan, Y. J. Chao, W. K. Lee, C. S. Smith, J. W. van Zee and C. T. William, Degradation of gasket materials in a simulated fuel cell environment, Proceedings of the 4th International Conference on Fuel Cell Science Engineering and Technology, Irvine, CA, June (2006).
  26. J. Tan, Y. J. Chao, M. Yang, C. T. Williams and J. W. van Zee, "Degradation characteristics of elastomeric gasket materials in a simulated PEM fuel cell environment", J. Mater. Eng. Perform., 17, 785 (2008). https://doi.org/10.1007/s11665-008-9233-5
  27. P. F. Aparicio, B. Gallardo-Lopez, A. M. Chaparro and L. Daza, "Physico-chemical study of the degradation of membrane-electrode assemblies in a proton exchange membrane fuel cell stack", J. Power Sourc., 196, 4242 (2011). https://doi.org/10.1016/j.jpowsour.2010.10.059
  28. J. Feng, Q. Zhang, Z. Tu, W. Tu, Z. Wan, M. Pan and H. Zhang, "Degradation of silicone rubbers with different hardness in various aqueous solutions", Polym. Degrad. Stab., 109, 122 (2014). https://doi.org/10.1016/j.polymdegradstab.2014.07.011
  29. G. Li, J. Tan and J. Gong, "Degradation of the elastomeric gasket material in a simulated and four accelerated proton exchange membrane fuel cell environments", J. Power Sourc., 205, 244 (2012). https://doi.org/10.1016/j.jpowsour.2011.06.092
  30. A. Husar, M. Serra and C. Kunusch, "Description of gasket failure in a 7 cell PEMFC stack" J. Power Sourc., 169, 85 (2007). https://doi.org/10.1016/j.jpowsour.2007.01.078
  31. C. W. Lin, C. H. Chien, J. Tan, Y. J. Chao, and J. W. Van Zee, "Dynamic mechanical characteristics of five elastomeric gasket materials aged in a simulated and an accelerated PEM fuel cell environment", Int. J. Hydrogen Energ., 36, 6756 (2011). https://doi.org/10.1016/j.ijhydene.2011.02.112
  32. U. Basuli, J. Jose, R. H. Lee, Y. H. Yoo, K. U. Jeong, J. H. Ahn and C. Nah, "Properties and Degradation of the Gasket Component of a Proton Exchange Membrane Fuel Cell-A Review", J. Nanosci. Nanotechnol., 12, 7641 (2012). https://doi.org/10.1166/jnn.2012.6627