DOI QR코드

DOI QR Code

Studies on the Surface Properties of PMMA after Accelerated Weathering

  • Kwon, Young Bum (School of Materials Science and Engineering, Polymer Science and Engineering, RIGET, Gyeongsang National University) ;
  • Ha, Jin Uk (Lightweight & Convergent Materials R&D Center, Korea Automotive Technology Institute) ;
  • Hwang, Ye Jin (Lightweight & Convergent Materials R&D Center, Korea Automotive Technology Institute) ;
  • Oh, Jeong Seok (School of Materials Science and Engineering, Polymer Science and Engineering, RIGET, Gyeongsang National University)
  • Received : 2016.12.14
  • Accepted : 2016.12.22
  • Published : 2016.12.31

Abstract

The surface properties of poly(methyl methacrylate) (PMMA) were investigated after accelerated weathering. Glossinesses, contact angles, surface free energies, thermal stability, and mechanical properties were investigated. The glossiness of the weathered PMMA was decreased with increasing exposure time. Contact angles and surface free energies were not overtly changed because the amount of oxygen on the surface was remained. PMMA was compounded with anti-block and antistatic agents using a co-rotating twin screw extruder to improve the durability. The PMMA composites showed better glossinesses after accelerated weathering while maintaining the contact angles, surface energy, thermal stability, and mechanical properties without significant changes.

Keywords

References

  1. B. H. Lee, Y.-W. Chang, and H. M. Lim, "Preparation and Characterizations of Polymethylmethacrylate (PMMA)/Acrylate Rubber (ACM) Blend for Light Diffuser Applications", Elast. Compos., 50, 49 (2015). https://doi.org/10.7473/EC.2015.50.1.049
  2. N. Y. Abu-Thabit and A. S. Hamdy, "Stimuli-responsive Polyelectrolyte Multilayers for fabrication of self-healing coatings - A review", Surface and Coatings Technology, 303, 406 (2016). https://doi.org/10.1016/j.surfcoat.2015.11.020
  3. A. Noreen, K. M. Zia, M. Zuber, S. Tabasum, and A. F. Zahoor, "Bio-based polyurethane: An efficient and environment friendly coating systems: A review", Progress in Organic Coatings, 91, 25 (2016). https://doi.org/10.1016/j.porgcoat.2015.11.018
  4. D. Hegemann, H. Brunner, and C. Oehr, "Plasma treatment of polymers for surface and adhesion improvement", Nucl. Instrum. Methods Phys. Res. B, 208, 281 (2003). https://doi.org/10.1016/S0168-583X(03)00644-X
  5. C. Jie-Rong, W. Xue-Yan, and W. Tomiji, "Wettability of poly(ethylene terephthalate) film treated with low-temperature plasma and their surface analysis by ESCA", J. Appl. polym. Sci., 72, 1327 (1999). https://doi.org/10.1002/(SICI)1097-4628(19990606)72:10<1327::AID-APP13>3.0.CO;2-0
  6. N. Inagaki, K. Narushim, N. Tuchida, and K. Miyazaki, "Surface characterization of plasma?modified poly (ethylene terephthalate) film surfaces", J. Polym. Sci. Part B: Polym Phys., 42, 3727 (2004). https://doi.org/10.1002/polb.20234
  7. S.-H. Kim, D.-J. Choi, J.-S. Lee, and H.-S. Choi, "Surface Characterization of the d-PMMA Thin Films Treated by Oxygen Plasma", Polymer(Korea), 33, 23 (2009).
  8. S. Okuji, M. Sekiya, M. Nakabayashi, H. Endo, N. Sakudo, and K. Nagai, "Surface modification of polymeric substrates by plasma-based ion implantation", Nucl. Instrum. Methods Phys. Res. B, 242, 353 (2006). https://doi.org/10.1016/j.nimb.2005.08.153
  9. K. Dworecki, M. Drabilc, T. Hasegawa, and S. Wasik, "Modification of polymer membranes by ion implantation", Nucl. Instrum. Methods Phys. Res. B, 225, 483 (2004). https://doi.org/10.1016/j.nimb.2004.05.024
  10. S. Suzer, A. Argun, O. Vatansever, and O. Aral, "XPS and water contact angle measurements on aged and corona-treated PP", J. App. Polym. Sci., 74, 1846 (1999). https://doi.org/10.1002/(SICI)1097-4628(19991114)74:7<1846::AID-APP29>3.0.CO;2-B
  11. Y.-J. Jang and J. Jang, " Surface Treatment and Dyeability of Poly(phenylene sulfide) Films by $UV/O_3$ Irradiation", Textile Coloration and Finishing, 23, 284 (2011). https://doi.org/10.5764/TCF.2011.23.4.284
  12. M.-S. Kim, Y.-J. Jang, and J. Jang, "Photo-oxidation and Dyeability of Poly Ketone by $UV/O_3$ Irradiation", Textile Coloration and Finishing, 25, 25 (2013). https://doi.org/10.5764/TCF.2013.25.1.25
  13. M. X. Ramirez, D. E. Hirt, and L. L. Wright, "AFM Characterization of Surface Segregated Erucamide and Behenamide", Nano Letters, 2, 9 (2002). https://doi.org/10.1021/nl015591l
  14. T. Textor and B. Mahltig, "A Sol-Gel based Surface Treatment for Preparation of Water Repellent Antistatic Textiles", Applied Surface Science, 256, 1668 (2010). https://doi.org/10.1016/j.apsusc.2009.09.091
  15. M. E. L. Wouters, D. P. Wolfs, M. C. van der Linde, J. H. P. Hovens, and A. H. A. Tinnemans, "Transparent UV Curable Antistatic Hybrid Coatings on Polycarbonate Prepared by the Sol-Gel Method", Prog. in Organic Coatings, 51, 312 (2004). https://doi.org/10.1016/j.porgcoat.2004.07.020
  16. M. Verma and L. Crewdson, "A Study of the Color Change of Automotive Coatings Subjected to Accelerated and Natural SAE Weathering Tests for Exterior Materials Durability", SAE Technical Paper 940856 (1994).
  17. D. K. Owens and R. C. Wendt, "Estimation of the Surface Free Energy of Polymers", J. Appl. Polym. Sci., 13, 1741 (1969). https://doi.org/10.1002/app.1969.070130815
  18. D. H. Kaelble, "Dispersion-Polar Surface Tension Properties of Organic Solids", J. Adhes., 2, 66 (1970). https://doi.org/10.1080/0021846708544582
  19. D. Janssen, R. De Palma, S. Verlaak, P. Heremans, and W. Dehaen, "Static solvent contact angle measurements, surface free energy and wettability determination of various self-assembled monolayers on silicon dioxide", Thin Solid Films, 515, 1433 (2006). https://doi.org/10.1016/j.tsf.2006.04.006