Journal of the Korean Ceramic Society (한국세라믹학회지)

The Korean Ceramic Society (한국세라믹학회)
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Stability of Zirconium Metal Organic Frameworks with 9,10- Dicarboxylic Acid Anthracene as Ligand

  • Xiao, Sheng-Bao (Anhui Key Laboratory of Advanced Building Materials, Anhui Jianzhu University) ;
  • Chen, Sai-Sai (Anhui Key Laboratory of Advanced Building Materials, Anhui Jianzhu University) ;
  • Liu, Jin (Anhui Key Laboratory of Advanced Building Materials, Anhui Jianzhu University) ;
  • Li, Zhen (School of Materials Science and Chemical Engineering, Anhui Jianzhu University) ;
  • Zhang, Feng-Jun (Anhui Key Laboratory of Advanced Building Materials, Anhui Jianzhu University) ;
  • Wang, Xian-Biao (Anhui Key Laboratory of Advanced Building Materials, Anhui Jianzhu University) ;
  • Oh, Won-Chun (Department of Advanced Materials Science & Engineering, Hanseo University)
  • Received : 2015.10.22
  • Accepted : 2016.02.04
  • Published : 2016.03.31
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Abstract

With high specific surface area and pore structural diversity, MOFs show important applications in gas storage, catalysis, sensing, separation, and biomedicine. However, the stability of the structure of MOFs has restricted their application and development. In this study, zirconium metal organic frameworks with 9,10-dicarboxylic acid anthracene as ligand, named UIO-66 ($H_2DCA$), were synthesized and their properties and structures were characterized by XRD, SEM, and $N_2$ adsorption. We focus on the stability of the structure of UIO-66 ($H_2DCA$) under different conditions (acid, alkali, and water). The structural changes or ruins of UIO-66 ($H_2DCA$) were traced by means of XRD, TG, and FT-IR under different conditions. The results show that the UIO-66 ($H_2DCA$) materials are stable at 583 K, and that this structural stability is greatly influenced by different types of acid and alkali compounds. Importantly, we found that the structures maintain their stability in environments of nitric acid, triethylamine, and boiling water.

Keywords

References

  1. O. M. Yaghi, N. W. Ockwig, and H. K. Chae, "Reticular Synthesis and the Design of New Materials," Nature, 423 [6941] 705-14 (2003). https://doi.org/10.1038/nature01650
  2. H. Huang, W. Zhang, and D. Liu, "Effect of Temperature on Gas Adsorption and Separation in ZIF-8: a Combined Experimental and Molecular Simulation Study," Chem. Eng. Sci., 66 6297-305 (2011). https://doi.org/10.1016/j.ces.2011.09.009
  3. F. J. Xu, X. D. Hou, and M. J. Sepaniak, "Metal-Organic Framework MIL-53(Fe) for Highly Selective and Ultrasensitive Direct Sensing of $MeHg^+$," Chem. Comm., 49 [41] 4670-72 (2013). https://doi.org/10.1039/c3cc40821c
  4. J. A. Greathouse and M.D. Allendorf, "The Interaction of Water with MOF-5 Simulated by Molecular Dynamics," J. Am. Chem. Soc., 128 [33] 10678-79 (2006). https://doi.org/10.1021/ja063506b
  5. D. Saha and S. Deng, "Structural Stability of Metal Organic FrameworkMOF-177," J. Phys. Chem. Lett., 1 [1] 73-8 (2010). https://doi.org/10.1021/jz900028u
  6. J. H. Cavka, S. Jakobsen, and U. Olsbye, "A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability," J. Am. Chem. Soc., 130 13850-51 (2008). https://doi.org/10.1021/ja8057953
  7. M. Kandiah, M. H. Nilsen, and S.Usseglio, "Synthesis and Stability of Tagged UiO-66 Zr-MOFs," Chem. Mater., 22 [24] 6632-40 (2010). https://doi.org/10.1021/cm102601v
  8. S. J. Garibay and S. M. Cohen, "Isoreticular Synthesis and Modification of Frameworks with the UiO-66 Topology," Chem. Comm., 46 7700-2 (2010). https://doi.org/10.1039/c0cc02990d
  9. Y. Huang, W. Qin, Z. Li, and Y. Li, "Enhanced Stability and $CO_2$ Affinity of a UiO-66 Type Metal-Organic Framework Decorated with Dimethyl Groups," Dalton Trans., 41 [31] 9283-85 (2012). https://doi.org/10.1039/c2dt30950e
  10. J. Ren, N. M. Musyoka, H. W. Langmi, B. C. North, M. Mathe, X. Kang, and S. Liao, "Hydrogen Storage in Zr-Fumarate MOF," Int. J. Hydrogen Energ., 40 [33] 10542-46 (2015). https://doi.org/10.1016/j.ijhydene.2015.06.109
  11. X. Liu, N. K. Demir, Z. Wu, and K. Li, "Highly Water-Stable Zirconium Metal-Organic Framework UiO-66 Membranes Supported on Alumina Hollow Fibers for Desalination," J. Am. Chem. Soc., 137 6999-7002 (2015). https://doi.org/10.1021/jacs.5b02276
  12. C. G. Piscopo, A. Polyzoidis, and M. Schwarzer, "Stability of UiO-66 under Acidic Treatment: Opportunities and Limitations for Post-Synthetic Modifications," Microporous Mater., 208 30-5 (2015). https://doi.org/10.1016/j.micromeso.2015.01.032
  13. T. Sagara, J. Klassen, J. Ortony, and E. Ganz, "Binding Energies of Hydrogen Molecules to Isoreticular Metal -Organic Framework Materials," J. Chem. Phys., 123 [1] 014701-16 (2005). https://doi.org/10.1063/1.1944730
  14. U. Herrmann, B. Tuemmler, G. Maass, P. K. T. Mew, and F. Voegtle, "Anthracenoyl Crown Ethers and Cryptands as Fluorescent Probes for Solid-Phase Transitions of Phosphatidylcholines: Syntheses and Phospholipid Membrane Studied," Biochem., 23 [18] 4059-60 (1984). https://doi.org/10.1021/bi00313a008
  15. G. Ferey, C. Serre, and C. Mellot-Draznieks, "A Hybrid Solid with Giant Pores Prepared by Acombination of Targeted Chemistry, Simulation, and Powder Diffraction," Angew. Chem. Int. Ed., 43 [46] 6296-301(2004). https://doi.org/10.1002/anie.200460592
  16. P. Horcajada, C. Serre, and G. Maurin, "Flexible Porous Metal-Organic Frameworks for a Controlled Drug Delivery," J. Am.Chem. Soc., 130 6774-80 (2008). https://doi.org/10.1021/ja710973k
  17. M. Kandiah, M. H. Nilsen, and S. Usseglio, "Synthesis and Stability of Tagged UiO-66 Zr-MOFs," Chem. Mater., 22 [24] 6632-40 (2010). https://doi.org/10.1021/cm102601v
  18. L. Zhang and Y. H. Hu, "A Systematic Investigation of Decomposition of Nano $Zn_4O$ $(C_8H_4O_4)_3$ Metal-Organic Frameworks," J. Phys. Chem. C, 114 [6] 2566-72 (2010). https://doi.org/10.1021/jp911043r
  19. M. Bin and S. W. Krista, "Thermal Analysis and Heat Capacity Study of Metal Organic Frameworks," J. Phys. Chem. C, 115 22748-54 (2011). https://doi.org/10.1021/jp205538a
  20. K. S. Park, J. Y. Choi, and R. D. Huang, "Exceptional Chemical and Thermal Stability of Zeolitic Imidazolate Frameworks," Proc. Natl. Acad. Sci. U.S.A., 103 [27] 10186-91 (2006). https://doi.org/10.1073/pnas.0602439103

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