DOI QR코드

DOI QR Code

Aroma Characteristics of Acai Berry

아사이베리의 향기성분 특성 연구

  • 임승희 (단국대학교 융합기술대학 식품공학과) ;
  • 남희섭 (동원 F&B) ;
  • 백형희 (단국대학교 융합기술대학 식품공학과)
  • Received : 2016.03.08
  • Accepted : 2016.04.15
  • Published : 2016.04.30

Abstract

The objective of this study was to identify the volatile compounds and aroma-active compounds from acai berry (Euterpe oleracea). Volatiles were isolated by high vacuum distillation using solvent-assisted flavor evaporation (SAFE) and liquid-liquid continuous extraction (LLCE). To identify the characteristic aroma-active compounds of acai berry, gas chromatography-mass spectrometry-olfactometry was used. Aroma-active compounds were evaluated by aroma extract dilution analysis (AEDA). A total of 51 and 54 volatile compounds from acai berry were identified from SAFE and LLCE extracts, respectively. Alcohols were confirmed to be important volatile compounds in acai berry, as the major volatile compounds were 2-phenylethanol, (Z)-3-hexenol, and benzyl alcohol. ${\beta}-Damascenone$ (berry, rose), trans-linalool oxide (woody), (Z)-3-hexenol (grass), and 2-phenylethanol (rose, honey) were considered the aroma-active compounds in acai berry. The most intense aroma-active compound of acai berry was ${\beta}-damascenone$.

아사이베리의 특징적인 향기성분을 동정하기 위하여 SAFE와 LLCE를 이용하여 추출하고 GC-MS와 GC-O로 분석하였다. 아사이베리에서 공통적으로 동정된 휘발성 향기성분은 2-phenylethanol, (Z)-3-hexenol과 benzyl alcohol 등으로 함량이 높았으며 8-hydroxy linalool과 maltol은 LLCE에서 높은 함량을 나타내었다. 아사이베리의 휘발성 향기성분은 알코올류가 가장 함량이 높았으며 아사이베리의 중요한 휘발성 향기성분이라고 생각된다. 아사이베리의 향 활성 화합물 중 ${\beta}-damascenone$은 SAFE에서 $log_2FD=4$와 LLCE에서 $log_2FD=1$을 나타냈으며 장미향과 베리향 특성을 나타내어 아사이베리의 특징적인 향에 기여하는 중요한 화합물이라 생각된다. 또한 trans-linalool oxide, (Z)-3-hexenol과 2-phenylethanol 등이 아사이베리의 향 활성 화합물로 동정되었다.

Keywords

References

  1. Kang J, Li Z, Wu T, Jensen GS, Schauss AG, Wu X. Anti-oxidant capacities of flavonoid compounds isolated from acai pulp (Euterpe oleracea Mart.). Food Chem. 122: 610-617 (2010) https://doi.org/10.1016/j.foodchem.2010.03.020
  2. Marcason W. What is the acai berry and are there health benefits? J. Am. Diet. Assoc. 109: 1968 (2009) https://doi.org/10.1016/j.jada.2009.09.017
  3. Jeong CH, Choi SG, Heo HJ. Analysis of nutritional compositions and antioxidative activities of Korean commercial blueberry and raspberry. J. Korean Soc. Food Sci. Nutr. 37: 1375-1381 (2008) https://doi.org/10.3746/jkfn.2008.37.11.1375
  4. Spada PDS, Dani C, Bortolini GV, Funchal C, Henriques JAP, Salvador M. Frozen fruit pulp of Euterpe oleraceae Mart. (Acai) prevents hydrogen peroxide-induced damage in the cerebral cortex, cerebellum, and hippocampus of rats. J. Med. Food 12: 1084-1088 (2009) https://doi.org/10.1089/jmf.2008.0236
  5. Hertog MGL, Feskens EJM, Kromhout D. Antioxidant flavonols and coronary heart disease risk. Lancet 349: 699 (1997)
  6. Schauss AG. Acai (Euterpe oleracea Mart.): A macro and nutrient rich palm fruit from the Amazon rain forest with demonstrated bioactivities in vitro and in vivo. pp. 479-490. In: Bioactive Foods in Promoting Health. Watson RR, Preedy VR(eds). Academic Press, New York, NY, USA (2010)
  7. Schauss AG, Wu X, Prior RL, Ou B, Huang D, Owens J. Agarwal A, Jensen GS, Hart AN, Shanbrom E. Antioxidant capacity and other bioactivities of the freeze-dried Amazonian palm berry, Euterpe oleraceae Mart. (acai). J. Agr. Food Chem. 54: 8604-8610 (2006) https://doi.org/10.1021/jf0609779
  8. Jensen GS, Wu X, Patterson KM, Barnes J, Carter SG, Scherwitz L, Beaman R, Endres JR, Schauss AG. In vitro and in vivo antioxidant and anti-inflammatory capacities of an antioxidant-rich fruit and berry juice blend. Results of a pilot and randomized, double-blinded, placebo-controlled, crossover study. J. Agr. Food Chem. 56: 8326-8333 (2008) https://doi.org/10.1021/jf8016157
  9. Chung HJ. Physiological activity of acai berry (Euterpe oleracea Mart.) extracted with different solvents. J. Korean Soc. Food Cult. 27: 75-81 (2012) https://doi.org/10.7318/KJFC.2012.27.1.075
  10. Kraujalyte V, Leitner E, Venskutonis PR. Characterization of Aronia melanocarpa volatiles by headspace solid-phase microextraction (HS-SPME), simultaneous distillation/extraction (SDE), and gas chromatography-olfactometry (GC-O) methods. J. Agr. Food Chem. 61: 4728-4736 (2013) https://doi.org/10.1021/jf400152x
  11. Belitz HD, Grosch W. Fruits and fruit products. pp. 748-800. In: Food Chemistry. 2nd ed. Belitz HD, Grosch W (eds). Springer-Verlag Berlin Heidelberg, New York, NY, USA (1999)
  12. Klesk K, Qian M, Martin RR. Aroma extract dilution analysis of cv. Meeker (Rubusidaeus L.) red raspberries from Oregon and Washington. J. Agr. Food Chem. 52: 5155-5161 (2004) https://doi.org/10.1021/jf0498721
  13. Flamini R. Some advances in the knowledge of grape, wine and distillates chemistry as achieved by mass spectrometry. J. Mass Spectrom. 40: 705-713 (2005) https://doi.org/10.1002/jms.887
  14. Selli S, Canbas A, Varlet V, Kelebek H, Prost C, Serot T. Characterization of the most odor-active volatiles of orange wine made from a Turkish cv. Kozan (Citrus sinensis L. Osbeck). J. Agr. Food Chem. 56: 227-234 (2008) https://doi.org/10.1021/jf072231w
  15. Mordi RC, Walton JC, Burton GW, Hughes L, Ingold KU, Lindsay DA. Exploratory study of ${\beta}$-carotene autoxidation. Tetrahedron Lett. 32: 4203-4206 (1991) https://doi.org/10.1016/S0040-4039(00)79905-9
  16. Semmelroch P, Laskawy G, Blank I, Grosch W. Determination of potent odorants in roasted coffee by stable isotope dilution assays. Flavor Frag. J. 10: 1-7 (1995) https://doi.org/10.1002/ffj.2730100102
  17. Klesk K, Qian M. Aroma extract dilution analysis of cv. Marion (Rubus spp. hyb) and cv. Evergreen (R. laciniatus L.) blackberries. J. Agr. Food Chem. 51: 3436-3441 (2003) https://doi.org/10.1021/jf0262209
  18. Ong PKC, Acree TE, Lavin EH. Characterization of volatiles in rambutan fruit (Nephelium lappaceum L.). J. Agr. Food Chem. 46: 611-615 (1998) https://doi.org/10.1021/jf970665t
  19. Braell PA, Acree TE, Butts RM. Zhou PG. Isolation of nonvolatile precursors of ${\beta}$-damascenone from grapes using charm analysis. pp. 75-84. In: Biogeneration of Aromas. Parliment TH, Croteau R (eds). American Chemical Society, Washington DC, USA (1986)
  20. Cunningham DG, Acree TE. Barnard J, Butts RM, Braell PA. Charm analysis of apple volatiles. Food Chem. 19: 137-147 (1986) https://doi.org/10.1016/0308-8146(86)90107-X
  21. Buttery RG. Teranishi R, Ling LC, Turnbaugh JG. Quantitative and sensory studies on tomato paste volatiles. J. Agr. Food Chem. 38: 336-340 (1990) https://doi.org/10.1021/jf00091a074