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Impact of hexeneuronic acid on kappa number determination in 3 different bamboo soda-anthraquinone(AQ) pulps

대나무류 3종 소다-안트라퀴논 펄프 내 존재하는 hexeneuronic acid가 카파 값에 미치는 영향

  • Song, Woo-Yong (Department of Forest Products and Engineering, Chungbuk National University) ;
  • Lee, Kyu-Seong (Department of Forest Products and Engineering, Chungbuk National University) ;
  • Lee, Suk-Gyeong (Department of Forest Products and Engineering, Chungbuk National University) ;
  • Shin, Soo-Jeong (Department of Forest Products and Engineering, Chungbuk National University)
  • Received : 2016.05.25
  • Accepted : 2016.06.20
  • Published : 2016.06.30

Abstract

Hexeneuronic acid in soda-anthraquinone(AQ) pulps from Moso bamboo(Phyllostachys pubescebs), Timber bamboo(Phyllostachys bambusoides) and Henon bamboo(Phyllostachys nigra var. henonis) was investigated with mercuric chloride hydrolysis and UV spectroscopic quantification. Concentration of hexeneuronic acid in bamboo pulps was $36.6-45.4{\mu}mol/g$, which contributed to 3.1-3.9 value increase of kappa number. Lower concentration of 4-O-methylglucuronic acid in bamboo xylan contributed to lower hexeneruonic acid content in bamboo pulps than those of hardwood(yellow poplar or eucalyptus) but higher than softwood(red pine).

Keywords

References

  1. Scyrlock, J. M.O., Dayton, D. C., and Hames, B., Bamboo: an overlooked biomass resource?, Biomass and Bioenergy 19: 229-244(2000). https://doi.org/10.1016/S0961-9534(00)00038-6
  2. Yen, T. M., Ji, Y. J., and Lee, J. S., Estimating biomass production and carbon storage for a fast-growing makino bamboo (Phyllostachys makinoi) plant based on the diameter distribution model, Forest Ecology and Management 260: 339-344(2010). https://doi.org/10.1016/j.foreco.2010.04.021
  3. Peng, P., Peng, F., Bian, J., Xu, F., Sun, R.-C., and Kennedy, J. F., Isolation and structural characterization of hemicelluloses from the bamboo species Phyllostachys incarnata Wen, Carbohydrate Polymers 86: 883-890(2011). https://doi.org/10.1016/j.carbpol.2011.05.038
  4. Alves, E. F., Bose, S. K., Francis, R. C., Coledette, J. L., Lakovlev, M., and Heiningen, A. V., Carbohydrate composition of eucalyptus, bagasse and bamboo by a combination of methods, Carbohydrate Polymers 82: 1097-1101(2010). https://doi.org/10.1016/j.carbpol.2010.06.038
  5. Shin, S. J., Schroeder, L. R., and Lai, Y. Z., Impact of residual extractives on lignin determination in kraft pulps, Journal of Wood Chemistry and Technology 24(2): 139-151(2004). https://doi.org/10.1081/WCT-200026567
  6. Shin, S. J., Cho, N. S., and Lai, Y. Z., Residual extractives in aspen kraft pulps and their impact on kappa number and Klason lignin determination, Journal of Wood Science 53: 494-497(2007). https://doi.org/10.1007/s10086-007-0894-8
  7. Li, J., and Gellerstedt, G., The contribution of kappa number from hexeneuronic acid groups in pulp xylan, Carbohydrate Research 302: 213-218(1997). https://doi.org/10.1016/S0008-6215(97)00125-0
  8. Clayton, D. W., The alkaline degradation of some hardwood 4-O-methylglucuronoxyaln, Svenck Papperstidning 66: 115-124(1963).
  9. Ikeda, T., Tominura, Y., Magara, K., Ishihara, M., and Hosoya, S., Sulfuric acid bleaching of kraft pulp III: Reactivity of kraft pulping-resistant structures under acidic conditions, Journal of Wood Science 45: 417-424(1999). https://doi.org/10.1007/BF01177915
  10. Ikeda, T., Tominura, Y., Magara, K., Ishihara, M., and Hosoya, S., Sulfuric acid bleaching of kraft pulp II: Behavior of lignin and carbohydarte during sulfuric acid bleaching, Journal of Wood Science 45: 313-318(1999). https://doi.org/10.1007/BF00833496
  11. Ikeda, T., Hosoya, S., Tomimura, Y., Magara, K., and Takano, I., Sulfuric acid bleaching of kraft pulp I: Bleaching of hardwood and softwood kraft pulps, Journal of Wood Science 45: 233-237(1999). https://doi.org/10.1007/BF01177731
  12. Teleman, A., Harhunpaa, V., Tenkanen, M., Buchjert, J., HJausalo, T., Drakenberg, T., and Vuorinen, T., Characterization of 4-deoxy-beta-L-threo-hex-4-enopyranosyluronic acid attached to xylan in pine kraft pulp and pulping liquor by $^1H$ and $^{13}CNMR$ spectroscopy, CarbohydrateRes 272: 55-71(1995). https://doi.org/10.1016/0008-6215(95)96873-M
  13. Lee, K. S., Song, W. Y., and Shin, S. J., Elucidating soda and soda-anthraquinone pulping characteristics of Korean bamboo species, Journal of Korean TAPPI 48(3): 44-50(2016).
  14. Sung, Y. J., Lee, J. W., Kim, S. B., and Shin, S. J., Comparison of the soda-anthraquinone pulping properties between imported Eucalyptus mixture chips and domestic yellow poplar (Liriodendron tulipifera)chips. Journal of Korean TAPPI 10(3): 22-27(2010).
  15. Seca, A. M., Cavaleiro, J. A. S., Domingues, F. M. J., Silvestre, A. J. D., Evtuguin, D., and Neto, C. P., Structural characterization of the bark and core lignins from kenaf (Hibiscus cannabinus), Journal of Agricultural and Food Chemistry 46: 3100-3108(1998). https://doi.org/10.1021/jf9801320
  16. Baptista, C., Robert, D., and Duarte, A. P., Effect of pulping conditions on lignin structure from maritime pine kraft pulps, Chemical Engineering Journal 121: 153-158(2006). https://doi.org/10.1016/j.cej.2006.05.002
  17. Dence, C. W., The Determination of Lignin, In Methods in Lignin Chemistry, Lin, S. Y., and Dence, C. W., (eds.), Springer-Verlag, New York, p. 33-61(1992).
  18. Gellerstedt, G., and Li, J., An HPLC method for the quantitative determination of hexenueronic acid groups in chemical pulps. Carbohydrate Research 294: 41-51(1996). https://doi.org/10.1016/S0008-6215(96)90615-1
  19. Chai, X. S., Yoon, S. H., Zhu, J. Y., and Lim, J., The fate of hexenuronic acid group during alkaline pulping of loblloy pine. Journal of Pulp and Paper Science 27(12): 407-411(2001).
  20. Chai, X. S., Luo, Q., Yoon, S. H., and Zhu, J. Y., The fate of hexenuronic acid group during kraft pulping of hardwoods. Journal of Pulp and Paper Science 27(12): 403-406(2001).
  21. Shin, S. J., Sung, Y. J., and Park, J. M., Impact of hexeneuronic acid to kappa number determination in hardwood chemical pulps, Journal of Korea TAPPI 42(2): 35-40(2010).
  22. Chal, X. S., Zhu, J. Y., and Li, J., A simple and rapid method to determine hexeneuronic acid groups in chemical pulps, Journal of Pulp and Paper Science 27(5): 165-170(2001).