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Effect of Transition Metal Oxides Addition on Yttria - stabilized Zirconia for improving Physical and Mechanical Properties

  • Received : 2016.08.16
  • Accepted : 2016.09.12
  • Published : 2016.09.30

Abstract

Mechanical properties of Y2O3-containing tetragonal ZrO2 polycrystals(Y-TZP) were investigated. Several additives were used to modify the hardness and fracture toughness of Y-TZP. The effects of these individual additives were discussed and their interactions were also analysed. Each additive, such as CoO, Fe2O3, MnO2 was found to deteriorate the mechanical properties of Y-TZP when it was used singly. But the fracture toughness of Y-TZP was significantly improved when these additives and Al2O3 were added in combination at a certain ratio. The addition of CoO, Fe2O3 and MnO2 into Y-TZP resulted in the more complex behavior of fracture toughness and hardness. The specimen with 1.5 wt%-Fe2O3, 3.0 wt% -Al2O3 and 1.5 wt%-CoO showed the monoclinic to tetragonal phase ratio of 18% and the highest toughness of $10.8MPa{\cdot}m1/2$ with Vickers hardness of 1201 kgf/mm2. However, the toughness decreased as the ratio increased and macrocracks developed beyond the ratio of 25%. Sample No. 16 is improved high Physical and Mechanical Properties.

Keywords

References

  1. O. Yamamoto and Y. Taketa, "Electrical Conductivity of Polycrystalline Tetragonal Zirconia $ZrO_2-M_2O_3$ (M=Sc, Y, Yb)," J. Mater. Sci. Lett., 8, 1989, pp. 198-200. https://doi.org/10.1007/BF00730724
  2. P. Duran and P. Recio, "Preparation, Sintering and Properties of Translucent $Er_2O_3$- Doped Tetragonal Zirconia," J.Am. Ceram. Soc., 72(11), 1989, pp. 2088-2093. https://doi.org/10.1111/j.1151-2916.1989.tb06036.x
  3. T. Masaki, "Mechanical Properties of Toughened $ZrO_2-Y_2O_3$ Ceramics," J.Am.Ceram. Soc., 69(8), 1986, pp. 638-640. https://doi.org/10.1111/j.1151-2916.1986.tb04823.x
  4. E.C. Subbarao, "Zirconia-an Overview, in Science and Technology of Zirconia," edited by A.H.Heuer and L.W. Hobbs, The American Ceramic Society, Columbus, Ohio, 1981, pp. 1-24.
  5. W.Pada and K.Haberko, "Zirconia Stabilized with a Mixture of the Rare Earth Oxides," J.Eur.Ceram. Soc., 10, 1992, pp. 453-459. https://doi.org/10.1016/0955-2219(92)90020-E
  6. M.V. Swain and L.R. Rose, "Strength Limitation of Transformation Toughened Zirconia Alloys," J. Am. Ceram. Soc., 69(7), 1986, pp. 511-518. https://doi.org/10.1111/j.1151-2916.1986.tb04785.x
  7. D.Michel, L.Mazerolles and M.Perezjorba, "Fracture of Metastable Tetragonal Zirconia Crystals," J.Mater. Sci, 18, 1983, pp. 2618-2628. https://doi.org/10.1007/BF00547578
  8. 정의영, "반도체 산업의 성과 분석을 통한 메모리 산업의 미래 전략 도출," 디지털산업정보학회, 디지털산업정보학회논문지, 제11권, 제4호, 2015, pp. 1-12. https://doi.org/10.17662/ksdim.2015.11.4.001
  9. 박상혁, 박정선, 이명관, "성공적인 6차산업을 위한 가치사슬 모형과 빅데이터 활용 방안," 디지털산업정보학회, 디지털산업정보학회논문지, 제11권, 제2호, 2015, pp. 141-152. https://doi.org/10.17662/KSDIM.2015.11.2.141
  10. 김정주, "부분안정화 지르코니아 요업체의 상변태에 따른 미세구조 및 기계적 성질," 요업재료의 과학과 기술, 3(3), 1988, pp. 217-223.
  11. J. H. Lee, Y.B. Lee, Y.W. Kim and H.C. Park, "Fabrication and Characteristics of Y-TZP/Ce-TZP Structural Ceramics," J. Kor. Ceram. Soc., 33(10), 1996, pp. 1177-1185.