한국수소및신에너지학회논문집 (Transactions of the Korean hydrogen and new energy society)

  • 제28권1호
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  • Pages.77-84
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  • 2017
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  • 1738-7264(pISSN)
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  • 2288-7407(eISSN)
한국수소및신에너지학회 (The Korean Hydrogen and New Energy Society)
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저에너지 UV 경화형 무용제 소재 개발

Solventless UV Curable Material for Low Cost System

  • 투고 : 2016.12.13
  • 심사 : 2017.02.28
  • 발행 : 2017.02.28
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초록

In this study, Poly-urethane acrylate (PUA) was synthesized by the reaction between Polycaprolactonetriol (PCLT) and Isophorone dissocyanate (IPDI) and hybridized with inorganic materials. Tetraethylortho silicate (TEOS) and nano clay (Closite 20A) were used as inorganic particles. For the hybridization of TEOS with PUA, sol-gel method is used, in which TEOS is made into spherical particle in the firsthand. In the case of Nano clay, hybridization is carried out through the dispersion as Nano clay has a layered structure. The solution of PUA hybrid was made into a film after UV curing and its thermo and electrical properties were measured. The experimental analysis and result demonstrate that the PUA hybrid shows an improved thermal properties and lower dielectric constant than that of the non-hybrid PUA. The trend of improved properties was different depending on structure of inorganic materials.

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참고문헌

  1. E. Dzunuzovic, S. Tasic, B. Bozic, D. Babic and B. Dunjic, "UV-Curable Hyperbranched Urethane Acrylate Oligomers Containing Soybean Fatty Acids", Prog. Org. Coat., Vol. 52, 2005, p. 136. https://doi.org/10.1016/j.porgcoat.2004.10.003
  2. J. Lange, E. Stenroos and E. Malmstrom, "Barrier Coatings for Flexible Packaging Based on Hyperbranched Resins", Polymer, Vol. 42, 2001, p. 7403. https://doi.org/10.1016/S0032-3861(01)00189-6
  3. X. Chen, Y. Hu, L Song and C. Jiao, "Preparation and Thermal Properties of a Novel UV-CUred Star Polyurethane Acrylate Coating", Polym. Adv. Technol., Vol. 19, 2008, p. 322. https://doi.org/10.1002/pat.995
  4. J. Seo, E.-S. Jang, J.-H. Song, S. Choi, S. B. Khan and H. Han, "Preparation and Properties of Poly(uretane acrylate) Films for Ultraviolet-Curable Coatings", J. Appl. Polym. Sci., Vol. 118, 2010, p. 2454.
  5. V. Waterlot, D. Couturier and C. Waterlot, "Structure and Physical Properties in Crosslinked Polyurethanes", J. Appl. Polym. Sci., Vol. 119, 2011, p. 1742. https://doi.org/10.1002/app.32874
  6. S. Gogolewski, "Selected Topics in Biomedical Polyurethanes. A Review", Colloid Polym. Sci., Vol. 267, 1989, p. 757. https://doi.org/10.1007/BF01410115
  7. B. K. Kim and J. C. Lee, "Waterborne Polyurethane and Their Properties", J. Polym. Sci. Part A Polym. Chem., Vol. 34, 1996, p. 1095. https://doi.org/10.1002/(SICI)1099-0518(19960430)34:6<1095::AID-POLA19>3.0.CO;2-2
  8. H. L. Manock, "New Developments in Polyurethane and PU/acylic Dispersions", Pigment Resin Technol., Vol. 29, 2000, p. 143. https://doi.org/10.1108/03699420010334295
  9. Y. J. Du, M. Damron, G. Tang, H. Zheng, C.-J. Chu and H. Osbome, "Inorganic/organic Hybrid Coatings for Aircraft Aluminum Alloy Substrates", Prog. Org. Coat., Vol. 41, 2001, p. 226. https://doi.org/10.1016/S0300-9440(01)00133-3
  10. G. Leder, T. ladwig, V. Valter, S. Frahn and J. Meyer, "New Effects of Fumed Silica in Modern Coatings", Prog. Org. Coat., Vol. 45, 2002, p. 139. https://doi.org/10.1016/S0300-9440(02)00049-8
  11. J. L. Luna-Xavier, A. Guyot and E. Bourgeat-Lami, "Synthesis and Characterization of Silica/poly(methyl methacrylate) Nanocomposite Latex Particles through Emulsion Polymerization using a Cationic Azo Initiator", J. Colloid Interface Sci., Vol. 250, 2002, p. 82. https://doi.org/10.1006/jcis.2002.8310
  12. S. Frings, H. A. Meinema, C. F. Nostrum and R. Linde, "Organic-inorganic Hybrid Coatings for Coil Coating Application Based on Polyesters and Tetraethoxysilane", Prog. Org. Coat., Vol. 33, 1998, p. 126. https://doi.org/10.1016/S0300-9440(98)00045-9
  13. J. Zou, W. Shi and X. Hong, "Characterization and Properties of a Novel Organic-inorganic Hybrid Based on Hyperbranched Aliphatic Polyester Prepared via Sol-gel Process", Compos. Part A Appl. Sci. Manuf., Vol. 36, 2005, p. 631. https://doi.org/10.1016/j.compositesa.2004.08.001
  14. J. M. Yeh, S. J. Liou, C. Y. Lai, P. C. Wu and T. Y. Tsai, "Enhancement of Corrosion Protection Effect in Polyaniline via the Formation of Polyaniline-Clay Nanocompoiste Materials", Chem. Mater., Vol. 13, 2001, p. 1131. https://doi.org/10.1021/cm000938r
  15. Y. H. Yu, J. M. Yeh, S. J. Liou and Y. P. Chang, "Organo-Soluble Polyimide (TBAPP-OPDA)/Clay Nanocomposite Materials with Advanced Anticorrosive Properties Prepared from Solution Dispersion Technique", Acta Materialia, Vol. 52, 2004, p. 475. https://doi.org/10.1016/j.actamat.2003.09.031
  16. J. Seo, E.-S. Jang, J.-H. Song, S. Choi, S. B. Khan and H. Han, "Preparation and Properties of Poly(urethane acrylate) Films for Ultraviolet-curable Coatings", J. Appl. Polym. Sci., Vol. 118, 2010, . 2454.
  17. V. D. Athawale and M. A. Kulkami, "Preparation and Properties of Urethane/acrylate Composite by Emulsion Polymerization Technique", Prog. Org. Coat., Vol. 65, 2009, p. 392. https://doi.org/10.1016/j.porgcoat.2009.03.004
  18. J.-S. Choi, J. Seo, S. B. Khan, E. S. Jang and H. Han, "Effect of Acrylic Acid on the Physical Properties of UV-Cured Poly(urethane acrylate-co-acrylic acid) Films for Metal Coating", Prog. Org. Coat., Vol. 71, 2011, p. 110. https://doi.org/10.1016/j.porgcoat.2011.01.005
  19. E. S. Jang, S. B. Khan, J. Seo, K. Akhtar, J. Choi, K. I. Kim and H. Han, "Synthesis and Characterization of Novel UV-Curable PU-Si Hybrids: Influence of Silica on Thermal, Mechanical, and Water Sorption Properties of Polyurethane Acrylates", Macromoleular Research, Vol. 19, 2011, p. 1006. https://doi.org/10.1007/s13233-011-1002-x
  20. S. B. Khan, J. Seo, E. S. Jang, J. Choi, S. Choi and H. Han, "Injluence of Organically Modified Layered Silicates on Thermal and Water Absorption Properties of PPC/organo-clay Nanohybrid", Mem. J., Vol. 19, 2009, p. 341.
  21. S. B. Khan, M. M. Rahman, E. S. Jang, K. Akhtar and H. Han, "Special Susceptive Aqueous Ammonia Chemi-sensor: Extended Applications of Novel UV-curable Polyurethaneclay Nonahybrid", Talanta, Vol. 84, 2011, p. 1005. https://doi.org/10.1016/j.talanta.2011.02.036
  22. S. B. Khan, J. Seo, E. S. Jang, K. Akhtar, K. I. Kim and H. Han, "Synthesis and Characterization of Novel PPC-Silica Hybrid with Improved Thermal, Mechanical, and Water Sorption Properties", Macromolecular Research, Vol. 19, 2011, p. 876. https://doi.org/10.1007/s13233-011-0913-x
  23. H. Zhou, Y. Chen, H. Fan, H. Shi, Z., Luo and B. Shi, "The Polyurethane/SiO2 Nano-hybrid Membrane with Temperature Sensitivity for Water Vapor Permeation", J. Memb. Sci., Vol. 318, 2008, p. 71. https://doi.org/10.1016/j.memsci.2008.02.024
  24. K. Yano, A. Usuki, A. Okada, T. Kurauchi and O. Kamigaito, "Synthesis and Properties of Polyimide-clay Hybrid", J. Polym. Sci. Part A Polym. Chem., Vol. 31, 1993, p. 2493. https://doi.org/10.1002/pola.1993.080311009
  25. T. C. Huang, C. F. Hsieh, T. C. Yeh, C. L. Lai, M. H. Tsai and J. M. Yeh, "Comparative Studies on Corrosion Protection Properties of Polyimide-silica and Polyimide-clay Composite Materials", J. Appl. Polym. Sci., Vol. 119, 2011, p. 548. https://doi.org/10.1002/app.32669
  26. H. Liu, C. Han and L. Dong, "Study of the Biodegradable Poly(${\varepsilon}$-caprolactone)/clay Nanocomposite Foams", J. Appl. Polym. Sci., Vol. 115, p. 3120.
  27. S. Chakraborty, R. Sengupta, S. Dasgupta, R. Mukhopadhyay, S. Bandyopadhyay, M. Joshi and S. C. Ameta, "Synthesis and Characterization of in situ Sodium-activated and Organomodified Bentonite Clay/styrene-butadiene Rubber Nanocomposites by a Latex Blending Technique", J. Appl. Polym. Sci., Vol. 113, 2009, p. 1316. https://doi.org/10.1002/app.30146
  28. G. Bonilla, M. Martinez, A. M. Mendoze and J.-M. Widmaier, "Ternary Interpenetratinig Networks of Polyurethanepoly (methyl methacrylate)-silica: Preparation by the Sol-gel Process and Characterization of Films", Eur. Polym. J., Vol. 42, 2006, p. 2977. https://doi.org/10.1016/j.eurpolymj.2006.07.011
  29. E. S. Jang, S. B. Khan, J. Seo, Y. H. Nam, W. J. Choi, K. Akhtar and H. Han, "Synthesis and Characterziation of Novel UV-Curable Polyurethane-clay Nanohybrid: Injluence of Organically Modified Layered Silicates on the Properties of Polyurethane", Prog. Org. Coat., Vol. 71, 2011, p. 36. https://doi.org/10.1016/j.porgcoat.2010.12.007
  30. J. Xu, W. Pang and W. Shi, "Synthesis of UV-curable Organic-inorganic Hybrid Urethane Acrylates and Properties of Cured Films", Thin Solid Films, Vol. 514, 2006, p. 69. https://doi.org/10.1016/j.tsf.2006.02.032
  31. P. Liu and Z. Su, "Thermal Stabilities of Polystyrene/silica Hybrid Nanocomposites via Microwave-assisted in situ Polymerization", Mater. Chem. Phys., Vol. 94, 2005, p. 412. https://doi.org/10.1016/j.matchemphys.2005.05.023
  32. R. S. Mishra, A. K. Mishra and K. V. S. N. Raju, "Synthesis and Property Study of UV-curable Hyperbranched Polyurethane acrylate/ZnO Hybrid Coatings", Eur. Polym. J., Vol. 45, 2009, p. 960. https://doi.org/10.1016/j.eurpolymj.2008.11.023
  33. D. W. Chae and B. C. Kim, "Characterization on Polystyrene/zinc oxide Nanocomposites Prepare from Solution Mixing", Polym. Adv. Tech., Vol. 16, 2005, p. 846. https://doi.org/10.1002/pat.673