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Study on Reversible Electrolysis Characteristic of a Planar Type SOFC

평판형 고체산화물 연료전지의 양방향 수전해 특성 연구

  • CHOI, YOUNGJAE (Energy Materials Research Group, Research Institute of Industrial Science & Technology (RIST)) ;
  • AHN, JINSOO (Energy Materials Research Group, Research Institute of Industrial Science & Technology (RIST))
  • 최영재 ((재)포항산업과학연구원 에너지소재연구그룹) ;
  • 안진수 ((재)포항산업과학연구원 에너지소재연구그룹)
  • Received : 2017.10.16
  • Accepted : 2017.12.29
  • Published : 2017.12.31

Abstract

This paper presents the reversible electrolysis characteristics of a solid oxide fuel cell (SOFC) using a $10{\times}10cm^2$ anode supported planar cell with an active area of $81cm^2$. In this work, current-voltage characteristic test and reversible electrolysis cycle test were carried out sequentially for 2,114 hours at a furnace temperature of $700^{\circ}C$. The current-voltage characteristics for reversible electrolysis mode was measured at a current of ${\pm}26.7A$ under various $H_2O$ utilization conditions. The reversible electrolysis cycle was performed 50 times at a current of ${\pm}32.4A$. As a result, The performance degradation of SOEC mode was larger than that of SOFC mode.

Keywords

References

  1. V. N. Nguyen, Q. Fang, U. Packbier, and L. Blum, "Long-term tests of a Julich planar short stack with reversible solid oxide cells in both fuel cell and electrolysis modes", Int. J. Hydrogen Energy, Vol. 38, 2013, pp. 4281-4290. https://doi.org/10.1016/j.ijhydene.2013.01.192
  2. W. Doenitz and R. Schmidberger, "Concepts and design for scaling up high temperature water vapour electrolysis", Int. J. Hydrogen Energy, Vol. 7, 1982, pp. 55-63.
  3. A. Hauch, S. H. Jensen, S. Ramousse, M. Mogensen, "Performance and durability of solid oxide electrolysis cells", J. Electrochem. Soc., Vol. 153, 2006, pp. A1741-A1747. https://doi.org/10.1149/1.2216562
  4. C. M. Stoots, J. E. O'Brien, K. Condie, L. Moore-McAteer, G. Housley, and J. J. Hartvigsen, J. S. Herring, "The high-temperature electrolysis integrated laboratory experiment", Nucl. Technol., Vol. 166, 2009, pp. 32-42. https://doi.org/10.13182/NT09-A6966
  5. M. Zahid, J. Schefold, and A. Brisse, "Hydrogen and fuel cells, fundamentals, technologies and applications", D. Stolten ed., Wiley-VCH, Weinheim, Germany, 2008, pp. 227-242.
  6. P. Mocoteguy and A. Brisse, "A review and comprehensive analysis of degradation mechanisms of solid oxide electrolysis cells", Int. J. Hydrogen Energy, Vol. 38, 2013, pp. 15887-15902. https://doi.org/10.1016/j.ijhydene.2013.09.045
  7. M. S. Sohal, J. E. O'Brien, C. M. Stoots, V. I. Sharma, B. Yildiz, and A. Virkar, "Degradation issues in solid oxide cells during high temperature electrolysis", J. Fuel Cell Sci. Technol., Vol. 9, 2011, pp. 011017.
  8. F. Tietz, D. Sebold, A. Brisse, and J. Schefold, "Degradation phenomena in a solid oxide electrolysis cell after 9000 h of operation", Journal of Power Sources, Vol. 223, 2013, pp. 129-135. https://doi.org/10.1016/j.jpowsour.2012.09.061