DOI QR코드

DOI QR Code

Characterization of the Schottky Barrier Height of the Pt/HfO2/p-type Si MIS Capacitor by Internal Photoemission Spectroscopy

내부 광전자방출 분광법을 이용한 Pt/HfO2/p-Si Metal-Insulator-Semiconductor 커패시터의 쇼트키 배리어 분석

  • Lee, Sang Yeon (Department of Energy Systems Research, Ajou University) ;
  • Seo, Hyungtak (Department of Energy Systems Research, Ajou University)
  • 이상연 (아주대학교 에너지 시스템학과) ;
  • 서형탁 (아주대학교 에너지 시스템학과)
  • Received : 2016.10.19
  • Accepted : 2016.12.02
  • Published : 2017.01.27

Abstract

In this study, we used I-V spectroscopy, photoconductivity (PC) yield and internal photoemission (IPE) yield using IPE spectroscopy to characterize the Schottky barrier heights (SBH) at insulator-semiconductor interfaces of Pt/$HfO_2$/p-type Si metal-insulator-semiconductor (MIS) capacitors. The leakage current characteristics of the MIS capacitor were analyzed according to the J-V and C-V curves. The leakage current behavior of the capacitors, which depends on the applied electric field, can be described using the Poole-Frenkel (P-F) emission, trap assisted tunneling (TAT), and direct tunneling (DT) models. The leakage current transport mechanism is controlled by the trap level energy depth of $HfO_2$. In order to further study the SBH and the electronic tunneling mechanism, the internal photoemission (IPE) yield was measured and analyzed. We obtained the SBH values of the Pt/$HfO_2$/p-type Si for use in Fowler plots in the square and cubic root IPE yield spectra curves. At the Pt/$HfO_2$/p-type Si interface, the SBH difference, which depends on the electrical potential, is related to (1) the work function (WF) difference and between the Pt and p-type Si and (2) the sub-gap defect state features (density and energy) in the given dielectric.

Keywords

References

  1. G. Jegert, A. Kersch, W. Weinreich and P. Lugli, J. Appl. Phys., 109, 014504 (2011). https://doi.org/10.1063/1.3531538
  2. S. K. Kim, S. W. Lee, J. H. Han, B. Lee, S. Han and C. S. Hwang, Adv. Funct. Mater., 20, 2989 (2010). https://doi.org/10.1002/adfm.201000599
  3. H. J. Cho, Y. D. Kim, D. S. Park, E. Lee, C. H. Park, J. S. Jang, K. B. Lee, H. W. Kim, Y. J. Ki, I. K. Han and Y. W. Song, Solid-State Electron., 51, 1529 (2007). https://doi.org/10.1016/j.sse.2007.09.030
  4. J. Wu, L. F. Register and E. Rosenbaum, Reliability Physics Symposium Proceedings, 1999. 37th Annual. 1999 IEEE International, 389, (1999).
  5. C. Ho Jin, K. Young Dae, P. Dong Su, L. Euna, P. Cheol Hwan, J. Jun Soo, L. Keum Bum, K. Hai Won, C. Soo Jin, K. Young Jong, H. Il Keun and S. Yong Wook, Solid-State Device Research Conference, 2006. ESSDERC 2006. Proceeding of the 36th European, 146 (2006).
  6. S. Y. Lee, J. Chang, Y. Kim, H. Lim, H. Jeon and H. Seo, Appl. Phys. Lett., 105, 201603 (2014). https://doi.org/10.1063/1.4902244
  7. L. Gerald, S. Hyungtak, L. Sanghyun, B. F. Leslie, D. U. Marc, L. Jan, L. Pat and B. Gennadi, Jap. J. Appl. Phys., 46, 1899 (2007). https://doi.org/10.1143/JJAP.46.1899
  8. V. V. Afanas'ev, Internal photoemission spectroscopy : principles and applications. Elsevier: (2008).
  9. V. V. Afanas'ev and A. Stesmans, J. Appl. Phys., 102, 081301 (2007). https://doi.org/10.1063/1.2799091
  10. W. Gopel, J. A. Anderson, D. Frankel, M. Jaehnig, K. Phillips, J. A. Schafer and G. Rocker, Surf. Sci., 139, 333 (1984). https://doi.org/10.1016/0039-6028(84)90054-2
  11. N. V. Nguyen, O. A. Kirillov and J. S. Suehle, Thin Solid Films, 519, 2811 (2011). https://doi.org/10.1016/j.tsf.2010.11.080
  12. N. V. Nguyen, O. Kirillov, H. D. Xiong and J. S. Suehle, AIP Conference Proceedings, 931, 308 (2007).
  13. Z. Haowei, G. Bin, Y. Shimeng, L. Lin, Z. Lang, S. Bing, L. Lifeng, L. Xiaoyan, L. Jing, H. Ruqi and K. Jinfeng, Simulation of Semiconductor Processes and Devices, 2009. SISPAD '09. International Conference on, 1, (2009).
  14. V. V. Afanas'ev, M. Houssa, A. Stesmans and M. M. Heyns, J. Appl. Phys., 91, 3079 (2002). https://doi.org/10.1063/1.1436299
  15. E. Y. Chan, H. C. Card and M. C. Teich, Quantum Electronics, IEEE Journal of, 16, 373 (1980). https://doi.org/10.1109/JQE.1980.1070476
  16. L. F. Register, E. Rosenbaum and K. Yang, Appl. Phys. Lett., 74, 457 (1999). https://doi.org/10.1063/1.123060
  17. J. Robertson, J. Vac. Sci. Technol. B, 18, 1785 (2000). https://doi.org/10.1116/1.591472
  18. S. Furukawa and T. Miyasato, Phys. Rev. B, 38, 5726 (1988). https://doi.org/10.1103/PhysRevB.38.5726