Transactions on Electrical and Electronic Materials

The Korean Institute of Electrical and Electronic Material Engineers (한국전기전자재료학회)
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Paramagnetic Zn(1-x)MnxO (0.00≤x≤0.06) Nanoparticles Prepared by The Coprecipitation Method

  • Harsono, Heru (Department of Mechanical Engineering, Faculty of Engineering and Department of Physics, Faculty of Mathematics and Natural Sciences, Universitas Brawijaya) ;
  • Wardana, I Nyoman Gede (Department of Mechanical Engineering, Faculty of Engineering, Universitas Brawijaya) ;
  • Sonief, Achmad As'ad (Department of Mechanical Engineering, Faculty of Engineering, Universitas Brawijaya) ;
  • Darminto, Darminto (Department of Physics, Faculty of Mathematics and Natural Sciences, Institut Teknologi Sepuluh Nopember)
  • Received : 2015.11.20
  • Accepted : 2016.11.01
  • Published : 2017.02.25
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Abstract

The Zn1-xMnxO ($0.00{\leq}x{\leq}0.06$) samples have been synthesized in the form of powder by the coprecipitation method at low temperature using $Zn(CH_3COO)_2$. $2H_2O$ and $Mn(CH_3COO)_2$. $4H_2O$ powders, as well as HCl and $NH_4OH$ solutions as starting materials. Characterization was conducted using XRD, TEM, XRF, FTIR and VSM. The result shows that the $Zn_{(1-x)}Mn_xO$ ($0.00{\leq}x{\leq}0.06$) nanoparticles have the wurtzite phase with a hexagonal structure and particle sizes ranging from 17.48 to 118.83 nm. In a qualitative analysis of XRF, the peaks that confirm the existence of the manganese element in Mn-doped ZnO samples were observed. Meanwhile, FTIR test result shows that there are peaks at around $500cm^{-1}$ and $400cm^{-1}$ in the FTIR spectra for Mn doped ZnO samples which clearly reveal the existence of the (Zn, Mn)-O strain mode. The (Zn, Mn)-O absorption peak positions have shifted to a lower wave number with increasing Mn doping content. The peak intensity is also lower if compared to that of the ZnO sample without doping. From the VSM test, it is shown that $Zn_{(1-x)}Mn_xO$ ($0.00{\leq}x{\leq}0.06$) nanoparticles are all paramagnetic having monotonically increased susceptibility as increasing Mn content.

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References

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