Textile Coloration and Finishing (한국염색가공학회지)

The Korean Society of Dyers and Finishers (한국염색가공학회)
권호 표지
DOI QR코드

DOI QR Code

Synthesis of Non-fluorinated Polystearyl methacrylate Water Repellent and Its Properties on Textile Fibers

비불소계 폴리스테아릴메타크릴레이트 발수제의 합성과 발수특성

  • Kim, Taekyeong (Department of Textile System Engineering, Kyungpook National University) ;
  • Kang, Hyejin (Department of Textile System Engineering, Kyungpook National University) ;
  • Park, Jihoon (Department of Textile System Engineering, Kyungpook National University)
  • 김태경 (경북대학교 섬유시스템공학과) ;
  • 강혜진 (경북대학교 섬유시스템공학과) ;
  • 박지훈 (경북대학교 섬유시스템공학과)
  • Received : 2017.03.10
  • Accepted : 2017.04.12
  • Published : 2017.06.27
Download PDF
⟨ Previous Next ⟩

Abstract

A non-fluorinated polystearyl methacrylate water repellent was synthesized by emulsion polymerization. The number and weight averaged molecular weights were obtained at around 137,277 and 237,754g/mole. The melting point was observed at $32^{\circ}C$. The contact angle of water droplet on fabrics treated with the water repellent was $140{\sim}145^{\circ}$ for cotton and polyester, and $125{\sim}130^{\circ}$ for wool and nylon. Since the critical surface tension was estimated at 20.7mN/m, even though relatively not so strong as fluorinated water repellent, it is considered to be used as a good water repellent practically.

Keywords

References

  1. D. Heywood, "Textile Finishing", Dyers' Company Publication Trust, Hampshire, pp.135-210, 2003.
  2. J. Shore, "Colorants and Auxiliaries", Dyers' Company Publication Trust, West Yorkshire, pp.463-467, 1990.
  3. P. E. Slade, "Handbook of Fiber Finish Technology", Marcel Dekker Inc., New York, pp.401-416, 1998.
  4. B. J. Potthoff, "Understanding Textiles, 5th ed.", Prentice-Hall Inc., New Jersey, pp.393-395, 1997.
  5. B. C. Kim, H. J. Koo, O. K. Kwon, S. S. Kim, T. K. Kim, H. S. Kim, J. S. Bok, B. I. Jeon, D. H. Cho, H. H. Cho, andC. H. Joo, "Textile Basic Technology", Hanrimwon, Seoul, pp.346-347, 2012.
  6. B. R. Choi, S. S. Han, andM. C. Lee, Water and Oil Repellency of Wool Fabric Treated with Nano-type Finishing Agent, Textile Coloration and Finishing, 20(6), 26(2008). https://doi.org/10.5764/TCF.2008.20.6.026
  7. Y. K. Jeong, Y. J. Jeong, and J. H. Jang, Preferential Face Coating of Knitted PET Fabrics via UV Curing for Water- and Oil-repellent Finish, Textile Coloration and Finishing, 17(6), 27(2005).
  8. Z. Jiang, Y. Wang,Y. Liu, and X. Ren, Water Repellent Treatment of Cotton Fabrics by Electron Beam Irradiation, Fiber Polym., 17(7), 1013(2016). https://doi.org/10.1007/s12221-016-6376-0
  9. S. Y. Lee, H. G. Sohn, S. C. Lim, H. Y. Lee, and S. G. Lee, Effect of E-beam Irradiation on the Water-repellency and Washing Durability of the Water-repellent Finished Chemically-recycled PET(CR-PET) Fabrics, Textile Coloration and Finishing, 27(2), 119(2015). https://doi.org/10.5764/TCF.2015.27.2.119
  10. E. K. Choe, J. S. Ra, Y. D. Cho, K. B. Song, S. Y. Lee, and G. S. Seok, Chemical Structural Approach to Understand Global Prohibited on Perfluorinated Compounds and their Uses, Textile Coloration and Finishing, 23(3), 134(2016).
  11. M. M. Schultz, D. F. Barofsky, and J. A. Field, Fluorinated Alkyl Surfactants, Environmental Engineering Science, 20(5), 487(2004). https://doi.org/10.1089/109287503768335959
  12. S. S. Latthe, D. Y. Nadargi, and A. V. Rao, TMOS based Water Repellent Silica Thin Films by Co-precursor Method using TMES as a Hydrophobic Agent, Applied Surface Science, 255(6), 3600(2009). https://doi.org/10.1016/j.apsusc.2008.10.005
  13. Q. Gao, Q. Zhu, and Y. Guo, Formation of Highly Hydrophobic Surfaces on Cotton and Polyester Fabrics Using Silica Sol Nanoparticles and Nonfluorinated Alkylsilane, Industrial and Engineering Chemistry Research, 48(22), 9797(2009). https://doi.org/10.1021/ie9005518
  14. J. M. Lee, J. W. Kim, K. J. Kim, and K. Kang, "Textile Finishing", Hyungseol Publish Co., Seoul, pp.283-305, 2004.
  15. H. K. Rouette, "Encyclopedia of Textile Finishing", Springer, New York, pp.2051-2061, 2000.
  16. T. Kim, H. Kang, and N. Yoon, Synthesis of Non-fluorinated Paraffinic Water Repellents and Application Properties on Textile Fibers, Fibers and Polymers, 18(2), 285(2017). https://doi.org/10.1007/s12221-017-6469-4
  17. J. Wang, G. Mao, C. K. Ober, and E. J. Kramer, Liquid Crystalline, Semifluorinated Side Group Block Copolymers with Stable Low Energy Surfaces: Synthesis, Liquid Crystalline Structure, and Critical Surface Tension, Macromolecules, 30(7), 1906(1997). https://doi.org/10.1021/ma961412o
  18. S. Shibuichi, T. Yamamoto, T. Onda, and K. Tsujii, Super Water- and Oil-Repellent Surfaces Resulting from Fractal Structure, J. Colloid and Interface Science, 208(1), 287(1998). https://doi.org/10.1006/jcis.1998.5813
  19. R. M. Silverstein, G. C. Bassler, and T. C. Morill, "Spectrometric Identification of OrganicCompounds, 5th ed.", John Wiley & Sons Inc., New York, pp.105-106, 1991.
  20. D. L. Pavia, G. M. Lampman, G. S. Kriz, and J. A. Vyvyan, "Introduction to Spectroscopy, 4th ed.", Cengage Laerning, Korea, pp.44-46, 2010.