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강유전체(K0.5Na0.5)NbO3의 제조 및 전기적 특성 분석

Fabrication and Electrical Propertie of the Ferroelectric (K0.5Na0.5)NbO3

  • 투고 : 2017.08.07
  • 심사 : 2017.08.25
  • 발행 : 2017.08.31

초록

Ferroelectric ceramics are broadly used for various industrial applications. In this research, the lead-free ferroelectric ceramics of $(K_{0.5}Na_{0.5})NbO_3$ was fabricated by using the solid state synthesis. The $(K_{0.5}Na_{0.5})NbO_3$ pellets were sintered at 1200, 1150 and $1100^{\circ}C$ for 4 hours in air atmosphere. Field-emission scanning electron microscopy (FE-SEM) characterization of the sintered KNN ceramics revealed surface morphology and grain size. And we used the X-ray diffraction (XRD) for measuring the sample crystal phase. Temperature dependence of the dielectric constant was measured by using an LCR meter. The sintered at $1150^{\circ}C$ for 4 hours sample has a highest dielectric constant 6011 at Curie temperature ($T_C$) and dense structure with $2.33{\mu}m$ grain size.

키워드

참고문헌

  1. Michihito Ueda, Yukihiro Kaneko, Yu Nishitani, Atsushi Omote, Battery-less shock-recording device consisting of a piezoelectric sensor and a ferroelectric-gate field-effect transistor, Sensors and Actuators A, 232 (2015) 75-83. https://doi.org/10.1016/j.sna.2015.05.012
  2. Terence Mittmann, Franz P.G. Fengler, Claudia Richter, Min Hyuk Park,Thomas Mikolajick, Uwe Schroeder, Optimizing process conditions for improved $Hf_{1-x}Zr_xO_2$ ferroelectric capacitor performance, Microelectronic Engineering, 178 (2017) 48-51. https://doi.org/10.1016/j.mee.2017.04.031
  3. Preeti Sharma, Parveen Kumar, R.S. Kundu, N. Ahlawat, R. Punia, Enhancement in magnetic, piezoelectric and ferroelectric properties on substitution of titanium by iron in barium calcium titanate ceramics, Ceramics International, Vol. 42, Issue 10 (2016) 12167-12171. https://doi.org/10.1016/j.ceramint.2016.04.152
  4. V.V. Sidsky, A.V. Semchenko, A.G. Rybakov, V.V. Kolos, A.S. Turtsevich, A.N. Asadchyi, W. Strek3, $La^{3+}$-doped $SrBi_2Ta_2O_9$ thin films for FRAM synthesized by sol-gel method, JOURNAL OF RARE EARTHS, Vol. 32, No. 3 (2014) 277-281. https://doi.org/10.1016/S1002-0721(14)60065-X
  5. Wei Lin Tan, Dennis M. Kochmann, An effective constitutive model for polycrystalline ferroelectric ceramics: Theoretical framework and numerical examples, Computational Materials Science, 136 (2017) 223-237. https://doi.org/10.1016/j.commatsci.2017.04.032
  6. R. Castaneda-Guzman, R. Lopez-Juarez, J.J. Gervacio, M.P. Cruz, S. Diaz de la Torre, S.J. Perez-Ruiz, Structural and piezo-ferroelectric properties of $K_{0.5}Na_{0.5}NbO_3$ thin films grown by pulsed laser deposition and tested as sensors, Thin Solid Films 636 (2017) 458-463. https://doi.org/10.1016/j.tsf.2017.06.039
  7. Gui-gui Peng, De-yi Zheng, Cheng Cheng, Jing Zhang, Hao Zhang, Effect of rare-earth addition on morphotropic phase boundary and relaxation behavior of the PNN-PZT ceramics, Journal of Alloys and Compounds 693 (2017) 1250-1256. https://doi.org/10.1016/j.jallcom.2016.10.079
  8. L.B. Kong, T.S. Zhang, J. Ma, F. Boey, Progress in synthesis of ferroelectric ceramic materials via high-energy mechanochemical technique, Progress in Materials Science 53 (2008) 207-322. https://doi.org/10.1016/j.pmatsci.2007.05.001
  9. Enwei Sun a, Wenwu Cao, Relaxor-based ferroelectric single crystals: Growth, domain engineering, characterization and applications, Progress in Materials Science 65 (2014) 124-210. https://doi.org/10.1016/j.pmatsci.2014.03.006
  10. Shujun Zhang a, Fei Li, Xiaoning Jiang, Jinwook Kim, Jun Luo, Xuecang Geng, Advantages and challenges of relaxor-$PbTiO3_$ ferroelectric crystals for electroacoustic transducers - A review, Progress in Materials Science 68 (2015) 1-66. https://doi.org/10.1016/j.pmatsci.2014.10.002
  11. T. Takenaka and H. Nagata, Current status and prospects of lead-free piezoelectric ceramics, J. Eur. Ceram. Soc., 25 (2005) 2693. https://doi.org/10.1016/j.jeurceramsoc.2005.03.125
  12. L. Egerton and D.M. Dillon, Piezoelectric and Dielectric Properties of Ceramics in the System Potassium-Sodium Niobate, J. Am. Ceram. Soc., 42 (1959) 438. https://doi.org/10.1111/j.1151-2916.1959.tb12971.x
  13. N. M. Hagh, B. Jadidian and A. Safari, Propertyprocessing relationship in lead-free (K, Na, Li)$NbO_3$-solid solution system, J. Electroceram., 18 (2007) 339. https://doi.org/10.1007/s10832-007-9171-x
  14. Y. Guo, K. Kakimoto and H. Ohsato, $(Na_{0.5}K_{0.5})NbO_3$-$LiTaO_3$ lead-free piezoelectric ceramics, Materials Letters., 59 (2005) 241. https://doi.org/10.1016/j.matlet.2004.07.057
  15. S. Zhang, R. Xia, T. R. Shrout, ead-free piezoelectric ceramics vs. PZT?, J. Electroceram., 19 (2007) 251. https://doi.org/10.1007/s10832-007-9056-z
  16. Y. Guo, K. Kakimoto and H. Ohsato, Appl, Phase transitional behavior and piezoelectric properties of $(Na_{0.5}K_{0.5})NbO_3$-$LiNbO_3$ ceramics, Phys. Lett., 85 (2004) 4121. https://doi.org/10.1063/1.1813636
  17. Kumar, M. Pattanaik, Sonia. Synthesis and characterizations of KNN ferroelectric ceramics, Ceramics International., 39 (2013) 65. https://doi.org/10.1016/j.ceramint.2012.05.093
  18. P. Kumara,n, M. Pattanaika, Soniab, Synthesis and characterizations of KNN ferroelectric ceramicsnear 50/50 MPB, Ceramics International 39 (2013) 65. https://doi.org/10.1016/j.ceramint.2012.05.093
  19. Roopam Gaur, K. Chandramani Singh, Radhapiyari Laishram, Effect of Sintering Parameters on the Electrical and the Piezoelectric Properties of Double-calcined $(K_{0.48}Na_{0.48}Li_{0.04})(Nb_{0.96}Sb_{0.04})O_3$ Nanopowders, Journal of the Korean Physical Society, Vol. 66, No. 5 (2015) 800. https://doi.org/10.3938/jkps.66.800
  20. Beom-Seok Yang, Chang Yun Shin, Chang Whan Won, Effects of Sr on the Electrical Properties of PZT Ceramics Prepared by Self-propagating Hightemperature Synthesis, Journal of the Korean Ceramic Society Vol. 45, No. 11 (2008) 713. https://doi.org/10.4191/KCERS.2008.45.1.713