DOI QR코드

DOI QR Code

Anaysis of Fe in Seepage Water and Precipitates around a Hydrothermal Alteration Zone

  • Yun, Hyun-Seok (Department of Earth and Environmental Sciences, Chungbuk National University) ;
  • Moon, Seong-Woo (Department of Earth and Environmental Sciences, Chungbuk National University) ;
  • Lee, Jin-Kook (Department of Geology, Kyungpook National University) ;
  • Jeong, Gyo-Cheol (Department of Earth and Environmental Sciences, Andong National University) ;
  • Seo, Yong-Seok (Department of Earth and Environmental Sciences, Chungbuk National University)
  • Received : 2017.09.12
  • Accepted : 2017.09.20
  • Published : 2017.09.30

Abstract

Acid drainage in civil engineering structures such as tunnels may lead to the deposition of precipitates that clog drainage channels and pipework. In evaluating acid drainage, the Fe content of water and precipitates, indicated by reddish brown coloration of rock surfaces, rivers, and soils, may be an important factor. In this study, acid drainage was evaluated by analyzing the Fe content of reddish brown seepage water that occurred in part of a tunnel. Geological investigations around the tunnel revealed a hydrothermal alteration zone cutting the bedrock, and cropping out in the upper parts of the tunnel. Analysis of drillcore revealed many fracture zones and veins. Inductively coupled plasma spectrophotometric analyses of water, precipitates, and soil samples, collected in the seepage water zone and around the tunnel, were conducted to evaluate acid drainage. The Fe content of seepage water in the tunnel was 0.030-0.333 mg/kg, which is 2-22 times higher than in local groundwater. The Fe content of precipitates in the tunnel was 165,403-301,051 mg/kg, similar to the 206,167-422,964 mg/kg content of drillcore from the hydrothermal alteration zone located above the tunnel. It is concluded that the seepage water is derived from Fe-containing acid drainage flowing in perforated tunnel drainpipes along the fracture zones and veins around the hydrothermal alteration zone.

Keywords

References

  1. Akcil, A. and Koldas, S., 2006, Acid Mine Drainage (AMD): causes, treatment and case studies, Journal of Cleaner Production, 14, 1139-1145. https://doi.org/10.1016/j.jclepro.2004.09.006
  2. Cheong, Y. W., 2004, An overview of coal mine drainage treatment, Economic and Environmental Geology, 37(1), 107-111 (in Korean with English abstract).
  3. Choi, S. G., Pak, S. J., Lee, P. K., and Kim, C. S., 2004, An overview of geoenvironmental implications of mineral deposits in Korea, Economic and Environmental Geology, 37(1), 1-19 (in Korean with English abstract).
  4. Choi, S. W., Lee, C. H., Won, K. S., and Kim, I. S., 2001, Geological and hydrogeochemical characteristics of the Hoibug area along the designed express way from Cheongju to Sangju, Korea, Journal of the Geological Society of Korea, 37(1), 83-106 (in Korean with English abstract).
  5. Choo, C. O., Lee, J. K., and Cho, H. G., 2004, Formation of alunite and schwertmannite under oxidized condition and Its implication for environmental geochemistry at Dalseong mine, Journal of the Mineralogical Society of Korea, 17(1), 37-47 (in Korean with English abstract).
  6. Cui, M. C., Lim, J. H., Kweon, B., Jang, M., Shim, Y., and Khim, J., 2009, Effect of pH and temperature on the adsorption of heavy metals in acid mine drainage (AMD) onto coal mine drainage sludge (CMDS), Journal of Soil and Groundwater Environment, 14(1), 29-35 (in Korean with English abstract).
  7. Im, G. Y., Min, G. M., Oh, J. G., and Yun C. S., 2013, Improvement of existing tunnel drainage system, 61, Technology II, Korean Society of Civil Engineers, 61(11), 34-39 (in Korean).
  8. Kelly, M., 1988, Mining and the freshwater environment. Elsevier Applied Science, London and New York, 231p.
  9. Kim, J. G., 2007, Acid drainage and damage reduction strategy in construction site: an introduction, Economic and Environmental Geology, 40(5), 651-660 (in Korean with English abstract).
  10. Kim, J. G., Song, Y. S., Chon, C. M., and Nam, I. H., 2014, Assessment and stabilization embankment methods of acid rock drainage, The Magazine of Korean Society of Civil Engineers, 36-41 (in Korean).
  11. Kim, J. J. and Kim, S. J., 2002, Variations in geochemical characteristics of the acid mine drainages due to mineral-water interactions in Donghae Mine area in Taebaek, Korea, Economic and Environmental Geology, 35(1), 55-66 (in Korean with English abstract).
  12. Koryak, M., Shapiro, M. A., and Sykora, J. L., 1972, Riffle zoobenthos in streams receiving acid mine drainage, Water Research, 6, 1239-1274. https://doi.org/10.1016/0043-1354(72)90024-3
  13. Lee, G. H., Kim, J. G., Lee, J. S., Chon, C. M., Park, S. G., Kim, T. H., Ko, K. S., and Kim, T. K., 2005, Generation characteristics and prediction of acid rock drainage (ARD) of cut slopes, Economic and Environmental Geology, 38(1), 91-99 (in Korean with English abstract).
  14. Lee, J. S., Kim, J. G., Park, J. S., Chon, C. M., and Nam, I. H., 2013, Assessment and damage reduction strategy of acid rock drainage in highway construction site, Economic and Environmental Geology, 46(5), 411-424 (in Korean with English abstract). https://doi.org/10.9719/EEG.2013.46.5.411
  15. Michaud, L. H., 1995, Recent technology related to the treatment of acid drainage, Earth and Mineral Sciences, 63, 53-55.
  16. Park, M. E., Sung, K. Y., and Koh, Y. K., 2000, Formation of acid mine drainage and pollution of geological environment accompanying the sulfidation zone of nonmetallic deposits: Reaction path modeling on the formation of AMD of Tongnae pyrophyllite mine, Economic and Environmental Geology, 33(5), 405-415 (in Korean with English abstract).
  17. Sengupta, M., 1993, Environmental impacts of mining: monitoring, restoration, and control, Lewis Publishers, London, 494p.
  18. Tateiwa, I., 1922, Geological map Choyo sheet, Geological Survey of Korea.
  19. Woo, J. T., 2005, A study on analysis of influx path and ingredient of sedimentation substance and groundwater influx quantity in downtown tunnel, Tunneling Technology, 7(3), 219-226 (in Korean with English abstract).
  20. Youm, S. J., Yun, S. T., Kim, J. H., and Park, M. E., 2002, Neutralization of acid rock drainage from the Dongrae pyrophyllite deposit: A study on behavior of heavy metals, Journal of Soil and Groundwater Environment, 7(4), 68-76 (in Korean with English abstract).
  21. Yu, J. Y. and Coleman, M., 2000, Isotopic compositions of dissolved sulfur in acid mine drainages: Case study on Youngdong and Gangreung coal mines, Korea, Journal of the Geological Society of Korea, 36(1), 1-10 (in Korean with English abstract).