Textile Science and Engineering (한국섬유공학회지)

The Korean Fiber Society (한국섬유공학회)
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Properties of a Nanosilver-Silica Composite Synthesized with Different Molecular Weights and Polyvinylpyrrolidone Concentrations

PVP 분자량과 농도 변화에 따른 은-실리카 나노복합체의 특성에 관한 연구

  • Son, Eun-Jong (Department of Textile Business, Bucheon University) ;
  • Jeong, Sung-Hoon (Department of Organic and Nano Engineering, Hanyang University)
  • 손은종 (부천대학교 섬유패션비즈니스과) ;
  • 정성훈 (한양대학교 유기나노공학과)
  • Received : 2017.07.30
  • Accepted : 2017.08.30
  • Published : 2017.10.31
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Abstract

Well-dispersed nanosilver particles were synthesized by a chemical reduction method, where silica was treated with amino groups, mercapto groups, and polyvinylpyrrolidone (PVP) as a dispersant. Transmission electron microscopy (TEM) images showed that both the concentration and the molecular weight of PVP considerably affected the size of the silver nanoparticles. The average size of the silver nanoparticles prepared with amino-treated silica increased with increasing PVP concentration, whereas the size of the silver nanoparticles prepared with mercapto-treated silica was not affected by the PVP concentration. As the molecular weight of PVP increased, the average size of the silver nanoparticles also increased. The number of silver particles formed with mercapto-treated silica was larger, and the size distribution was narrower than those formed from aminotreated silica.

Keywords

References

  1. Y.-W. Chih and W.-T. Cheng, "Supercritical Carbon Dioxideassisted Synthesis of Silver Nano-Particles in Polyol Process", Mater. Sci. Eng., 2007, 145, 67-75. https://doi.org/10.1016/j.mseb.2007.10.006
  2. P. K. Khanna, N. Singh, D. Kulkarni, S. Deshmukh, S. Charan, and P. V. Adhyapak, "Water Based Simple Synthesis of Redispersible Silver Nano-Particles", Mater. Lett., 2007, 61, 3366-3370. https://doi.org/10.1016/j.matlet.2006.11.064
  3. S. Wei, X. Xu, Y. Liu, and J. Yang, "Preparation of Hydrophobic Nano-Silver Colloid and Aqueous Nano-Silver Colloid by Phase Transfer", Mater. Chem. Phys., 2011, 126, 12-15. https://doi.org/10.1016/j.matchemphys.2010.11.012
  4. H. Wang, X. Qiao, J. Chen, X. Wang, and S. Ding, "Mechanisms of PVP in the Preparation of Silver Nanoparticles", Mater. Chem. Phys., 2005, 94, 449-453. https://doi.org/10.1016/j.matchemphys.2005.05.005
  5. H. S. Shin, H. J. Yang, S. B. Kim, and M. S. Lee, "Mechanism of Growth of Colloidal Silver Nanoparticles Stabilized by Polyvinyl Pyrrolidone in ${\gamma}$-Irradiated Silver Nitrate Solution", J. Colloid Interface Sci., 2004, 274, 89-94. https://doi.org/10.1016/j.jcis.2004.02.084
  6. Z. Zaheer, M. A. Malik, F. M. Al-Nowasier, and Z. Khan, "Preparation of Silver Nanoparticles using Tryptophan and its Formation Mechanism", Colloids Surf. B Biointerfaces, 2010, 81, 587-592. https://doi.org/10.1016/j.colsurfb.2010.08.001
  7. C. Wu, B. P. Mosher, K. Lyons, and T. Zeng, "Reducing Ability and Mechanism for Polyvinylpyrrolidone (PVP) in Silver Nanoparticles Synthesis", J. Nanosci. Nanotechnol., 2010, 10, 2342-2347. https://doi.org/10.1166/jnn.2010.1915
  8. C. Y. Tai, Y.-H. Wang, C.-T. Tai, and H.-S. Liu, "Preparation of Silver Nanoparticles Using a Spinning Disk Reactor in a Continuous Mode", Ind. Eng. Chem. Res., 2009, 48, 10104-10109. https://doi.org/10.1021/ie9005645
  9. Z. Li, Y. Wang, and Q. Yu, "Significant Parameters in the Optimization of Synthesis of Silver Nanoparticles by Chemical Reduction Method", J. Mater. Eng. Performance, 2009, 19, 252-256.
  10. J. L. Lan, C.-C. Wan, and Y.-Y. Wang, "Mechanistic Study of Ag/Pd-PVP Nanoparticles and Their Functions as Catalyst for Electroless Copper Deposition", J. Electrochem. Soc., 2008, 155, K77-K83. https://doi.org/10.1149/1.2838908