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Influence of Organomodified Nanoclay on the Mechanical and Flammability behavior of Jute Fabric/Vinyl Ester Nanocomposites

  • Latif, M. (Department of Mechanical Engineering, Changwon National University) ;
  • Prabhakar, M.N. (Department of Mechanical Engineering, Changwon National University) ;
  • Nam, Gi-Beop (Department of Mechanical Engineering, Changwon National University) ;
  • Lee, Dong-Woo (Department of Mechanical Engineering, Changwon National University) ;
  • Song, Jung-Il (Department of Mechanical Engineering, Changwon National University)
  • Received : 2017.08.15
  • Accepted : 2017.10.28
  • Published : 2017.10.31

Abstract

Organo-montmorillonite (OMMT) has attracted much attention for fiber-reinforced polymer composites as a filler material due to high aspect ratio and low charge density. The present study focused on the fabrication of nanocomposites using Vinyl ester and Jute fabric as matrix and reinforcement respectively. The OMMT was uniformly dispersed in vinyl ester resin at 1, 2 and 3 wt%, loading through high speed mechanical stirrer at room temperature and further nanocomposites were manufactured through vacuum assisted resin infusion (VARI) technique. Effects of OMMT on the mechanical properties of vinyl ester/Jute composites were carefully investigated through tensile, bending and Izod impact tests, which revealed significant improvement in mechanical properties. The morphology of the nanocomposites after tensile test was investigated by SEM which affirmed that OMMT filled nanocomposites has improved interactions with the host matrix than the pure composites. Based on the nature and flame retardancy mechanism, the OMMT slightly improved the flammability property which was clearly explained by horizontal burning test.

Keywords

References

  1. Razak, N.W.A., and Kalam, A., "Effect of OPEFB Size on the Mechanical Properties and Water Absorption behaviour of OPEFB/PPnanoclay/PP Hybrid Composites", Procedia Engineering, Vol. 41, 2012, pp. 1593-1599. https://doi.org/10.1016/j.proeng.2012.07.355
  2. Braga, R.A., and Magalhaes Jr, P.A.A., "Analysis of the Mechanical and Thermal Properties of Jute and Glass Fiber as Reinforcement Epoxy Hybrid Composites", Materials Science & Engineering. C, Materials for Biological Applications, Vol. 56, 2015, pp. 269-73. https://doi.org/10.1016/j.msec.2015.06.031
  3. Alavudeen, A., Rajini, N., Karthikeyan, S., Thiruchitrambalam, M., and Venkateshwaren, N., "Mechanical Properties of Banana/kenaf Fiber-reinforced Hybrid Polyester Composites: Effect of Woven Fabric and Random Orientation", Materials and Design, Vol. 66, 2015, pp. 246-257. https://doi.org/10.1016/j.matdes.2014.10.067
  4. Ahmed, K.S., and Vijayarangan, S., "Tensile, Flexural and Interlaminar Shear Properties of Woven Jute and Jute-glass Fabric Reinforced Polyester Composites," Journal of Materials Processing Technology, Vol. 207, 2008, pp. 330-335. https://doi.org/10.1016/j.jmatprotec.2008.06.038
  5. Dhawan, V., Singh, S., and Singh, I., "Effect of Natural Fillers on Mechanical Properties of GFRP Composites", Journal of composites, Vol. 2013, 2013, pp. 8.
  6. Luo, X., Li, J., Feng, J., Yang, T., and Lin, X., "Mechanical And Thermal Performance of Distillers Grains Filled Poly(butylene succinate) Composites", Mater. Des., Vol. 57, 2014, pp. 195-200. https://doi.org/10.1016/j.matdes.2013.12.056
  7. Ridzuan, M.J.M., Abdul Majid, M.S., Afendi, M., Azduwin, K., Amin, N.A.M., Zahri, J.M., et al. "Moisture Absorption and Mechanical Degradation of Hybrid Pennisetum Purpureum/glass-epoxy Composites", Composite Structures, Vol. 141, 2016, pp. 110-116. https://doi.org/10.1016/j.compstruct.2016.01.030
  8. Ganguly, A., Maiti, M., and Bhowmick, A.K., "Structure-property Relationship of Specialty Elastomer-clay Nanocomposites", Bulletin of Materials Science, Vol. 31, 2008, pp. 455-459. https://doi.org/10.1007/s12034-008-0071-8
  9. Jo, B.-W., Kook, S., Kim, P., and Keun, D., "Mechanical Properties of Nano-MMT Reinforced Polymer Composite and Polymer Concrete", Construction and Building Materials, Vol. 22, 2008, pp. 14-20. https://doi.org/10.1016/j.conbuildmat.2007.02.009
  10. Madaleno, L., and Schjodt-Thomsen, J., "Morphology, Thermal and Mechanical Properties of PVC/MMT Nanocomposites Prepared by Solution Blending and Solution Blending ${\beta}$ Melt Compounding", Composites Science and Technology, Vol. 70, 2010, pp. 804-814. https://doi.org/10.1016/j.compscitech.2010.01.016
  11. Vishnu Mahesh, K.R., Narasimha Murthy, H.N., Kumaraswamy, B.E., Sridhar, R., Krishna, M., and Sherigara, B.S., "The Influence of Montmorillonite on Mechanical, Thermal and Fire Retardation Properties of Vinylester/glass Composites", Journal of Composite Materials, Vol. 47, 2012, pp. 2163-2178.
  12. Ji, G., and Li, G., "Effects of Nanoclay Morphology on the Mechanical, Thermal, and Fire-retardant Properties of Vinyl Ester Based Nanocomposites", Materials Science and Engineering A, Vol. 498, 2008, pp 327-334. https://doi.org/10.1016/j.msea.2008.08.003
  13. Wang, L., He, X., and Wilkie, C.A., "The Utility of Nanocomposites in Fire Retardancy", Materials, Vol. 3, 2010, pp. 4580-4606. https://doi.org/10.3390/ma3094580
  14. Uddin, F., "Clays, Nanoclays, and Montmorillonite Minerals", Metallurgical and Materials Transactions A, Vol. 39, 2008, pp. 2804-2814. https://doi.org/10.1007/s11661-008-9603-5
  15. Alateyah, A.I., Dhakal, H.N., and Zhang, Z.Y., "Processing, Properties, and Applications of Polymer Nanocomposites Based on Layer Silicates: A Review", Advances in Polymer Technology, Vol. 32, 2013.
  16. Wang, L., Wang, K., Chen, L., Zhang, Y., and He, C., "Preparation, Morphology and Thermal/mechanical Properties of Epoxy/nanoclay Composite," Composites-Part A: Applied Science and Manufacturing, Vol. 37, 2006, pp. 1890-1896. https://doi.org/10.1016/j.compositesa.2005.12.020
  17. Chandradass, J., Kumar, M.R., and Velmurugan, R., "Effect of Nanoclay Addition on Vibration Properties of Glass Fibre Reinforced Vinyl Ester Composites", Materials Letters, Vol. 61, 2007, pp. 4385-4388. https://doi.org/10.1016/j.matlet.2007.02.009
  18. Alateyah, A.I., Dhakal, H.N., and Zhang, Z.Y., "Mechanical and Thermal Properties Characterization of Vinyl Ester Matrix Nanocomposites Based on Layered Silicate," International Journal of Mechanical, Aerospace, Industrial and Mechatronics Engineering, Vol. 7, 2013, pp. 701-708.
  19. Chiu, C.W., Huang, T.K., Wang, Y.C., Alamani, B.G., and Lin, J.J., "Intercalation Strategies in Clay/polymer Hybrids," Progress in Polymer Science, Vol. 39, 2014, pp. 443-485. https://doi.org/10.1016/j.progpolymsci.2013.07.002
  20. Sridhar, R., Narasimha Murthy, H.N., Pattar, N., Vishnu Mahesh, K.R., and Krishna, M., "Parametric Study of Twin Screw Extrusion for Dispersing MMT in Vinyl Ester Using Orthogonal Array Technique and Grey Relational Analysis", Composites: Part B, Vol. 43, 2012, pp. 599-608. https://doi.org/10.1016/j.compositesb.2011.08.025
  21. Mittal, G., Dhand, V., Ryu, J.I., Rhee, K.Y., Kim, H.-J., and Jung, D.H., "Fabrication of Modified MMT/Glass/Vinylester Multiscale Composites and Their Mechanical Properties", Journal of Nanomaterials, Vol. 2015, pp. 9.
  22. Haque, A., Hossain, F., Dean, D., and Shamsuzzoha, M., "S2-Glass/vinylester Polymer Nanocomposites: Manufacturing, Structures, Thermal and Mechanical Properties", Journal of Composite Materials, Vol. 37, 2002, pp. 1821-1837.
  23. Kornmann, X., Lindberg, H., and Berglund, L.A., "Synthesis of Epoxy-clay Nanocomposites: Influence of the Nature of the Clay on Structure", Polymer, Vol. 42, 2001, pp. 1303-1310. https://doi.org/10.1016/S0032-3861(00)00346-3
  24. Thiagarajan, A., Palaniradja, K., and Mathivanan, N.R., "Effect of Nanoclay on the Impact Properties of Glass Fiber-Reinforced Polymer Composites," Polymer-Plastics Technology and Engineering, Vol. 51, 2012, pp. 1403-1410. https://doi.org/10.1080/03602559.2012.696762
  25. Sivasaravanan, S., and Bupesh Raja, V.K., "Impact Properties of Epoxy/glass Fiber/nano Clay Composite Materials", Journal of Mechanical and Civil Engineering, 2014, pp. 39-41.
  26. Mylavarapu, P., and Woldesenbet, E., "Effect of Nanoclay Incorporation on the Impact Properties of Adhesively Bonded Composite Structures", Journal of Adhesion Science and Technology, Vol. 24, 2010, pp. 389-405. https://doi.org/10.1163/016942409X12541266699554
  27. Ray, S.S., and Okamoto, M., "Polymer/layered Silicate Nanocomposites: A Review from Preparation to Processing", Progress in Polymer Science, Vol. 28, 2003, pp. 1539-1641. https://doi.org/10.1016/j.progpolymsci.2003.08.002