DOI QR코드

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Multi- effect air gap membrane distillation process for pesticide wastewater treatment

  • Pangarkar, Bhausaheb L. (Chemical Engineering Department, Sir Visvesvaraya Institute of Technology (SavitribaiPhule Pune University)) ;
  • Deshmukh, Samir K. (Chemical Engineering Department, Priyadarshini Institute of Engineering and Technology) ;
  • Thorat, Prashant V. (Chemical Engineering Department, College of Engineering and Technology (SantGadge Baba Amravati University))
  • 투고 : 2015.10.13
  • 심사 : 2017.04.25
  • 발행 : 2017.11.25

초록

A multi-effect air gap membrane distillation (ME-AGMD) module for pesticide wastewater treatment is studied with internal heat recovery, sensible heat of brine recovery, number of stages and the use of fresh feed as cooling water in a single module is implemented in this study. A flat sheet polytetrafluroethylene (PTFE) membrane was used in the 4-stage ME-AGMD module. The maximum value of permeate flux could reach $38.62L/m^2h$ at feed -coolant water temperature difference about $52^{\circ}C$. The performance parameter of the module like, specific energy consumption and gain output ratio (GOR) was investigated for the module with and without heat recovery. Also, the module performance was characterized with respect to the separation efficiency of several important water quality parameters. The removal efficiency of the module was found to be >98.8% irrespective water quality parameters. During the experiment the membrane fouling was caused due to the deposition of the salt/crystal on the membrane surface. The membrane fouling was controlled by membrane module washing cycle 9 h and also by acidification of the feed water (pH=4) using 0.1M HCl solution.

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참고문헌

  1. Ahalya, N., Ramchandra, T.V. and Kanamadi, R.D. (2003), "Biosorption of heavy metals", Res. J. Chem. Environ., 7(4), 71-74.
  2. Al-Anezi, A.A., Sharif, A.O., Sanduk, M.I. and Khan, A.R. (2013), "Potential of membrane distillation- a compressive review", Int. J. Water, 7(4), 317-346. https://doi.org/10.1504/IJW.2013.056674
  3. Al Hattab, M.T. and Ghaly, A.E. (2012), "Disposal and treatment methods for pesticide containing wastewaters: critical review and comparative analysis", J. Environ. Protect., 3, 431-453. https://doi.org/10.4236/jep.2012.35054
  4. Ali, I., Asim, M. and Tabrez, A. (2012), "Low cost adsorbents for the removal of organic pollutants from wastewater", J. Environ. Managm., 113, 170-183. https://doi.org/10.1016/j.jenvman.2012.08.028
  5. Alkhudhiri, A., Darwish, N. and Hilal, N. (2013), "Treatment of saline solutions using air gap membrane distillation: Experimental study", Desalination, 323, 2-7. https://doi.org/10.1016/j.desal.2012.09.010
  6. Alklaibi, A.M. and Lior, N. (2004), "Membrane-distillation desalination: status and potential", Desalination, 171, 111-131.
  7. Babu, B.R., Seenimira, K.M. and Venkatesan, P. (2011), "Removal of pesticides from wastewater by electrochemical methods- A comparative approach", Sustain. Environ. Res., 21(6), 401-406.
  8. Barth and Mays (1991), Modern Methods of Polymer Characterization, Wiley and Sons, New York.
  9. Chiron, S., Fernandez-Alba, A., Rodriguez, A. and Garcia-Calvo, E. (2000), "Pesticide chemical oxidation: State of the art", Water Res., 34(2), 366-377. https://doi.org/10.1016/S0043-1354(99)00173-6
  10. Cipollina, A., Disparti, M.G., Tambarlni, A. and Micale, G. (2012), "Development of a membrane distillation module for solar energy seawater desalination", Chem. Eng. Res. Des., 90(12), 2101-2121. https://doi.org/10.1016/j.cherd.2012.05.021
  11. Curcio, E. and Drioli, E. (2005), "Membrane distillation and related operations- A review", Separat. Purif. Rev., 34, 35-86. https://doi.org/10.1081/SPM-200054951
  12. Dong, D., Li, P., Li, X., Zhao, Q., Zhang, Y., Jia, C. and Li, P. (2010), "Investigation on the photocatalytic degradation of pyrene on soil surfaces using nanometer anatase $TiO_2$ under UV radiation", J. Hazard. Mater., 174, 859-863. https://doi.org/10.1016/j.jhazmat.2009.09.132
  13. El-Abbassi, A., Hafidi, A., Khayet, M. and Garcia-Payo, M.C. (2013), "Integrated direct contact membrane distillation for olive mill wastewater treatment", Desalination, 323, 31-38. https://doi.org/10.1016/j.desal.2012.06.014
  14. Elimelech, M. and Phillip, W.A. (2011), "The future of seawater desalination: energy, technology, and the environment", Sci., 333, 712-717. https://doi.org/10.1126/science.1200488
  15. Geng, H., Wang, J., Zhang, C., Li, P. and Chang, H. (2015), "High water recovery of RO brine using multistage air gap membrane distillation", Desalination, 355, 178-185. https://doi.org/10.1016/j.desal.2014.10.038
  16. Goh, S., Zhang, Q., Zhang, J., McDougald, D., Krantz, W.B., Liu, Y. and Fane, A.G. (2013), "Impact of a biofouling layer on the vapor pressure driving force and performance of a membrane distillation process", J. Membr. Sci., 438, 140-152. https://doi.org/10.1016/j.memsci.2013.03.023
  17. Gryta, M. (2007), "Effect of iorn oxides scaling on the MD process performance", Desalination, 216, 88-102. https://doi.org/10.1016/j.desal.2007.01.002
  18. Gryta, M. (2008), "Alkaline scaling in the membrane distillation process", Desalination, 228, 128-134. https://doi.org/10.1016/j.desal.2007.10.004
  19. Gryta, M. (2010), "Application of membrane distillation process for tap water purification", Membr. Water Treat., 1(1), 1-12. https://doi.org/10.12989/mwt.2010.1.1.001
  20. Hausmann, A., Sanciolo, P., Vasiljevic, T., Weeks, M., Schroen, K., Gray, S. and Duke, M. (2013), "Fouling of dairy components on hydrophobic polytetrafluoroethylene (PTFE) membranes for membrane distillation", J. Membr. Sci., 442, 149-159. https://doi.org/10.1016/j.memsci.2013.03.057
  21. He, F., Gilron, J., Lee, H., Song, L. and Sirkar, K. (2008), "Potential for scaling by sparingly soluble salts in crossflow DCMD", J. Membr. Sci., 311, 68-80. https://doi.org/10.1016/j.memsci.2007.11.056
  22. Jani, J.P., Rajyani, C.V., Mistry, J.S., Patel, J.S., Desai, N.M. and Kashyap, S.K. (1991), "Residue of organochlorine pesticides and polycyclic aromatic hydrocarbons in drinking water of Ahmedabad City, India", Bull Environ. Contamin. Toxicol., 47(3), 381-387. https://doi.org/10.1007/BF01702198
  23. Khalifa, A., Lawal, D., Antar, M. and Khayet, M. (2015), "Experimental and theoretical investigation on water desalination using air gap membrane distillation", Desalination, 376, 94-108. https://doi.org/10.1016/j.desal.2015.08.016
  24. Khan, E.U. and Martin, A.R. (2014), "Water purification of arsenic- contaminated drinking water via air gap membrane distillation (AGMD)", Periodica Polytechnica, 58(1), 47-53.
  25. Kumar, S. and Singh, K.P. (1997), "Comparative profile of contaminants in ground water and surface water sources in Khasi Hills", Indian J. Environ. Protect., 13, 349-357.
  26. Kumar, S., Singh, K.P. and Gopal, K. (1995), "Organochlorine residues in rural drinking water sources of Northen and North Eastern India", J. Environ. Sci. Hlth., 30(6), 1211-1222.
  27. Lawson, K.W. and Lloyd, D.R. (1997), "Membrane distillation", J. Membr. Sci., 124, 1-25. https://doi.org/10.1016/S0376-7388(96)00236-0
  28. Li, N.N., Fane, A.G., Ho, W.S. and Matsuura, T. (2008), Advanced Membrane Technology and Applications, John Wiley and Sons, Inc., Hoboken, New Jersey.
  29. Liu, G.L., Zhu, C., Cheung, C.S. and Leung, C.W. (1998), "Theoretical and experimental studies on air gap membrane distillation", Heat Mass Transf., 34, 329-335. https://doi.org/10.1007/s002310050267
  30. Liu, R., Qin, Y., Li, X. and Liu, L. (2012), "Concentrating aqueous hydrochloric acid by multiple-effect membrane distillation", Front. Chem. Sci. Eng., 6(3), 311-321. https://doi.org/10.1007/s11705-012-1207-3
  31. Lu, S.J., Gao, Q.J. and Lu, X.L. (2012), "Device and process study on vacuum multiple-effect membrane distillation", Adv. Mater. Res., 573, 120-125.
  32. Mannella, G.A., Carrubba, L. and Brucato, V. (2010), "Charecterization of hydrophobic polymeric membranes for membrane distillation process", Int. J. Mater. Form., 3(1), 563-566. https://doi.org/10.1007/s12289-010-0832-y
  33. Method 508, (1975), Standard Methods for the Examination of Water and Wastewater, 14th Edition, 550.
  34. Mokhtar, N.M., Lau, W.J. and Goh, P.S. (2013), "Effect of hydrophobicity degree on PVDF hallow fiber membranes for textile wastewater treatment using direct contact membrane distillation", J. Teknologi, 65(4), 77-81.
  35. Mokhtar, N.M., Lau, W.J., Ismail, A.F. and Veerasamy, D. (2015), "Membrane distillation technology for treatment of wastewater from rubber industry in Malaysia", Procedia CIRP, 26, 792-796. https://doi.org/10.1016/j.procir.2014.07.161
  36. Oren, Y. (2008), "Capacitive deionization (CDI) for desalination and water treatment-past, present and future (a review)", Desalination, 228, 10-29. https://doi.org/10.1016/j.desal.2007.08.005
  37. Pangarkar, B.L. and Deshmukh, S.K. (2015), "Theoretical and experimental analysis of multi-effect air gap membrane distillation process (ME-AGMD)", J. Environ. Chem. Eng., 3, 2127-2135. https://doi.org/10.1016/j.jece.2015.07.017
  38. Pathak, R.K. and Dikshit, A.K. (2011), "Various techniques for Atrazine removal", Int. Conf. on Life Sci. and Tech. (IPCBEE), Singapore.
  39. Poroda, S., Zhao, R., van der Wal, A., Presser, V. and Biesheuvel, P.M. (2013), "Review on the science and technology of water desalination by capacitve deionization", Prog. Mater. Sci., 58, 1388-1442. https://doi.org/10.1016/j.pmatsci.2013.03.005
  40. Singh, V.K., Singh, R.S., Tiwari, P.N., Singh, J.K., Gode, F. and Sharma, Y.C. (2010), "Removal of malathion from aqueous solution and waste water using fly ash", J. Water Res. Protect., 2, 322-330. https://doi.org/10.4236/jwarp.2010.24037
  41. Srivastava, B., Jhelum, V., Basu, D.D. and Patanjali, P.K. (2009), "Adsorbents for pesticide uptake from contaminated water: A review", J. Scie. Indus. Res., 68, 839-850.
  42. Warsinger, D.E.M., Swaminathan, J. and Lienhard, J.H. (2014), Procedding of the 15th Int. Heat Transfer Conf., IHTC-15, 10-15.
  43. Zhao, K., Heinzel, W., Wenzel, M., Buttner, S., Bollen, F. et al. (2013), "Experimental study of the memsys vacuum-multi-effect membrane distillation (V-MEMD) module", Desalination, 323, 150-160. https://doi.org/10.1016/j.desal.2012.12.003