DOI QR코드

DOI QR Code

A Study on the Thermal and Electrical Properties of Fabricated Mo-Cu Alloy by Spark Plasma Sintering Method

방전 플라즈마 소결법으로 제작한 Mo-Cu 합금의 열적, 전기적 특성

  • Lee, Han-Chan (Heat Treatment R&D Group, Korea Institute of Industrial Technology, Research Institute of Advanced Manufacturing Technology) ;
  • Lee, Boong-Joo (Dept. of Electronic Engineering, Namseoul University)
  • Received : 2017.05.30
  • Accepted : 2017.09.27
  • Published : 2017.11.01

Abstract

Mo-Cu alloys have been widely used for heat sink materials, vacuum technology, automobile and many other applications due to their excellent physical and electronic properties. Especially, Mo-Cu composites with 5~20 wt% copper are widely used for the heavy duty service contacts due to their excellent properties like low coefficient of thermal expansion, wear resistance, high temperature strength and prominent electrical and thermal conductivity. In most of the applications, high dense Mo-Cu materials with homogeneous microstructure are required for high performance, which has led in turn to attempts to prepare ultra-fine and well-dispersed Mo-Cu powders in different ways, such as spray drying and reduction process, electroless plating technique, mechanical alloying process and gelatification-reduction process. However, most of these methods were accomplished at high temperature (typically degree), resulting in undesirable growth of large Cu phases; furthermore, these methods usually require complicated experimental facilities and procedure. In this study, Mo-Cu alloying were prepared by planetary ball milling (PBM) and spark plasma sintering (SPS) and the effect of Cu with contents of 5~20 wt% on the microstructure and properties of Mo-Cu alloy has been investigated.

Keywords

References

  1. Li, Zaiyuan; Zhai, Yuchun; Tian, Yanwen, "Sintering behavior of nanocrystalline Mo-Cu composite powders", Nanomaterial & Structure, 2003, 4: 23
  2. Chwa, S. O.; Klein, D.; Liao, H. L, "Temperature dependence of microstructure and hardness of vacuum plasma sprayed Cu-Mo composite coatings", Surface and Coatings Technology, 2006, 200: 5682 https://doi.org/10.1016/j.surfcoat.2005.08.114
  3. D. Wang, X. Dong, P. Zhou, A. Sun, and B. Duan, "Mechanical alloying of Cu-Mo powder mixtures and thermodynamic study of solubility", Mater. Lett., 61, 929 (2007). https://doi.org/10.1016/j.matlet.2006.11.070
  4. X. L. Zhou, Y. H. Dong, X. Z. Hua, R. U. Din, and Z.G. Ye, "Effect of Fe on the sintering and thermal properties of Mo-Cu composites", Mater. Des., 31, 1603 (2010). https://doi.org/10.1016/j.matdes.2009.09.014
  5. J. H. Shin, Q. M. Wang, and K. H. Kim, "Microstructural evolution and tribological behavior of Mo-Cu-N coatings as a function of Cu content", Mater. Chem. Phys., 130, 870 (2011). https://doi.org/10.1016/j.matchemphys.2011.08.002
  6. A. Kumar, K. Jayasankar, M. Debata, and A. Mandal, "Mechanical alloying and properties of immiscible Cu-20 wt.% Mo alloy", J.Alloy. Compd., 647, 1040 (2015). https://doi.org/10.1016/j.jallcom.2015.06.129
  7. H. S. Nalwa, Handbook of Nanostructured Materials and Nanotechnology, 269 (2000).
  8. Chen, Guoqin; Zhu, Dezhi; Zhang, Qiang, "Highly dense Mo/Cu composites fabricated by squeeze casting and their thermal conduction properties", The Chinese Journal of Nonferrous Metals, 2005, 15(11): 1864
  9. Zhou, Xianliang; Ye, Zhiguo; Hua, Xiaozhen, "Sintering behavior of nanocrystalline Mo-Cu composite powders", Nonferrous Metals, 2006, 58(2): 1
  10. S. O. Chwa, D. D. Klein, H. L. Liao, L. C. Dembinski, and C. Christian, "Temperature dependence of microstructure and hardness of vacuum plasma sprayed Cu-Mo composite coatings", Surf. Coat. Technol., 200, 5682 (2006). https://doi.org/10.1016/j.surfcoat.2005.08.114
  11. C. Aguilar, S. Ordonez, J. Marin, F. Castro, V. Martinez, "Study and methods of analysis of mechanically alloyed Cu-Mo powders", Mat. Sci. Eng. A, 464, 288 (2007). https://doi.org/10.1016/j.msea.2007.02.017
  12. J. L. Fan, C. Yubo, L. Tao, and T. Jiamin, "Sintering behavior of nanocrystalline Mo-Cu composite powders", Rare Metal Mat. Eng., 38, 1693 (2009). https://doi.org/10.1016/S1875-5372(10)60051-3
  13. P. Song, J. G. Cheng, L. Wan, J. S. Zhao, Y. F. Wang, and Y. B. Cai, J, "Preparation and characterization of Mo-15 Cu superfine powders by a gelatification- reduction process", Alloy. Compd., 476, 226 (2009). https://doi.org/10.1016/j.jallcom.2008.09.097
  14. A. K. Sun, D. Z. Wang, Z. Z. Wu, and X. Q. Zan, J, "Synthesis of ultra-fine Mo-Cu nanocomposites by coreduction of mechanical-activated CuMoO 4-MoO 3 mixtures at low temperature", Alloy. Compd., 505, 588 (2010). https://doi.org/10.1016/j.jallcom.2010.06.080
  15. Y. Wang, Z. Y. Pan, Z. Wang, X. G. Sun, and L. Wang, "Sliding wear behavior of Cr-Mo-Cu alloy cast irons with and without nano-additives", Wear, 271, 2953 (2011). https://doi.org/10.1016/j.wear.2011.06.015
  16. M. Abdellaoui and E. Gaffet, "The physics of mechanical alloying in a planetary ball mill: mathematical treatment", Acta Metal Mater., 43, 1087 (1995). https://doi.org/10.1016/0956-7151(95)92625-7
  17. C. C. Koch and J. D. Whittenberger, "Mechanical milling/alloying of intermetallics", Intemrrtdlics, 4, 339 (1996).
  18. J. Kano and F. Saito, "Correlation of powder characteristics of talc during planetary ball milling with the impact energy of the balls simulated by the particle element method", Powder Technol., 98, 166 (1998). https://doi.org/10.1016/S0032-5910(98)00039-4
  19. C. Suryanarayana, C.C. Koch, "Nanocrystalline materials - Current research and future directions", Hyperfine Interactions, 130, 5 (2000).
  20. O. Mamoru, "Sintering, consolidation, reaction and crystal growth by the spark plasma system (SPS)" Mater. Sci. Eng. A, 297, 183 (2000).
  21. Z. A. Munir and U. Anselmi-Tamburini, "The effect of electric field and pressure on the synthesis and consolidation of materials: a review of the spark plasma sintering method", J. Mater. Sci., 41, 763 (2006). https://doi.org/10.1007/s10853-006-6555-2