Membrane and Water Treatment

  • 제9권2호
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  • Pages.87-94
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  • 2018
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  • 2005-8624(pISSN)
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  • 2092-7037(eISSN)
테크노프레스 (Techno-Press)
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DOI QR코드

DOI QR Code

Binding of Methylene Blue to two types of water soluble polymer and its removal by polyelectrolyte enhanced ultrafiltration

  • Mansour, Nadia Cheickh (Wastewater Treatment Laboratory, Water Research and Technologies Center) ;
  • Ouni, Hedia (Department of Chemistry, Faculty of Science at Yanbu, Taibah University Yanbu, Medina Mounawara) ;
  • Hafiane, Amor (Wastewater Treatment Laboratory, Water Research and Technologies Center)
  • 투고 : 2016.06.09
  • 심사 : 2017.06.25
  • 발행 : 2018.03.25
⟨ 이전 논문 다음 논문 ⟩

초록

The interactions of water soluble polymers with dye are studied by ultrafiltration using a molecular weight cut off of 10 KDa regenerated cellulose ultrafiltration membrane. Two water-soluble polymers, namely Poly (Sodium-4 Styrenesulfonate) (PSS) and Poly (Vinyl Alcohol) (PVA) were selected for this study. The effects of process parameters, such as, polyelectrolyte concentrations, transmembrane pressure, ionic strength and pH of solution on dye retention and permeation flux were examined. PSS enhanced ultrafiltration achieved dye retention as high as 99% as a result of complexation between polyanion containing aromatic groups and cationic dye. This result was confirmed by the red shift. The retention of dye decreases as the salt concentration increases, a high retention was obtained at pH above 4. However, in case of PVA, relatively low retention (50%) was observed. Ionic strength and pH has no significant effect on the removal of MB. The permeate flux depended slightly on polyelectrolytes concentrations, transmembrane pressure, salt concentration and pH.

키워드

참고문헌

  1. Abdullah, F., Rauf, M.A. and Ashraf, S.S. (2007), "Photolytic oxidation of Safranin O with $H_2O_2$", Dyes Pigments, 72(3), 349-352. https://doi.org/10.1016/j.dyepig.2005.09.015
  2. Albanis, T.A., Hela, D.G., Sakellarides, T.M. and Danis, T.G. (2000), "Removal of dyes from aqueous solutions by adsorption on mixtures of fly ash and soil in batch and column techniques", Global Nest J., 2(3), 237-244.
  3. Antonov, L., Gergov, G., Petrov, V., Kubista, M. and Nygrem, J. (1999), "UV-Vis spectroscopic and chemometric study on the aggregation of ionic dyes in water", Talanta, 49(1), 99-106. https://doi.org/10.1016/S0039-9140(98)00348-8
  4. Chakraborty, S., Dasgupta, J., Farooq, U., Sikder, J., Drioli, E. and Curcio, S. (2014), "Experimental analysis modeling and optimization of chromium (VI) removal from aqueous solutions by polymer enhanced ultrafiltration", Membr. Sci., 456, 139-154. https://doi.org/10.1016/j.memsci.2014.01.016
  5. Dasgupta, J., Sikder, J., Mandal, T. and Adhikari, U. (2015), "Reactive red 120 retention through ultrafiltration enhanced by synthetic and natural polyelectrolytes", J. Hazard. Mater., 299, 192-205. https://doi.org/10.1016/j.jhazmat.2015.06.017
  6. Dragan, S., Dragan, D., Cristea, M., Airine., A. and Ghimici, L. (1999), "Polyelectrolytes complexes II specific aspects of the formation of polycation/dye/polyanion complexes", Polym. Sci. A, 37(4), 409 https://doi.org/10.1002/(SICI)1099-0518(19990215)37:4<409::AID-POLA4>3.0.CO;2-T
  7. Fradj, A.B., Ben Hamouda, S., Ouni, H., Lafi, R., Gaza, L. and Hafiane, A. (2014), "Removal of methylene blue from aqueous solutions by poly(acrylic acid) and poly(ammonium-acrylate) assisted ultrafiltration", Sep. Purif. Technol., 133, 76-81. https://doi.org/10.1016/j.seppur.2014.06.038
  8. Girgis, E., Adel, D., Tharwat, C., Attallah, A. and Rao, K.V. (2015), "Cobalt ferrite nanotubes and porous nanorods of dye removal", Adv. Nano Res., 7(6), 111-121.
  9. Hessel, C., Allegre, C., Maissers, M., Charbit, F. and Moulin, P. (2007), "Guidelines and legislation for dye house effluents", J. Environ. Manage., 83(2), 171-180. https://doi.org/10.1016/j.jenvman.2006.02.012
  10. Ingole, P.G., Sawat, S.Y., Ingole, N.P., Pawar, R.R., Bajaj, H.C., Singh, K., Cho, M.H. and Lee, H.K. (2016), "Preparation of activated carbon incorporated polysulfone membranes for dye separation", Membr. Water Treat., 7(6) 477- 493. https://doi.org/10.12989/mwt.2016.7.6.477
  11. Iqbal, M. and Ashiq, M., (2007), "Adsorption of dyes from aqueous solutions on activated charcoal", J. Hazard. Mater., 139(1), 57-66. https://doi.org/10.1016/j.jhazmat.2006.06.007
  12. Kadiogln, S.I., Yilmaz, L., Aydogan, N. and Ozbelge, H.O. (2010), "Removal of heavy metals from multicomponent metal mixtures by polymer enhanced ultrafiltration: Effects of pH, ionic strength and conformational changes in polymer structure", Sep. Sci. Technol., 45(10), 1363-1373. https://doi.org/10.1080/01496391003674274
  13. Ku, Y., Lee, P. and Wang, W. (2005), "Removal of acidic dyestuffs in aqueous solution by nanofiltration", J. Membr. Sci., 250(1-2), 159-165. https://doi.org/10.1016/j.memsci.2004.10.023
  14. Lin, S.H. and Peng, C.F. (1996), "Continuous treatment of textile wastewater by combined coagulation, electrochemical oxidation and activated sludge", Water Res., 30(3), 587-592. https://doi.org/10.1016/0043-1354(95)00210-3
  15. Majewska-Nowak, K. (2008), "The effect of a polyelectrolyte on the efficiency of dye-surfactant solution treatment by ultrafiltration", Desalination, 221(1-3), 395-404. https://doi.org/10.1016/j.desal.2007.02.057
  16. Mohan, N., Balusubramamiau, N. and Ahmed Basha, C. (2007), "Electrochemical oxidation of textile wastewater and its reuse", J. Hazard. Mater., 147(1-2), 644-651. https://doi.org/10.1016/j.jhazmat.2007.01.063
  17. Mondal, S., Ouni, H., Dhahbi, M. and De, S. (2012), "Kinetic modeling for dye removal using polyelectrolyte enhanced ultrafiltration", J. Hazard. Mater., 229, 381-389.
  18. Moreira, R.F.P.M., Peruch, M.G. and Kuhnen, N.C. (1998), "Adsorption of textile dyes on alumina: Equilibrium studies and contact time", Braz. J. Chem. Eng., 15(1).
  19. Morena Villoslada, I., Torres, C., Gonzalez, F., Shibue, T. and Nishide, H. (2009), "Binding of methylene blue to polyelectrolytes containing sulfonate groups", Macromol. Chem. Phys., 210(13-14), 1167-1175. https://doi.org/10.1002/macp.200900042
  20. Nidheesh, P.V., Gandhimathi, R. and Ramesh, S.T. (2013), "Degradation of dyes from aqueous solution by Fenton processes: A review", Environ. Sci. Pollut. Res., 20(4), 2099-2132. https://doi.org/10.1007/s11356-012-1385-z
  21. Ouni, H. and Dhahbi, M. (2010b), "Spectrometric study of crystal violet in presence of polyacrylic acid and polyethylenimine and its removal by polyelectrolyte enhanced ultrafiltration", Sep. Purif. Technol., 72(3), 340-346. https://doi.org/10.1016/j.seppur.2010.03.003
  22. Ouni, H. and Dhahbi, M. (2010a), "Removal of dyes from wastewater using polyelectrolyte enhanced ultrafiltration (PEUF)", Desalin. Water Treat., 22(1-3), 355-362. https://doi.org/10.5004/dwt.2010.1234
  23. Purkait, M.K., Das Guptu, S. and Pe, S. (2004), "Resistance enhanced in series model for micellar VF of eosin dye", J. Colloid Interfac. Sci., 270(2), 496-506. https://doi.org/10.1016/j.jcis.2003.10.030
  24. Quadrifoglio, F. and Grescenzi, V. (1971), "The interaction of methyl orange and other azo dyes with polyelectrolytes and with colloidal electrolytes in dilute aqueous solution", J. Colloid Interfac. Sci., 35(3), 447-459. https://doi.org/10.1016/0021-9797(71)90145-7
  25. Safarik, I., Ptackora, L. and Saforikova, M. (2002), "Adsorption of dyes on magnetically labeled baker's yeast cell", Eur. Cell. Mater., 3(2), 52-55.
  26. Shen, J.J., Rena, L.L. and Zhuang, Y.Y. (2006), "Interaction between anionic dyes and cationic floculant (PAM-DMC) in synthetic solutions", J. Hazard. Mater., 136(3), 809-815. https://doi.org/10.1016/j.jhazmat.2006.01.013
  27. Srisukphum, T., Cheimchaisri, C., Urase, T. and Yamamoto, K. (2009), "Experimentation and modeling of foulant interaction and reverse osmosis membrane fouling during textile wastewater reclamation", Sep. Purif. Technol., 68(1), 37-40 https://doi.org/10.1016/j.seppur.2009.04.006
  28. Tan, X., Kyaw, N.N., Teo, W.K. and Li, K. (2006), "Decolorization of dye containing aqueous solutions by the polyelectrolyte enhanced ultrafiltration (PEUF) process using a hollow fiber membrane module", Sep. Purif. Technol., 52(1), 110-116. https://doi.org/10.1016/j.seppur.2006.03.028
  29. Torrades, F. and Garcia-Montano, J. (2014), "Using central composite experimental design to optimize the degradation of real dye wastewater by Fenton and photo-Fenton reactions", Dyes Pigments, 100, 184-189. https://doi.org/10.1016/j.dyepig.2013.09.004
  30. Yao, H., Isohashi, T. and Kimura, K. (2007), "Electrolyte induced mesoscopic aggregation of thiacarbon cyanine dye in aqueous: counter ion size specificity", J. Phys. Chem B, 111(25), 7176-7183 https://doi.org/10.1021/jp070520h
  31. Zaghbani, N., Hafiane, A. and Dhahbi, M. (2007), "Separation of methylene blue from aqueous solution by micellar enhanced ultrafiltration", Sep. Purif. Technol., 55(1), 117-124. https://doi.org/10.1016/j.seppur.2006.11.008
  32. Zaghbani, N., Hafiane, A. and Dhahbi, M. (2008), "Removal of Safranin T from wastewater using micellar enhanced ultrafiltration", Desalination, 222(1-3), 348-356. https://doi.org/10.1016/j.desal.2007.01.148

피인용 문헌

  1. Interaction of toluidine blue dye with heptamolybdate: UV-visible and ultrafiltration study vol.22, pp.5, 2018, https://doi.org/10.1007/s10668-019-00402-8