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Performance Analysis of a Vacuum Pyrolysis System

  • Ju, Young Min (Division of Wood Chemistry & Microbiology, Department of Forest Products, Korea Forest Research Institute) ;
  • Oh, Kwang Cheol (Department of Biosystems Engineering, Kangwon National University) ;
  • Lee, Kang Yol (Eco Plant Co., Ltd.) ;
  • Kim, Dae Hyun (Department of Biosystems Engineering, Kangwon National University)
  • Received : 2018.01.17
  • Accepted : 2018.02.26
  • Published : 2018.03.01

Abstract

Purpose: The purpose of this study was to investigate the performance of a vacuum pyrolysis system, to analyze bio-oil characteristics, and to examine the applicability for farm-scale capacity. Methods: The biomass was pyrolyzed at 450, 480, and $490^{\circ}C$ on an electric heat plate in a vacuum reactor. The waste heat from the heat exchanger of the reactor was recycled to evaporate water from the bio-oil. The chemical composition of the bio-oil was analyzed by gas chromatography-mass spectrometry (GC-MS). Results: According to the analysis, the moisture content (MC) in the bio-oil was approximately 9%, the high heating value (HHV) was approximately 26 MJ/kg, and 29 compounds were identified. These 29 compounds consisted of six series of carbohydrates, 17 series of lignins, and six series of resins. Conclusions: Owing to low water content and the oxygen content, the HHV of the bio-oil produced from the vacuum reactor was higher by about 6 MJ/kg than that of the bio-oil produced from a fluidized bed reactor.

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References

  1. Bridgwater, A. V., S. Czernik, J. Diebold, D. Meier, A. Oasmaa, C. Peacocke, J. Piskorz and D. Radlein. 1999. Fast Pyrolysis of Biomass: A Handbook. Newbury, UK: CPL Press.
  2. Fan, Y., W. Zhao, S. Shao, Y. Cai, Y. Chen and L. Jin. 2018. Promotion of the vapors from biomass vacuum pyrolysis for biofuels under Non-thermal Plasma Synergistic Catalysis (NPSC) system. Energy 142: 462-472. https://doi.org/10.1016/j.energy.2017.10.060
  3. Guedes, R. E., A. S. Luna and A. R. Torres. 2017. Operating parameters for bio-oil production in biomass pyrolysis: A review. Journal of Analytical and Applied Pyrolysis 129:134-149.
  4. Kim, T. S., J. Y. Kim, S. Oh, H. Hwang and J. W. Choi. 2007. Investigation of physicochemical properties of biooils produced from pitch pine (Pinus rigida) at various temperatures. Korean Society of Wood Science & Technology, 40, 204-211.
  5. Lopez, G., R. Aguado, M. Olazar, M. Arabiourrutia and J. Bilbao. 2009. Kinetics of scrap tyre pyrolysis under vacuum conditions. Waste Management 29(10):2649-2655. https://doi.org/10.1016/j.wasman.2009.06.005
  6. Marathe, P. S., S. R. G. Oudenhoven, P. W. Heerspink, S. R. A. Kersten and R. J. M. Westerhof. 2017. Fast pyrolysis of cellulose in vacuum: The effect of potassium salts on the primary reactions. Chemical Engineering Journal 329:187-197. https://doi.org/10.1016/j.cej.2017.05.134
  7. Kaltschmitt, M. and A. V. Bridgwater. 1997. Biomass Gasification and PyrolysisState of the Art and Future Prospects. Newbury, UK: CPL Press.
  8. Oasmaa, A., E. Leppamaki, P. Koponen, J. Levander and E. Tapola. 1997. Physical Characterisation of Biomass-based Pyrolysis Liquids, Application of Standard Fuel Oil Analyses. Biologinkuja, Finland: VTT Energy.
  9. Oasmaa, A. and C. Peacocke. 2001. A Guide to Physical Property Characterization of Biomass-derived Fast Pyrolysis Liquids. Biologinkuja, Finland: VTT Energy.
  10. Oasmaa, A., E. Kuoppala and Y. Solantausta. 2003. Fast pyrolysis of forestry residue. 2. Physicochemical composition of product liquid. Energy and Fuels 17:433-443. https://doi.org/10.1021/ef020206g
  11. Garcia-Perez, M., A. Chaala and C. Roy. 2002. Vacuum pyrolysis of sugarcane bagasse. Journal of Analytical and Applied Pyrolysis 65:111-136. https://doi.org/10.1016/S0165-2370(01)00184-X