Applied Chemistry for Engineering (공업화학)

The Korean Society of Industrial and Engineering Chemistry (한국공업화학회)
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Preparation of Hybrid Beads Containing Polysulfone Modified with Carbon Nanotubes, Tributyl Phosphate and Di-(2-ethylhexyl)-phosphoric Acid and Removal Characteristics of Sr(II)

Polysulfone에 Carbon Nanotubes, Tributyl Phosphate와 Di-(2-ethylhexyl)-phosphoric Acid를 고정화한 하이브리드 비드의 제조와 Sr(II)의 제거 특성

  • Kam, Sang-Kyu (Department of Environmental Engineering, Jeju National University) ;
  • Suh, Jung-Ho (Department of Environmental & Chemical Industry, Ulsan College) ;
  • Yun, Jong-Won (Department of Biotechnology, Daegu University) ;
  • Lee, Min-Gyu (Department of Chemical Engineering, Pukyoung National University)
  • 감상규 (제주대학교 환경공학과) ;
  • 서정호 (울산과학대학교 환경화학공업과) ;
  • 윤종원 (대구대학교 생명공학과) ;
  • 이민규 (부경대학교 화학공학과)
  • Received : 2017.12.27
  • Accepted : 2018.02.09
  • Published : 2018.06.10
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Abstract

PSf/D2EHPA/TBP/CNTs beads were prepared by immobilizing carbon nanotubes (CNTs) and two extractants, di-(2-ethylhexyl)-phosphoric acid (D2EHPA) and tributyl phosphate (TBP) on polysulfone (PSf). The prepared PSf/D2EHPA/TBP/CNTs beads were characterized by SEM, TGA, and FTIR. The removal rate of Sr(II) by PSf/D2EHPA/TBP/CNTs beads was well described by the pseudo-second-order kinetic model. The maximum removal capacity of Sr(II) obtained from Langmuir isotherm was found to be 5.52 mg/g. The results showed that the removal efficiency of Sr(II) by PSf/D2EHPA/CNTs beads prepared in this study was significantly improved compared to that of using PSf/D2EHPA/CNTs beads without TBP.

Polysulfone (PSf)에 탄소 나노 튜브(CNTs, carbon nano tubes)와 두 가지 추출제, di-(2-ethylhexyl)-phosphoric acid (D2EHPA)와 tributyl phosphate (TBP)를 고정화시킨 PSf/D2EHPA/TBP/CNTs 비드를 제조하였다. 제조한 비드의 특성은 SEM, TGA 및 FTIR로 분석하였다. 제조한 PSF/D2EHPA/TBP/CNTs 비드에 의한 Sr(II)의 제거속도는 유사 2차 속도식에 의해 잘 설명되었으며, Langmuir 등온식으로 구한 Sr(II)의 최대 제거 용량은 5.52 mg/g이었다. 본 연구에서 제조한 PSf/D2EHPA/CNTs 비드에 의한 Sr(II)의 제거효율은 TBP가 첨가되지 않은 PSf/D2EHPA/CNTs 비드에 의한 Sr(II)의 제거효율 보다 크게 향상되는 결과를 나타내었다.

Keywords

References

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