Environmental Engineering Research

  • 제23권2호
  • /
  • Pages.129-135
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  • 2018
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  • 1226-1025(pISSN)
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  • 2005-968X(eISSN)
대한환경공학회 (Korean Society of Environmental Engineers)
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Efficient use of ferrate(VI) in the oxidative removal of potassium hydrogen phthalate from aqueous solutions

  • Tiwari, Diwakar (Department of Chemistry, School of Physical Science, Mizoram University) ;
  • Sailo, Lalsaimawia (Department of Chemistry, School of Physical Science, Mizoram University) ;
  • Yoon, Yi-Yong (Department of Environmental Engineering, Catholic Kwandong University) ;
  • Lee, Seung-Mok (Department of Environmental Engineering, Catholic Kwandong University)
  • 투고 : 2017.07.03
  • 심사 : 2017.10.12
  • 발행 : 2018.06.30
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초록

The aim of this study is to assess the applicability of ferrate(VI) in the efficient treatment of aqueous waste contaminated with potassium hydrogen phthalate (KHP) which is known to be a potent endocrine disrupting chemicals. Simulated batch reactor operations were conducted at a wide range of pH (7.0 to 12.0) and molar ratios of KHP to ferrate(VI). Kinetic studies were performed in the degradation process and overall rate constant was found to be 83.40 L/mol/min at pH 8.0. The stoichiometry of ferrate(VI) and KHP was found to be 1:1. Further, lower pH values and higher KHP concentrations were favoured greatly the degradation of KHP by ferrate(VI). Total organic carbon analysis showed that partial mineralization of KHP was achieved. The presence of several background electrolytes were studied in the degradation of KHP by ferrate(VI).

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참고문헌

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피인용 문헌

  1. Innovative oxidation and kinetic studies of ferrous ion by sodium ferrate (VI) and simultaneous removal of metals from a synthetic acid mine drainage vol.124, pp.p1, 2018, https://doi.org/10.1016/j.pce.2020.102932