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Performance Analysis of Upgrading Process with Amine-Based CO2 Capture Pilot Plant

  • Kwak, No-Sang (Creative Research Laboratory, KEPCO Research Institute, Korea Electric Power Corporation) ;
  • Lee, Junghyun (Creative Research Laboratory, KEPCO Research Institute, Korea Electric Power Corporation) ;
  • Lee, Dong Woog (Creative Research Laboratory, KEPCO Research Institute, Korea Electric Power Corporation) ;
  • Lee, Ji Hyun (Creative Research Laboratory, KEPCO Research Institute, Korea Electric Power Corporation) ;
  • Shim, Jae-Goo (Creative Research Laboratory, KEPCO Research Institute, Korea Electric Power Corporation)
  • Received : 2018.01.03
  • Accepted : 2018.06.11
  • Published : 2018.06.30

Abstract

This study applied upgrades to the processes of a 10 MW wet amine $CO_2$ capture pilot plant and conducted performance evaluation. The 10 MW $CO_2$ Capture Pilot Plant is a facility that applies 1/50 of the combustion flue gas produced from a 500 MW coal-fired power plant, and is capable of capturing up to 200 tons of $CO_2$. This study aimed to quantitatively measure efficiency improvements of post-combustion $CO_2$ capture facilities resulting from process upgrades to propose reliable data for the first time in Korea. The key components of the process upgrades involve absorber intercooling, lean/rich amine exchanger efficiency improvements, reboiler steam TVR (Thermal Vapor Recompression), and lean amine MVR (Mechanical Vapor Recompression). The components were sequentially applied to test the energy reduction effect of each component. In addition, the performance evaluation was conducted with the absorber $CO_2$ removal efficiency maintained at the performance evaluation standard value proposed by the IEA-GHG ($CO_2$ removal rate: 90%). The absorbent used in the study was the highly efficient KoSol-5 that was developed by KEPCO (Korea Electric Power Corporation). From the performance evaluation results, it was found that the steam consumption (regeneration energy) for the regeneration of the absorbent decreased by $0.38GJ/tonCO_2$ after applying the process upgrades: from $2.93GJ/ton\;CO_2$ to $2.55GJ/tonCO_2$. This study confirmed the excellent performance of the post-combustion wet $CO_2$ capture process developed by KEPCO Research Institute (KEPRI) within KEPCO, and the process upgrades validated in this study are expected to substantially reduce $CO_2$ capture costs when applied in demonstration $CO_2$ capture plants.

Keywords

Acknowledgement

Supported by : Korea Institute of Energy Technology Evaluation and Planning (KETEP)

References

  1. KPX, Power System Performance Report 2011, 298.
  2. IEA, Energy Technology Perspectives 2017, International Energy Agency, 2017, 361-389.
  3. IPCC 5th Assessment Report, 2014, 25.
  4. Davidson, R. M., "Post combustion carbon capture from coal fired plants-solvent scrubbing", IEA GHG Report CCC/12, London, UK, 2007.
  5. Rao, A. B. and Rubin, E. S., "A Technical, Economic and Environmental Assessment of Amine-based $CO_2$ capture Technology for Power Plant Greenhouse Gas Control", Environ., 2000, 30-36.
  6. Choi, W. J., Lee, J. S., Han, K. H., and Min, B. M., Characteristics of $CO_2$ Absorption and Degradation of Aqueous Alkanolamine Solutions in $CO_2$ and $CO_2-O_2$ System", Korean Chem. Eng. Res. (HWAHAK KONGHAK), 2011, 49(2), 256-262. https://doi.org/10.9713/kcer.2011.49.2.256
  7. Lee, J. H., Kim, B. J., Shin, S. H., Kwak, N. S., Lee, D. W., Lee, J. H. and Shim, J. G., "0.1MW Test Bed $CO_2$ Capture Studies with New Absorbent (KoSol-5)", Appl. Chem. Eng., 2016, 27(4), 391-396. https://doi.org/10.14478/ace.2016.1046
  8. IEA Greenhouse Gas R&D Programme, "Criteria for Technical and Economic Assessment of Plants with Low $CO_2$ Emissions", International Energy Agency ed., Gloucestershire, U.K., 2009, 25.
  9. Lee, J. H., Kwak, N. S., Lee, I. Y., Jang, K. R. and Shim, J. G., "Performance and Economic Analysis of Domestic Supercritical Coal-Fired Power plant with Post-Combustion $CO_2$ capture Process", Korean Chem. Eng. Res. (HWAHAK KONGHAK), 2012, 50(2), 365-370. https://doi.org/10.9713/kcer.2012.50.2.365
  10. Park, S., "Theoretical Study on Optimal Conditions for Absorbent Regeneration in $CO_2$ Absorption Process", Korean Chem. Eng. Res. (HWAHAK KONGHAK), 2012, 50(6), 1002-1007. https://doi.org/10.9713/kcer.2012.50.6.1002
  11. Lee, J. H., Kim, J. H., Lee, I. Y., Jang, K. R. and Shim, J. G., "Bench scale carbon dioxide from the flue gas by monoethanolamine", J. Chem. Eng. Jpn., 2010, 43, 720-726. https://doi.org/10.1252/jcej.10we033
  12. Lee, J. H., Kim, J. H., Lee, I. Y., Jang, K. R. and Shim, J. G., "Development of amine absorbents for post-combustion capture", 1st Post Combustion Capture Conference, Abu Dhabi, 2011.
  13. Kwak, N. S., Lee, J. H., Lee, I. Y., Jang, K. R. and Shim, J. G., "A study of new absorbent for post-combustion $CO_2$ capture test bed", J. Taiwan Inst. Chem. Eng., 2014, 45(5), 2549-2556. https://doi.org/10.1016/j.jtice.2014.06.002
  14. Aspen Plus. Aspen Plus version 7.1. Cambridge, MA, USA: Aspen Technology Inc; 2010.
  15. Rabensteiner, M., Kinger, G., Koller, M., Hochenauer, C., "Pilot plant study of aqueous solution of piperazine activated 2-amino-a-methyl-1-propanol for post combustion carbon dioxide capture", Int. J. Greenhouse Gas Control, 2016, 51, 106-117. https://doi.org/10.1016/j.ijggc.2016.04.035
  16. Mangalapally, H.P., Hasse, H., "Pilot plant study of new solvents for post combustion carbon dioxide capture by reactive absorption and comparision to monoethanolamine", Chem. End. Sci., 2011, 66(22), 5512-5522. https://doi.org/10.1016/j.ces.2011.06.054