Journal of Electrical Engineering and Technology

  • 제13권4호
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  • Pages.1692-1696
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  • 2018
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  • 1975-0102(pISSN)
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  • 2093-7423(eISSN)
대한전기학회 (The Korean Institute of Electrical Engineers)
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Preparation of BaTiO3/Poly(vinylidene fluoride) 0-3 Composite Films for Dielectric Applications

  • 투고 : 2017.09.17
  • 심사 : 2018.04.24
  • 발행 : 2018.07.01
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초록

Ferroelectric $BaTiO_3$/poly(vinylidene fluoride) (PVDF) nanocomposite films were successfully prepared by mixing $BaTiO_3$ nano-particles into PVDF solution dissolved in dimethylformamide under ultrasonification. The mixture was casted onto glass petri dish and then annealed at $100^{\circ}C$ for 12 h in vacuum dry oven. Crystal structure and surface morphology of the samples were analyzed by using an X-ray diffraction analysis and a field emission-scanning electron microscope, respectively. The relative dielectric permittivity and loss tangent were determined in the frequency range of 50 Hz to 1 MHz. For the $BaTiO_3/PVDF$ nanocomposites, the entire diffraction peaks match those indicated by standard $BaTiO_3$ perovskite structure. The FE-SEM image reveals the homogeneity of the $BaTiO_3$ nanopowder distribution and also predominant 0-3 connectivity. All results show that the dielectric properties of the nanocomposite films are desirable and the fabrication technique for preparing the $BaTiO_3/PVDF$ nanocomposites has a potential in the electronic applications.

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참고문헌

  1. Li Ma, Zhaoquan Gong, Yongqin Liu, Qizhuang He, Dongfang Xu and Dazhi Sun, "Preparation and property of $BaTiO_3$/PVDF composites," Mater. Sci. Forum, vol. 687, pp. 366-369, 2011. https://doi.org/10.4028/www.scientific.net/MSF.687.366
  2. Takeshi Otsuka and Yoshiki Chujo, "Synthesis of transparent poly(vinylidene fluoride) (PVdF)/zirconium oxide hybrids without crystallization of PVdF chains," Polymer, vol. 50, issue 14, pp. 3174-3181, July 2009. https://doi.org/10.1016/j.polymer.2009.05.018
  3. Alessandro Chiolerio, Mariangela Lombardi, Aadrea Guerriero, Giancarlo Canavese, Stefano Stassi, Rossana Gazia, Valentina Cauda, Diego Manfredi, Angelica Chipdoni, Alessio Verna, Matteo Cocuzza, Laura Montanaro and Candido Fabrizio Pirri, "Effect of the fabrication method of the functional properties of BaTiO3:PVDF nanocomposites," J. Mater. Sci., vol. 48, pp. 6943-6951, 2013. https://doi.org/10.1007/s10853-013-7500-9
  4. Ansari Seema, K. R. Dayas, and Justin M. Varghese, "PVDF-PZT-5H composites prepared by hot press and tape casting technique," J. Appl. Polymer Sci., vol. 106, pp. 146-151, 2007. https://doi.org/10.1002/app.26673
  5. A. Khorsand Zak, Wee Chen Gan, Wan Haliza Abd Majid, Majid Darroudi and Thamil Selvi Velayutham, "Experimental and theoretical dielectric studies of PVDF/PZT nanocomposite thin films," Ceram. Int., vol.37, pp. 1653-1660, 2011. https://doi.org/10.1016/j.ceramint.2011.01.037
  6. R. E. Newham, D. P. Skinner, and L. E. Cross, "Connectivity and piezoelectric-pyroelectric composites," Mater. Res. Bull., vol. 13, pp. 525-536, 1978. https://doi.org/10.1016/0025-5408(78)90161-7
  7. Yanan Hao, Xiaohui Wang, Stephen O'Brien, Julien Lombardi and Longtu Li, "Flexible $BaTiO_3$/PVDF gradated multilayer nanocomposite film with enhanced dielectric strength and high energy density," J. Mater. Chem., C, vol. 3, pp. 9740-9748, 2015.
  8. Yu Song, Yang Shen, Haiyang Liu, Yuanhua Lin, Ming Li and Ce-Wen Nan, "Enhanced dielectric and ferroelectric properties induced by dopamine-modified $BaTiO_3$ nanofibers in flexible poly(vinylidene fluoridetrifluoroethylene) nanocomposites," J. Mater. Chem., vol. 22, pp. 8063-8068, 2012. https://doi.org/10.1039/c2jm30297g
  9. Dang Hyok Yoon, "Tetragonality of barium titanate powder for a ceramic capacitor application," J. Ceram. Proc. Res., vol. 7, 704, pp. 343-354, 2006.
  10. Yeon Jung Kim, June Won Hyun, Hee Soo Kim, Joo Ho Lee, Mi Young Yun, S. J. Noh and Yong Hyun Ahn, "Microstructural characterization and dielectric properties of barium titanate solid solutions with donor dopants," Bull. Kor. Chem. Soc., vol. 30, issue 6, pp. 1267-1273, 2009. https://doi.org/10.5012/bkcs.2009.30.6.1267
  11. Zhi-Min Dang, Hai-Yan Wang, Yi-He Zhang and Jian- Quan Qi, "Morphology and dielectric property of homogeneous $BaTiO_3$/PVDF nanocomposites prepared via the natural adsorption action of nanosized $BaTiO_3$," Macromol. Rapid Commun., vol. 26, issue 14, pp. 1185-1189, 2005. https://doi.org/10.1002/marc.200500137
  12. Md Rajib, Mohammad Arif Ishtiaque Shuvo, Hasanul Karim, Diego Delfin, Samia Afrin and Yirong Lin, "Temperature influence on dielectric energy storage of nanocomposites," Ceram. Int. vol. 41, issue 1, pp. 1807-1813, January 2015. https://doi.org/10.1016/j.ceramint.2014.09.127
  13. Paritosh Singh, Hitesh Borkar, B. P. Singh, V. N. Singh and Ashok Kumar, "Ferroelectric polymer- ceramic composite thick films for energy storage applications," AIP Advances, vol. 4, issue 8, p. 087117, 2014. https://doi.org/10.1063/1.4892961