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A Study on the Application of Underbody Coating for Vehicles with Shell Thickness of Thermally Expandable Microspheres

  • Received : 2018.07.15
  • Accepted : 2018.07.24
  • Published : 2018.09.30

Abstract

In this study, research was conducted into the manufacture of thermally expandable microspheres for automotive underbody coatings and applications in industry. In particular, the relationship between heat resistance and the ratio of crosslinking agents and initiators in the manufacture of the thermally expandable microspheres was investigated. We focused on the results with various cross-linking agents; our aim was to make the walls of the microspheres thicker to solve the problem of reductions in size caused by shrinkage when the microspheres are heated to $T_m$ ($T_{max}$). We observed the sectional thickness and surface of the samples with thicker walls. The thick thermally expandable microspheres showed reduced shrinkage and excellent stability in spite of prolonged exposure to heat.

Keywords

References

  1. L. Cheah, N. D. Ciceri, E. Olivetti, S. Matsumura, D. Frterre, R. Roth, and R. Kirchain, "Manufacturing-focused emissions reductions in footwear production", J. Cleaner Product., 44, 18 (2013). https://doi.org/10.1016/j.jclepro.2012.11.037
  2. M. Jonsson, D. Nystrom, O. Nordin, and E. Malmstrom, "Surface modification of thermally expandable microspheres by grafting poly(glycidyl methacrylate using ARGET ATRP", Eur. Polym. J., 45, 2374 (2009). https://doi.org/10.1016/j.eurpolymj.2009.05.002
  3. M. Jonsson, O. Nordin, E. Malmstrom, and C. Hammer, "Suspension Polymerizatioin of Thermally Expandable core/shell particle", J. Polymer, 47, 3315 (2006). https://doi.org/10.1016/j.polymer.2006.03.013
  4. M. Jonsson, O. Nordin, A. L. Kron, and E. Malmstrom, "Thermally Expandable Microspheres with Excellent Expan- sion Characteristics at High Temperature", J. Appl. Polym. Sci., 117, 384 (2010).
  5. Y. Kawaguchi and T. Oishi, "Synthesis and Properties of Thermoplastic Expandable Microspheres: The Relation Between Cross lingking Densiy and Expandable property, J. Appl. Polym. Sci., 93, 505 (2004). https://doi.org/10.1002/app.20460
  6. G. J. Wang, C. S. Kang, and R. G. Jin, "Synthesis of acrylic core-shell composite polymers and properties of plastisolgels", Polym. Sci. and Tech., 2, 294, (1991).
  7. S. H. Jeon, W. C. Choi, T. H. Park, H. M. Kim, I. E. Jung, C. K. Baek, K. J. Seo, and B. H. Choi, "Development of a New Light-Weight Car Audio Using Polycarbonate/Acrylonitrile Butadiene-Styrene Copolymer Composite Based Hybrid Material", Int. J. Precis. Eng. Man., 13, 85 (2012). https://doi.org/10.1007/s12541-012-0012-8
  8. D. V. Rosato, "Advances in moulding reinforced plastic parts for automotive applications: A review of the industry in the USA", Composites, 4, 208 (1973).
  9. T. K. Lee and B. S. Kin, "Vibration analysis of automobile tire due to bump impact", Applied Acoustics, Applied Acoustics, 69, 473 (2008). https://doi.org/10.1016/j.apacoust.2007.12.003
  10. G. Wang, X. Wang, and R. Jin, "Preparation and properties of novel plastisols based on acrylic core-shell lattices", Colloid Polym. Sci., 283, 98 (2004). https://doi.org/10.1007/s00396-004-1104-5
  11. H. Y. You, J. H. Kim, M. W. Kim, K. I. Kim, and H. D. Park, "A Study of Characteristics Variation of Thermally Expandable Microspheres in Post-polymerization Treatment by Various Initiators", Elastomers and Composites, 52, 211 (2017).