Journal of Industrial and Engineering Chemistry

  • Volume 64
  • /
  • Pages.206-218
  • /
  • 2018
  • /
  • 1226-086X(pISSN)
  • /
  • 1876-794X(eISSN)
The Korean Society of Industrial and Engineering Chemistry (한국공업화학회)
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Improved photoelectric performance via fabricated heterojunction g-C3N4/TiO2/HNTs loaded photocatalysts for photodegradation of ciprofloxacin

  • Wu, Dongyao (Institute of Green Chemistry and Chemical Technology, School of Chemistry & Chemical Engineering, Jiangsu University) ;
  • Li, Jinze (Institute of Green Chemistry and Chemical Technology, School of Chemistry & Chemical Engineering, Jiangsu University) ;
  • Guan, Jingru (Institute of Green Chemistry and Chemical Technology, School of Chemistry & Chemical Engineering, Jiangsu University) ;
  • Liu, Chongyang (Institute of Green Chemistry and Chemical Technology, School of Chemistry & Chemical Engineering, Jiangsu University) ;
  • Zhao, Xiaoxu (Institute of Green Chemistry and Chemical Technology, School of Chemistry & Chemical Engineering, Jiangsu University) ;
  • Zhu, Zhi (Institute of Green Chemistry and Chemical Technology, School of Chemistry & Chemical Engineering, Jiangsu University) ;
  • Ma, Changchang (School of Environment, Jiangsu University) ;
  • Huo, Pengwei (Institute of Green Chemistry and Chemical Technology, School of Chemistry & Chemical Engineering, Jiangsu University) ;
  • Li, Chunxiang (Institute of Green Chemistry and Chemical Technology, School of Chemistry & Chemical Engineering, Jiangsu University) ;
  • Yan, Yongsheng (Institute of Green Chemistry and Chemical Technology, School of Chemistry & Chemical Engineering, Jiangsu University)
  • Received : 2017.10.11
  • Accepted : 2018.03.11
  • Published : 2018.08.25
⟨ Previous Next ⟩

Abstract

An Intercalated heterostructural $g-C_3N_4/TiO_2/HNTs$ supported photocatalyst was successfully prepared via sol-gel and calcination methods. The introduction of HNTs and the $g-C_3N_4-TiO_2$ heterojunction effectively enhanced the charge transfer and separation efficiency of photogenerated electron-hole pairs, which endued the $g-C_3N_4/TiO_2/HNTs$ hybrid material with an outstanding photoelectric performance and good stability. And an obviously enhanced photocatalytic activity was exhibited by photodegrading ciprofloxacin compared with pure $TiO_2$. Furthermore, the main active species were detected through trapping experiment and ESR spin-trap technique with DMPO, which confirmed that the $^{\bullet}O_2{^-}$ and the $h^+$ were the main active species in the photocatalytic system.

Keywords

Acknowledgement

Supported by : National Natural Science Foundation of China, National Science Foundation of Jiangsu Province, China Postdoctoral Science Foundation

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