Journal of the Semiconductor & Display Technology (반도체디스플레이기술학회지)

The Korean Society Of Semiconductor & Display Technology (한국반도체디스플레이기술학회)
권호 표지

Study on Mechanical Properties Modification of Styrene Butadiene Rubber Composites Filling with Graphene and Molybdenum Disulfide

  • Xu, Li Xiang (School of Energy, Materials, Chemical Engineering, Korea University of Technology and Education) ;
  • Sohn, Mi Hyun (School of Energy, Materials, Chemical Engineering, Korea University of Technology and Education) ;
  • Kim, Yu Soo (School of Energy, Materials, Chemical Engineering, Korea University of Technology and Education) ;
  • Jeong, Ye Rin (School of Energy, Materials, Chemical Engineering, Korea University of Technology and Education) ;
  • Cho, Ur Ryong (School of Energy, Materials, Chemical Engineering, Korea University of Technology and Education)
  • Received : 2019.09.02
  • Accepted : 2019.09.23
  • Published : 2019.09.30
Download PDF
⟨ Previous Next ⟩

Abstract

Styrene-butadiene rubber (SBR) composites, incorporated with graphene, molybdenum disulfide and their hybrid in different filling ratio, were fabricated by a two roll-mill. The dispersion states of all the samples' matrix were employed by carbon black dispersion tester. The curing properties of the pre-vulcanized rubber composites were investigated, after molding by heating press machine, the tensile strength, storage modulus, friction coefficient, the swelling property had also been tested according to ASTM. The composite G1M10 (filling with 1 phr graphene and 10 phr molybdenum) showed the best mechanical properties and viscoelastic properties in this research with a better filler dispersion state and more compact matrix structure.

Keywords

References

  1. Williams, C.K., Hillmyer, M.A., "Polymers from renewable resources: a perspective for a special issue of polymer reviews," Polym. Rev., 48(1), pp. 1-10, (2008). https://doi.org/10.1080/15583720701834133
  2. Lee, Y.J., Lee, S.B., Jung, J.Y., Lee, D.H., and Cho, U. R., "A Study on Composites of Ethylene-Vinyl Acetate Copolymer and Ethylene-Propylene-Diene Rubber with Aluminum Hydroxide as a Fire Retardant," Elastomers and Composites, 51(2), pp. 93-98, (2016). https://doi.org/10.7473/EC.2016.51.2.93
  3. Pfister, Daniel P., Ying Xia, Richard C. L., "Recent advances in vegetable oil‐based polyurethanes", ChemSusChem, 4(6), pp. 703-717, (2011). https://doi.org/10.1002/cssc.201000378
  4. Sahoo, S., Misra, M., Mohanty, A.K., "Enhanced properties of lignin-based biodegradable polymer composites using injection moulding process", COMPOS. PART A-APPL. S., 42(11), pp. 1710-1718, (2011). https://doi.org/10.1016/j.compositesa.2011.07.025
  5. Lee, D.H., Lee, K.H., Cho, U.R., "Property Comparison of Bio-Polyurethane and Petroleum based Polyurethane," J. SEMICONDUCT. DISPLAY. TECH., 17(2), pp. 47-52, (2018).
  6. Jang, S.H., Li, X.X., Cho, U.R., "A Study on Graphene Oxide and Carboxylated Styrene-Butadiene Rubber (XSBR) Nanocomposites," J. Semiconduct. Display. Tech., 16(1), pp. 52-58, (2017).
  7. Chung, Y.J., "Combustive Properties of Low Density Polyethylene and Ethylene Vinyl Acetate Composites Including Magnesium Hydroxide," Fire Science and Engineering, 25(5), pp. 69-75, (2011).
  8. Fritzen, F., Bohlke, T., "Reduced basis homogenization of viscoelastic composites", Compos. Sci. Technol., 76, pp. 84-91, (2013). https://doi.org/10.1016/j.compscitech.2012.12.012
  9. Lee, M., Yu. D., Kim, Y., Lee, S., Kim, J.H., Lee, Y.C., "Flame Retardancy and Physical Properties of Ethylene Vinyl Acetate/Aluminum Trihydroxide Composites," Polymer (Korea), 39(3), pp. 433-440, (2015). https://doi.org/10.7317/pk.2015.39.3.433
  10. Li, X.X., Lee, S.B., Cho, U.R., "Study on Property Change with a Fire Retardant Content in the Manufacture of Polymer Composites for Cable Sheath," Elastomers and Composites, 54(2), pp. 118-122, (2019). https://doi.org/10.7473/EC.2019.54.2.118
  11. Chen, X., Li, X.X., Cho, U.R., "Preparation of Hydroxyethyl Cellulose-Bamboo Charcoal (HxBy) Hybrid and Its Application to Reinforcement of Natural Rubber," Polymer (Korea), 43(3), pp. 351-358, (2019). https://doi.org/10.7317/pk.2019.43.3.351
  12. Li, X.X., Jeong, S.Y., Choi, E.J., Cho, U.R., "Study on Properties of Epoxidized Natural Rubber/Solution Styrene Butadiene Rubber Blend with Silica and Carbon Black in Different Filling Ratio," Polymer (Korea), 43(2), pp. 321-326, (2019). https://doi.org/10.7317/pk.2019.43.2.321
  13. Li, X.X., Lee, S.B., Cho, U.R., "Study on Manufacture and Properties of Polymer Compounds for Cable Sheath," J. Semiconduct. Display. Tech., 18(1), pp. 1-6, (2019).
  14. Lee, D.H., Li, X.X., Cho, U.R., "A Study on Properties of SSBR/NdBR Rubber Composites Reinforced by Silica", Elastomers and Composites, 53(4), pp. 202-206, (2019). https://doi.org/10.7473/EC.2018.53.4.202
  15. Chen, X., Li, X.X., Cho, U.R., "Study on Improvement of Properties for Epoxidized Natural Rubber by Addition of Starch and Molybdenum Disulfide," Polymer (Korea), 42(6), pp. 1085-1090, (2018). https://doi.org/10.7317/pk.2018.42.6.1085
  16. Yang, L.Y., Yu, T.T., Zheng, L., Liao, K., "Synergistic effect of hybrid carbon nantube-graphene oxide as a nanofiller in enhancing the mechanical properties of PVA composites," J. Mater. Chem., 21(29), pp. 10844-10851, (2011). https://doi.org/10.1039/c1jm11359c
  17. Kuilla, T., Bhadra, S., Yao, D., Kim, N.H., Bose, S., Lee, J.H., "Recent advances in graphene based polymer composites," Prog. Polym. Sci., 35(11), pp. 1350-1375, (2010). https://doi.org/10.1016/j.progpolymsci.2010.07.005
  18. Singh, V., Joung, D., Zhai, L., Das, S., Khondaker, S.I., Seal, S., "Graphene based materials: past, present and future," Prog. Mater. Sci., 56(8), pp. 1178-1271, (2011). https://doi.org/10.1016/j.pmatsci.2011.03.003
  19. Zhou, G., Wang, D. W., Yin, L., Li, C. N., Li, F. Cheng, H.M., "Oxygen bridges between NiO nanosheets and graphene for improvement of lithium storage," ACS nano, 6(4), pp. 3214-3223, (2012). https://doi.org/10.1021/nn300098m
  20. Hao, X., Jin, Z., Yang, H., Lu, G., Bi, Y., "Peculiar synergetic effect of $MoS_2$ quantum dots and graphene on metal-organic frameworks for photocatalytic hydrogen evolution," Appl. Catal. B-Environ., 210, pp. 45-56, (2017). https://doi.org/10.1016/j.apcatb.2017.03.057
  21. Tang, Z., Zhang, L., Feng, W., Guo, B., Liu, F., Jia, D., "Rational design of graphene surface chemistry for high-performance rubber/graphene composites," Macromolecules, 47(24), pp. 8663-8673, (2014). https://doi.org/10.1021/ma502201e
  22. Tang, Z., Zhang, C., Wei, Q., Weng, P., Guo, B., "Remarkably improving performance of carbon black-filled rubber composites by incorporating $MoS_2$ nano platelets," Compos. Sci. Technol., 132, pp. 93-100, (2016). https://doi.org/10.1016/j.compscitech.2016.07.001
  23. Min. S., Lu, G., "Sites for high efficient photocatalytic hydrogen evolution on a limited-layered MoS2 cocatalyst confined on graphene sheets-the role of graphene", J. Phys. Chem. C., 116(48), pp. 25415-25424, (2012). https://doi.org/10.1021/jp3093786
  24. Tsai, C.Y., Lin, S.Y., Tsai, H.C., "Butyl rubber nanocomposites with monolayer $MoS_2$ additives: structural characteristics, enhanced mechanical, and gas barrier properties", Polymers, 10(3), pp. 238-251, (2018). https://doi.org/10.3390/polym10030238